FOOTNOTES:
[50] "Modern American Methods of Copper Smelting" (Dr. Peters).
[51] "Journal of the Society of Chemical Industry," vol. v. No. 2.
[52] Lead when present is precipitated on the spiral in the form of a dark powder of dioxide (PbO2). Manganese is also thrown down on the spiral as dioxide (MnO2), the solution at the same time becomes violet from the formation of permanganic acid.
[53] See the method given under Examination of Commercial Copper.
[54] CuSO4 + 4KCy = 2KCy.CuCy2 + K2SO4.
[55] 2CuSO4 + 3KCy + Am2O = Cu2Cy2 + Am2SO4 + K2SO4 + KCyO.
[56] 2CuSO4 + 4KI = Cn2I2 + 2I + 2K2SO4.
[57] 2Na2S2O3 + 2I = 2NaI + Na2S4O6.
[58] For further information, see Appendix B., and a paper by J.W. Westmoreland, Journal of the Society of Chemical Industry, vol. v. p. 48.
[59]
3Cu2O + 6AgNO3 + 3H2O
= 2Cu2H3O3NO3 + 2Cu(NO3)2 + 6Ag.
(Insoluble basic salt.)
[60] K2CrO4 + Pb(NO3)2 = PbCrO4 + 2KNO3
[61] Made by dissolving 12 grams of tartaric acid and 4 grams of stannous chloride in water, and adding potash solution till it is alkaline. The solution should remain clear on heating to 60° or 70° C.
[62] It must be remembered that arsenate of bismuth is completely insoluble in this acid.
[63] SbCl5 + 2KI = I2 + SbCl3 + 2KCl.