ELECTROLYSIS.
Much has been said about the possibilities of electrolysis of underground metal by the action of the return current of electric railways, when such railways are operated with grounded circuits, as they usually are. If electric current is passed through a liquid from one metal electrode to another, electrolysis will take place; that is, metal will be deposited on the negative pole, and the positive pole or electrode will be dissolved by becoming oxidized from the action of the oxygen collecting at that pole.
Fig. 86. Showing Electrolytic Action.
In an electric-railway return circuit, there is necessarily a difference of potential between the rails at outlying parts of the system and the rails and other buried pieces of metal located near the power house. Just what this total difference of potential is, depends on the loss of voltage in the return circuit. Thus, suppose there is 25 volts drop in the return circuit between a certain point on the system and the power station. There is, therefore, a pressure of 25 volts tending to force the current through the moist earth from the rails at distant portions of the line, to the rails, water pipes, and other connected metallic structures located in the earth near the power station. The amount of current that will thus flow to earth in preference to remaining in the rails, depends on the relative resistance of the rails, the earth, and the other paths offered to the current to return to the power house.
To take a very simple case, let us suppose a single-track road, [Fig. 86], with a power house at one end, and a parallel line of water pipe on the same street passing the power house. If the positive terminals of the generators are connected to the trolley wire, the current passes, as indicated by the arrows, out over the trolley wire through the cars and to the rails. When it has reached the rails it has the choice of two paths back to the power house. One is through the rails and bonding; the other is through the moist earth to the line of water pipe and back to the power house, leaving the pipe for the rails, at the power house. Should the bonding of the rails be very defective, considerable current might pass through the earth to the water pipe.
Remembering now the principles of electrolysis, we see that the oxidizing action of this flow of current from the rails to the water pipes at the distant portion of the road will tend to destroy the rails, but will not harm the water pipe at that point, as it will tend to deposit metal upon it. When, however, the current arrives at the power house, it must in some way leave this water pipe to get back to the rails, and so to the negative terminals of the generators.
Here we see that there is a chance for electrolysis of the water pipe, because at this point the water pipe forms the positive electrode, which is the one likely to be oxidized and destroyed. This very simple case is taken merely for illustration. In actual practice the conditions are never so simple as this, for there are various pipes located in the ground running in various directions, which complicate the case very much; but we can see from this simple example that the principal place electrolysis of water pipe is to be feared is at points where a large volume of current is leaving the water pipe to take to some other conductor.
As an indication of how much current is likely to be leaving the water pipes at various points, it is customary to measure the voltage between the water pipes and the electric railway track and rails. When this voltage is high, it does not necessarily mean that a large volume of current is leaving the water pipes at the point where these pipes are several volts positive with reference to the rails; but such voltage readings indicate that, if there is a path of sufficiently low resistance through the earth, and if the moisture in the earth is sufficiently impregnated with salts or acids, there will be trouble from an electrolytic action due to a large flow of current. There is obviously no method of measuring exactly the amount of current leaving a water pipe at any given point, since the pipe is buried in the earth. Voltmeter readings between pipes and rails simply serve to give an indication as to where there is likely to be trouble from electrolysis. The danger to underground pipes and other metallic structures from electrolysis has been much overestimated by some people, as the trouble can be overcome by proper care and attention to the return circuit. Trouble from electrolysis, however, is sure to occur unless such care is given.
Prevention of Electrolysis. Remedies for electrolysis may be classified under two heads—general and specific. The general remedy is obviously to make the resistance of the circuit through the rails and supplementary return feeders so low that there will be but little tendency for the current to seek other conductors, such as water and gas pipes and the lead covering of underground cables. This remedy consists in heavy bonding, in ample connections, around switches and special work where the bonding is especially liable to injury, and in additional return conductors at points near the power house to supplement the conductivity of the rails.
It is important that all rail bonds be tested at intervals of six months to one year in order that defective bonds may be located and renewed, as a few defective bonds can greatly lower the efficiency of an otherwise low-resistance circuit.
The specific remedy for electrolysis which may be applied to reduce electrolytic action at certain specific points, consists in connecting the water pipe at the point where electrolysis is taking place, with the rail or other conductor to which the current is flowing. Thus, for example, if it is found that a large amount of current is leaving a water pipe and flowing to the rails or to the negative return feeders at the power house, the electrolytic action at this point can obviously be stopped by connecting the water pipe with the rails by means of a low-resistance copper wire or cable, thereby short-circuiting the points between which electrolytic action is taking place. There are certain cases in which it is advisable to adopt such a specific remedy. It should be remembered, however, that a low-resistance connection of this kind, while it reduces electrolysis at points near the power house, is an added inducement to the current to take to the water pipes at points distant from the power house, because of the decrease in resistance of the water-pipe path to the power house resulting from the introduction of the connection between the water pipe and the negative return feeder at the power house. With the water pipes connected to the return feeders in the vicinity of the power house, the current which flows from the rails to the water pipes at points distant from the power house will obviously cause electrolysis of the rails but not of the water pipes, since the current is passing from the earth to the pipe, and the pipe is negative to the earth. In this case the principal danger is that the high resistance of the joints between the lengths of water pipe will cause current to flow through the earth around each joint, as indicated on some of the joints, [Fig. 86], and will cause electrolytic action at each joint. It is evident, however, that the conditions of the track circuit and bonding must be very bad if current would flow over a line of water pipe, with its high-resistance joints, in sufficient volume to cause electrolysis, in preference to the rail-return circuit, especially since ordinarily the resistance offered to the flow of current over the water pipes back to the power house must include the resistance of the earth between the tracks and water pipes.
It is usually considered inadvisable to connect tracks and water pipes at points distant from the power house, because of the danger of electrolysis at water-pipe joints, as just explained.
Methods of testing rail bonds in the track will be explained under the head of “Tests.”