15. MATTER IS HEATABLE.
So long as heat was thought to be some kind of an imponderable thing, which might retain its
identity whether it were in or out of matter, its real nature was obscured by the name given to it. An imponderable was a mysterious something like a spirit, which was the cause of certain phenomena in matter. Heat, light, electricity, magnetism, gravitation, were due to such various agencies, and no one concerned himself with the nature of one or the other. Bacon thought that heat was a brisk agitation of the particles of substances, and Count Rumford and Sir Humphrey Davy thought they proved that it could be nothing else, but they convinced nobody. Mayer in Germany and Joule in England showed that quantitative relations existed between work done and heat developed, but not until the publication of the book called Heat as a Mode of Motion, was there a change of opinion and terminology as to the nature of heat. For twenty years after that it was common to hear the expressions heat, and radiant heat, to distinguish between phenomena in matter and what is now called radiant energy radiations, or simply ether-waves. Not until the necessity arose for distinguishing between different forms of energy, and the conditions for developing them, did it become clear to all that a change in the form of energy implied a change in the form of motion that embodied it. The energy called heat energy was proved to be a vibratory motion of molecules, and what happened
in the ether as a result of such vibrations is no longer spoken of as heat, but as ether waves. When it is remembered that the ultimate atoms are elastic bodies, and that they will, if free, vibrate in a periodic manner when struck or shaken in any way, just as a ball will vibrate after it is struck, it is easy to keep in mind the distinction between the mechanical form of motion spent in striking and the vibratory form of the motion produced by it. The latter is called heat; no other form of motion than that is properly called heat. It is this alone that represents temperature, the rate and amplitude of such atomic and molecular vibrations as constitute change, of form. Where molecules like those in a gas have some freedom of movement between impacts, they bound away from each other with varying velocities. The path of such motion may be long or short, depending upon the density or compactness of the molecules, but such changes in position are not heat for a molecule any more than the flight of a musket ball is heat, though it may be transformed into heat on striking the target.
This conception of heat as the rapid change in the form of atoms and molecules, due to their elasticity, is a phenomenon peculiar to matter. It implies a body possessing form that may be changed; elasticity, that its changes may be periodic, and
degrees of freedom that secure space for the changes. Such a body may be heated. Its temperature will depend upon the amplitude of such vibrations, and will be limited by the maximum amplitude.