SUBJECT INDEX
A
Acetaldehyde and paraldehyde, [204]
Acetic acid, chloroform, water, [241]
Acetone, phenol, water, [248]
Adsorption, [176]
Alcohol, chloroform, water, [246]
——, ether, water, [246]
Alloys, equilibrium curves of, [221]
—— of copper and tin, liquefaction of, by cooling, [194]
—— of iron and carbon, [223]
—— of thallium and mercury, [222]
——, ternary, [246]
Ammonia compounds of metal chlorides, [82]
Ammonia silver chlorides, [82]
—— —— ——, dissociation pressures of, [84]
Ammonia-soda process, [320]
Ammonium chloride, dissociation of, [3], [79]
—— cyanide, dissociation of, [80]
—— hydrosulphide, dissociation of, [80]
—— nitrate, solubility of, [113]
Aniline, phenol, water, [250]
Astracanite, [260], [261], [268], [274]
B
Babo, law of, [126]
Barium acetate, solubility of, [143]
Barium carbonate and potassium sulphate, [328]
—— nitrite, preparation of, [327]
Basic salts, [296]
Benzaldoximes, [203]
Benzene and picric acid, [216]
Bismuth, effect of pressure on the melting point of, [67]
——, lead, tin, [255]
—— nitrates, basic, [298]
Bivariant systems, [16]
Bromocinnamic aldehyde and chlorocinnamic aldehyde, [183]
C
Calcium carbonate, dissociation of, [3], [11], [81]
—— chloride hexahydrate, solubility of, [146]
—— ——, solubility of hydrates of, [148]
—— ——, vapour-pressure of hydrates of, [88]
Carnallite, [284]
Cementite, [224]
Chlorine and iodine, [161]
Chlorocinnamic aldehyde and bromocinnamic aldehyde, [183]
Chloroform, acetic acid, water, [241]
——, alcohol, water, [246]
Classification of systems, [17]
——, systems of one, [21], [55]
Components, choice of, [12], [13], [14], [76], [313]
——, determination of number of, [13]
——, systems of four, [312]
——, —— of three, [234]
——, variation in number of, [11], [14]
Composition, determination of, without analysis, [228], [302]
Concentration-temperature curve for two liquids, [101]
Condensed systems, [36]
Constituent, [10]
Cooling curve, [230]
Copper calcium acetate, [260]
—— chloride, heat of solution of, [110]
—— dipotassium chloride, [259]
—— sulphate, [85]
Critical concentration, [98], [242]
—— pressure of water, [23]
—— solution temperature, [98]
—— temperature of water, [23]
Cryohydric point, [117]
—— ——, changes at the, [119]
—— —— for silver nitrate and ice, [116]
Crystals, liquid, [51]
——, ——, equilibria of, [53]
——, ——, list of, [54]
——, ——, nature of, [52]
——, mixed, [180]
Crystallization, velocity of, [72], [74]
——, spontaneous, [114]
D
Deliquescence, [130]
Devitrification, [73]
Diethylamine and water, solubility of, [101]
Dilatometer, determination of transition points by, [331]
Dineric surface, [247]
Dissociation equilibrium, effect of addition of dissociation products on, [4]
—— of ammonia compounds of metal chlorides, [82], [84]
—— of ammonium chloride, [3], [79]
—— —— cyanide, [80]
—— —— hydrosulphide, [80]
—— of calcium carbonate, [3], [81]
—— of compounds, degree of, [147]
—— of phosphonium bromide, [80]
—— of salt hydrates, [85]
——, phenomena of, [79]
Dissociation pressure, [81]
Distillation of supercooled liquid to solid, [32], [50]
Double salt interval, [278]
—— salts, crystallization from solution, [280]
—— ——, decomposition by water, [267]
—— ——, formation of, [258], [273], [315]
E
Efflorescence, [86]
Electrical methods of determining transition points, [338]
Equilibria, Gibbs's theory of, [8]
——, metastable, [69]
Equilibrium apparent (false), [5], [6]
—— between ice and solution, [116]
—— between ice and water, [25]
—— between ice, water, vapour, [27]
—— between water and vapour, [21]
——, heterogeneous, [5]
——, homogeneous, [5]
——, independence of, on amounts of phases, [9]
——, law of movable, [58]
Ether, alcohol, water, [246]
——, succinic nitrile, water, [252]
Ethylene bromide, picric acid, β-naphthol, [256]
Eutectic mixtures, [117], [191], [209], [255], [257]
—— point, [117], [209], [213], [253]
F
Ferric chloride, evaporation of solutions of, [155]
—— ——, hydrates of, [151], [153]
—— ——, hydrogen chloride and water, systems of, [290]
Ferrite, modifications of, [224]
Freedom, degree of, [14]
Freezing mixtures, [120]
—— point, natural, [198]
Fusion curve, [66]
—— —— of ice, [25]
—— of ice, influence of pressure on, [26]
——, partial, [139]
G
Glasses, [176]
—— ——, transition curve of, [68], [140]
Graphic representation in space, [77], [284]
H
Hydrates, range of existence of, [89]
—— chloride and water, [174]
Hydrogen bromide and water, [174]
Hylotropic substances, [198]
I
Ice I., [32]
—— II., [32]
—— III., [32]
——, equilibrium between water and, [25]
——, influence of pressure on melting point of, [25], [26]
——, sublimation curve of, [24]
——, vapour pressure of, [25], [31]
Indifferent point, [150]
Individual, chemical, [92]
Inversion temperature, [36]
Iodine and chlorine, [161]
Iron—carbon alloys, [223]
——, carbon monoxide and carbon dioxide, [305]
Isomerides, dynamic, [195], [196]
——, ——, equilibrium between, [195], [196]
——, ——, equilibrium point of, [198]
——, transformation of unstable into stable, [201]
Isomerism, dynamic, [196]
Isothermal evaporation, [278]
—— solubility curves, [272]
L
Lead, bismuth, tin, [255]
——, desilverization of, [247]
——, silver, zinc, [246]
Le Chatelier, theorem of, [57]
Lime, burning of, [3]
Liquidus curve, [182]
M
Mandelic acid, [217]
Martensite, [224]
Mass action, law of, [7]
Melting point, influence of pressure on, [66]
—— ——, congruent, [146]
—— ——, incongruent, [139]
—— under the solvent, [122]
Menthyl mandelates, [219]
Mercuric bromide and iodide, [188]
Mercury salts, basic, [301]
Metastable equilibria, [69]
—— region, [30]
—— state, [30]
Methylethyl ketone and water, [100]
Minerals, formation of, [232]
Miscibility of liquids, complete, [95], [104], [114]
—— ——, partial, [95], [96], [121]
—— ——, changes in, with temperature, [192]
—— ——, examples of, [183], [186], [187], [190], [192], [219], [223]
—— ——, formation of, [181], [182]
—— ——, fractional crystallization of, [188]
—— ——, freezing points of, [182]
—— ——, melting points of, [182], [184]
—— ——, pseudoracemic, [219]
Mixtures, isomorphous, [181]
—— of constant boiling point, [105]
—— of constant melting point, [117], [186], [187], [192], [209], [255], [257]
Multivariant systems, [16]
N
Naphthalene and monochloracetic acid, [192]
—— and β-naphthol, mixed crystals of, [183]
β-Naphthol, ethylene bromide, picric acid, [256]
α-Naphthylamine and phenol, [213]
Nickel iodate, solubility of, [142]
o-Nitrophenol and p-toluidine, [213]
O
Occlusion of gases, [176]
Optical method of determining transition points, [338]
Optically active substances, freezing-point curves of, [216]
Order of a system, [13]
Organic compounds, application of Phase Rule to, [212]
P
Palladium and hydrogen, [90], [178]
Paragenesis, [320]
Paraldehyde and acetaldehyde, [204]
Partial pressures of two components, [102]
Pearlite, [224]
Phase, [8]
—— ——, deduction of, [18]
—— ——, scope of, [1]
Phases, formation of new, [69]
——, number of, [9]
Phenol, acetone, water, [248]
——, aniline, water, [250]
—— and α-naphthylamine, [213]
—— and p-toluidine, [214]
—— and water, solubility of, [97]
Phosphonium bromide, dissociation of, [80]
—— chloride, [65]
Phosphorus, [46]
——, distillation of white to red, [50]
——, melting point of red, [47]
——, —— —— of white, [48]
——, solubility of white and red, [47]
——, vapour pressure of white and red, [46]
Picric acid and benzene, [216]
—— ——, ethylene bromide, and β-naphthol, [256]
Polymorphic forms, solubility of, [112]
—— substances, list of, [63]
Polymorphism, [33]
Potassium nitrate and thallium nitrate, [192]
Potential, chemical, [19]
Pressure-concentration diagram for two liquids, [102]
Pressure-temperature diagram for solutions, [126]
Pseudomonotropy, [45]
Pseudo-racemic mixed crystals, [21]
Pyridine and methyl iodide, [147]
Pyrometer, registering, [230]
Q
Quadruple point, [116]
R
Racemates, characterization of, [217], [282]
Reactions, law of successive, [73]
Reciprocal salt-pairs, [313]
—— ——, transition point of, [314]
Rubidium tartrates, [265]
S
Salt hydrates, [85]
—— ——, indefiniteness of vapour pressure of, [87]
—— —— with definite melting point, [145]
Separation of salt on evaporation, [130]
Silicates, hydrated, [176]
Silver, lead, zinc, [246]
Silver nitrate, solubility of, [114]
—— —— and sodium nitrate, [190]
Single salt interval, [278]
Sodium ammonium tartrates, [266]
—— nitrate and silver nitrate, [190]
—— sulphate and water, equilibria between, [134]
Sodium sulphate and water, vapour pressures of, [138], [140]
—— ——, anhydrous, dehydration by, [138]
—— ——, solubility of, [135]
—— —— decahydrate, solubility of, [134]
—— —— ——, transition point of, [136], [139]
—— —— heptahydrate, solubility of, [136]
—— —— ——, transition point of, [137]
Solidus curve, [182]
Solubility curve at higher temperatures, [114]
—— ——, form of, [108]
—— —— of anhydrous salts, [111]
—— ——, retroflex, [146], [151], [162]
—— curves, interpolation and extrapolation of, [111]
—— —— of three component systems, [264]
——, determination of transition points by, [335]
——, influence of pressure on, [107]
——, —— of subdivision on, [10]
——, —— of temperature on, [109]
—— of metastable forms, [47], [112], [137]
Solubility of polymorphic forms, [112]
—— of salt hydrates, [133], [145]
—— of supercooled liquids, [125]
——, retrograde, [245]
Solute, [93]
Solution, definition of, [92]
——, supersaturated, [108]
—— temperature, critical, [98]
——, unsaturated, [108]
Solutions, bivariant systems, [129]
——, congruently saturated, [279]
——, incongruently saturated, [279], [289]
——, inevaporable, [157]
—— of gases in liquids, [93]
—— —— in solids, [176]
—— of liquids in liquids (binary), [95]
—— —— —— (ternary), [240]
—— ——, influence of temperature on, [247]
—— of solids in liquids, [106]
—— —— in solids, [180]
——, univariant systems, [127]
Space model for carnallite, [284]
Stability limit, [202]
Steel, formation of, [223]
Sublimation curve, [63]
—— —— of ice, [24]
—— without fusion, [65]
Succinic nitrile and water, [122]
—— ether, water, [252]
—— dioxide and water, [169]
—— —— and potassium iodide, [158]
——, transition point of rhombic and monoclinic, [36]
Supersaturation, [113], [114], [124]
——, limits of, [114]
Systems, condensed, [36]
—— of one component, [21]
—— of two components, [76], [77], [207]
T
Tachydrite, influence of pressure on the transition point of, [263]
Tartrate, dimethyl, [217]
——, sodium potassium, [259]
Tautomeric substances, [195]
Tensimeter, [91]
Thallium nitrate and potassium nitrate, [192]
Theorem of van't Hoff and Le Chatelier, [57]
Thermometric determination of transition point, [337]
Tin, [41]
——, lead, bismuth, [255]
—— plague, [43]
——, transition point of white and grey, [41]
p-Toluidine and o-nitrophenol, [213]
—— and phenol, [214]
Transformation of optically active substances, [220]
——, suspended, [37], [69], [89], [113], [137], [155]
——, velocity of, [70]
Transition curve, [66]
—— —— of Glauber's salt, [68], [140]
—— —— of rhombic and monoclinic sulphur, [37]
—— interval, [270], [277], [315]
—— point, [34]
—— —— for double salts, [258]
—— ——, influence of pressure on the, [68]
—— points, as fixed points in thermometry, [140]
—— ——, methods of determining, [331]
—— —— of polymorphic substances, [63]
Triangle, graphic representation by, [235]
Triethylamine and water, [101]
—— ——, arrangement of curves round, [56]
—— ——, changes at, [58]
—— ——, ice, water, vapour, [27]
—— ——, ice II., ice III., and water, [33]
—— ——, metastable, [38]
—— ——, monoclinic sulphur, liquid, vapour, [38]
—— ——, monoclinic and rhombic sulphur, liquid, [38]
—— ——, monoclinic and rhombic sulphur, vapour, [34]
—— ——, red phosphorus, liquid, vapour, [47]
—— ——, rhombic sulphur, liquid, vapour, [38]
—— —— solid, solid, vapour, [62]
—— ——, white phosphorus, liquid, vapour, [48]
U
Univariant systems, [16]
V
Van't Hoff, theorem of, [57]
Vaporization curve, [63]
—— ——, interpolation and extrapolation of, [66]
Vapour pressure, constancy of, and formation of compounds, [90]
—— ——, dependence of, on solid phase, [88]
—— ——, influence of surface tension on, [2]
—— —— in three-component systems, [261]
—— ——, measurement of, [91], [334]
—— —— of calcium chloride solutions, [150]
—— —— of small drops, [10]
—— —— of sodium sulphate and water, [138]
Vapour pressure of solid, solution, vapour, [126]
Variability of a system, [14], [16]
Variance of a system, [16]
Volatile components, two, [161]
W
Water, [21]
——, acetic acid, chloroform, [241]
——, acetone, phenol, [248]
——, alcohol, ether, [246]
——, ——, chloroform, [246]
——, aniline, phenol, [250]
——, bivariant systems of, [29]
——, critical pressure of, [23]
——, critical temperature of, [23]
——, equilibrium between ice and, [25]
——, —— between vapour and, [21]
——, ether, succinic nitrile, [252]
——, supercooled, [30]
——, ——, vapour pressure of, [31]
——, vaporization curve of, [21]
——, vapour pressure of, [23]
Z
Zeolites, [176]
Zinc, lead, silver, [246]
—— chloride in water, solubility of, [157]
THE END
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