COMPOSITION OF UNDERGROUND WATERS
Underground waters are never entirely free from dissolved mineral substances, and seldom are they free from suspended particles. Some waters are desired because they contain very small quantities of dissolved mineral matter. Others are prized because they have an unusually high content of certain mineral substances. In determining the deleterious or beneficial effect of dissolved substances, much depends on the purpose for which the water is to be used,—whether for drinking, washing, steam boilers, or irrigation. Near the surface underground waters may carry bacteria, as well as animal and vegetable refuse, which from a sanitary standpoint are usually objectionable. Deeper waters are more likely to lack this contamination because of filtration through rocks and soils.
The dissolved mineral substances of underground water are derived for the most part from the solution of rocks with which the waters come in contact, particularly at or near the surface. Through the agency of underground water most of the mineral and chemical changes of rocks are produced. The dissolved substances in solution at any time and place may therefore be regarded as by-products of rock alterations. Locally they may to some extent be derived from direct emanations from cooling igneous masses.
The most common mineral substances contained in waters are lime and magnesia. Less common, but abundant locally, are soda, potash, iron, and silica. Waters contain also certain acid and gaseous substances, the most common of which is carbon dioxide; and less widespread, but locally abundant, are chlorine and sulphur dioxide. Where lime and magnesia are abundant the water is ordinarily classed as a hard water. Where absent, or subordinate to soda and potash, the water is ordinarily classed as a soft water. Large amounts of the acid substances like chlorine and sulphur are detrimental for most purposes. Where there are unusual amounts of carbon dioxide or other gases present, they may by expansion cause the water to bubble.
If we were to attempt to describe and define the characteristics, with reference to dissolved mineral content and temperature, which make a given water more desirable than another, we should enter a field of the most amazing complexity and one with many surprising contradictions. For the most widespread use, the most desirable water is a cold water as free from mineral content as possible, and especially one lacking an excess of lime and magnesia which make it hard; also lacking an excess of acid constituents like sulphur dioxide, carbon dioxide, or chlorine, which give the water a taste, or which make impossible its use in boilers. Locally and for special reasons, waters of other qualities are in demand. Waters so excessively carbonated as to bubble, sulphureted waters, chlorine waters, waters high in iron, high in silica, high in potash, high in soda, or high in magnesia, or waters of high temperature, may come to be regarded as desirable. It is an interesting fact that any water with unusual taste, or unusual mineral content, or unusual temperature, is likely to be regarded as having medicinal value. Sometimes this view is based on scientific knowledge; sometimes it is an empirical conclusion based on experience; and again it may be merely superstition. In one case the desirable feature may be the presence of a large amount of carbon dioxide; in another case it may be its absence. In one case the desirable feature may be high temperature; in another case low temperature. The same combination of qualities which in a certain locality may be regarded as highly desirable, may be regarded as highly detrimental somewhere else where certain other types of waters are in vogue.
Proprietary rights and advertising have brought certain waters into use for drinking purposes which are not essentially different from more widely available waters which are not regarded as having special value. Two springs located side by side, or a spring and a deep well, whose waters have exactly the same chemical characteristics, may be used and valued on entirely different scales. Any attempt to classify mineral waters sold to the public in any scientific way discloses a most intricate and confused situation. One can only conclude that the popularity of certain waters is not based alone on objective qualities of composition, but rather on causes which lie in the fields of psychology and commerce.
The part played by sentiment in putting value on water is well illustrated by the general preference for spring waters as compared with well waters. In the public mind, "spring water" denotes water of unusual purity and of more desirable mineral content than well water. Illustrations could be cited of districts in which the surface or spring waters have a composition not different from that of the deeper well waters, and are much more likely to be contaminated because of proximity to the surface; and yet people will pay considerable sums for the spring water in preference to the cheaply available well water.