Geologic Features
Uranium is one of the rarer metals. Radium is found only in uranium ores and only in exceedingly small quantities. The maximum amount which can be present in a state of equilibrium is about one part of radium in 3,000,000 parts of uranium. The principal sources of uranium and radium are the minerals carnotite (hydrous potassium-uranium vanadate) and pitchblende or uraninite (uranium oxide).
The deposits of Joachimsthal, Bohemia, contain pitchblende, along with silver, nickel, and cobalt minerals and other metallic sulphides, in veins associated with igneous intrusions.
The important commercial deposits of Colorado and Utah contain carnotite, together with roscoelite (a vanadium mica) and small amounts of chromium, copper, and molybdenum minerals, as impregnations of flat-lying Jurassic sandstones. The ores carry up to 35 per cent uranium oxide (though largely below 2 per cent), and from one-third as much to an equal amount of vanadium oxide. The ore minerals are supposed to have been derived from a thick series of clays and impure sandstones a few hundred feet above, containing uranium and vanadium minerals widely disseminated, and to have been carried downward by surface waters containing sulphates. The ore bodies vary from very small pockets to deposits yielding a thousand tons or so, and are found irregularly throughout certain particular beds without any special relation to present topography or to faults. The association of many of the deposits with fossil wood and other carbonaceous material suggests that organic matter was an agent in their precipitation, but the exact nature of the process is not clear. In a few places in Utah the beds dip at steep angles, and the carnotite appears in spots along the outcrops and generally disappears as the outcrops are followed into the hillsides; this suggests that the carnotite may be locally redissolved and carried to the surface by capillary action, forming rich efflorescences. Because of the nature of the deposits no large amount of ore is developed in advance of actual mining; but estimates based on past experience indicate great potentialities of this region for future production.
In eastern Wyoming is a unique deposit of uranium ore in a quartzite which lies between mica-schist and granite. The principal ore mineral is uranophane, a hydrated calcium-uranium silicate, which is believed to be an oxidation product of pitchblende. Some of the ore runs as high as 4 per cent uranium oxide, and the ore carries appreciable amounts of copper but very little vanadium.
Very recently radium ores have been discovered in the White Signal mining district of New Mexico, which was formerly worked for gold, silver, copper, and lead. The radium-bearing minerals are torbernite and autunite (hydrous copper-uranium and calcium-uranium phosphates), and are found in dark felsite dikes near their intersections with east-west gold-silver-quartz veins. The possibilities of this district have not yet been determined.
Pitchblende has been found in gold-bearing veins in Gilpin County, eastern Colorado, and in pegmatite dikes in the Appalachians, but these deposits are of no commercial importance. Pitchblende is grayish-black, opaque, and so lacking in distinctive characteristics that it may readily be overlooked; hence future discoveries in various regions would not be surprising.
CHAPTER XIII
MISCELLANEOUS NON-METALLIC MINERALS
NATURAL ABRASIVES
Economic Features
Natural abrasives are less important commercially in the United States than artificial abrasives, but a considerable industry is based on the natural abrasives.
Silica or quartz in its various crystalline forms constitutes over three-fourths of the tonnage of natural abrasives used in the United States. It is the chief ingredient of sand, sandstone, quartzite, chert, diatomaceous earth, and tripoli. From the sand and sandstone are made millstones, buhrstones, grindstones, pulpstones, hones, oilstones, and whetstones. Sand, sandstone, and quartzite are also ground up and used in sand-blasts, sandpaper, and for other abrasive purposes. Chert or flint constitutes grinding pebbles and tube-mill linings, and is also ground up for abrasives. Diatomaceous (infusorial) earth is used as a polishing agent and also as a filtering medium, an absorbent, and for heat insulation. Tripoli (and rottenstone) are used in polishing powders and scouring soaps as well as for filter blocks and many other purposes.
Other important abrasives are emery and corundum, garnet, pumice, diamond dust and bort, and feldspar.
Imports of abrasive materials into the United States have about one-third of the value of those locally produced. While all of the various abrasives are represented in these imports, the United States is dependent on foreign sources for important parts of its needs only of emery and corundum, garnet, pumice, diamond dust and bort, and grinding pebbles.
Emery and corundum are used in various forms for the grinding and polishing of hard materials—steel, glass, stone, etc. The principal foreign sources of emery have been Turkey (Smyrna) and Greece (Naxos) where reserves are large and production cheap. Production of corundum has come from Canada, South Africa, Madagascar, and India. The domestic production of emery is mainly from New York and Virginia, and corundum comes from North Carolina. Domestic supplies are insufficient to meet requirements, and cannot be substituted for the foreign material for the polishing of fine glass and other special purposes. Curtailment of imports during the war greatly stimulated the development of artificial abrasives and their substitution for emery and corundum.
Garnet is used chiefly in the form of garnet paper for working leather, wood, and brass. Garnet is produced mainly in the United States and Spain. The United States is the only country using large amounts of this mineral and imports most of the Spanish output. The domestic supply comes mainly from New York, New Hampshire, and North Carolina.
Pumice is used in fine finishing and polishing of varnished and enameled surfaces, and in cleaning powders. The world's principal source for pumice is the Lipari Islands, Italy. There is a large domestic supply of somewhat lower-grade material (volcanic ash) in the Great Plains region, and there are high-grade materials in California and Arizona. Under war conditions these supplies were drawn on, but normally the high-quality Italian pumice can be placed in American markets more cheaply.
Diamond dust is used for cutting gem stones and other very hard materials, and borts or carbonadoes (black diamonds) for diamond-drilling in exploration. Most of the black diamonds come from Brazil, and diamond dust comes from South Africa, Brazil, Borneo, and India.
Chert or flint pebbles for tube-mills are supplied mainly from the extensive deposits on the French and Danish coasts. The domestic production has been small, consisting principally of flint pebbles from the California beaches, and artificial pebbles made from rhyolite in Nevada and quartzite in Iowa. War experience demonstrated the possibility of using the domestic supply in larger proportion, but the grade is such that in normal times this supply will not compete with importations.
Feldspar as an abrasive is used mainly in scouring soaps and window-wash. Domestic supplies are ample. The principal use of feldspar is in the ceramic industry and the mineral is discussed at greater length in the chapter on common rocks (p. 86).
For the large number of abrasives produced from silica, outside of flint pebbles, domestic sources of production are ample. Siliceous rocks are available almost everywhere. For particular purposes, however, rocks possessing the exact combinations of qualities which make them most suitable are in many cases distinctly localized. Millstones and buhrstones, used for grinding cereals, paint ores, cement rock, fertilizers, etc., are produced chiefly in New York and Virginia; partly because of trade prejudice and tradition, about a third of the American requirements are imported from France, Belgium, and Germany. Grindstones and pulpstones, used for sharpening tools, grinding wood-pulp, etc., come mainly from Ohio and to a lesser extent from Michigan and West Virginia; about 5 per cent of the consumption is imported from Canada and Great Britain. Hones, oilstones, and whetstones are produced largely from a rock called "novaculite" in Arkansas, and also in Indiana, Ohio, and New England; imports are negligible. Flint linings for tube-mills were formerly imported from Belgium, but American products, developed during the war in Pennsylvania, Tennessee, and Iowa, appear to be wholly satisfactory substitutes. Diatomaceous earth is produced in California, Nevada, Connecticut, and Maryland, and tripoli and rottenstone in Illinois, Missouri, and Oklahoma; domestic sources are sufficient for all needs, but due to questions of back-haul and cost of rail transportation there has been some importation from England and Germany.