On the constitution of atoms and molecules

THE LONDON, EDINBURGH, AND DUBLIN
PHILOSOPHICAL MAGAZINE AND JOURNAL OF SCIENCE.
JULY 1913.
CONTENTS
Introduction.
The principal difference between the atom-models proposed by Thomson and Rutherford consists in the circumstance that the forces acting on the electrons in the atom-model of Thomson allow of certain configurations and motions of the electrons for which the system is in a stable equilibrium; such configurations, however, apparently do not exist for the second atom-model. The nature of the difference in question will perhaps be most clearly seen by noticing that among the quantities characterizing the first atom a quantity appears—the radius of the positive sphere—of dimensions of a length and of the same order of magnitude as the linear extension of the atom, while such a length does not appear among the quantities characterizing the second atom, viz. the charges and masses of the electrons and the positive nucleus; nor can it be determined solely by help of the latter quantities.
This paper is an attempt to show that the application of the above ideas to Rutherford’s atom-model affords a basis for a theory of the constitution of atoms. It will further be shown that from this theory we are led to a theory of the constitution of molecules.
In the present first part of the paper the mechanism of the binding of electrons by a positive nucleus is discussed in relation to Planck's theory. It will be shown that it is possible from the point of view taken to account in a simple way for the law of the line spectrum of hydrogen. Further, reasons are given for a principal hypothesis on which the considerations contained in the following parts are based.
I wish here to express my thanks to Prof. Rutherford for his kind and encouraging interest in this work.
§1. General Considerations.
The inadequacy of the classical electrodynamics in accounting for the properties of atoms from an atom-model as Rutherford’s, will appear very clearly if we consider a simple system consisting of a positively charged nucleus of very small dimensions and an electron describing closed orbits around it. For simplicity, let us assume that the mass of the electron is negligibly small in comparison with that of the nucleus, and further, that the velocity of the electron is small compared with that of light.