SUPERFICIAL SALINE DEPOSITS.
This subject may be here conveniently treated of: I will begin with the most interesting case, namely, the superficial saline beds near Iquique in Peru. The porphyritic mountains on the coast rise abruptly to a height of between one thousand nine hundred and three thousand feet: between their summits and an inland plain, on which the celebrated deposit of nitrate of soda lies, there is a high undulatory district, covered by a remarkable superficial saliferous crust, chiefly composed of common salt, either in white, hard, opaque nodules, or mingled with sand, in this latter case forming a compact sandstone. This saliferous superficial crust extends from the edge of the coast-escarpment, over the whole face of the country; but never attains, as I am assured by Mr. Bollaert (long resident here) any great thickness. Although a very slight shower falls only at intervals of many years, yet small funnel-shaped cavities show that the salt has been in some parts dissolved. (It is singular how slowly, according to the observations of M. Cordier on the salt-mountain of Cardona in Spain “Ann. des Mines, Translation of Geolog. Mem.” by De la Beche page 60, salt is dissolved, where the amount of rain is supposed to be as much as 31.4 of an inch in the year. It is calculated that only five feet in thickness is dissolved in the course of a century.) In several places I saw large patches of sand, quite moist, owing to the quantity of muriate of lime (as ascertained by Mr. T. Reeks) contained in them. From the compact salt- cemented sand being either red, purplish, or yellow, according to the colour of the rocky strata on which it rested, I imagined that this substance had probably been derived through common alluvial action from the layers of salt which occur interstratified in the surrounding mountains (“Journal of Researches” page 444 first edition.): but from the interesting details given by M. d’Orbigny, and from finding on a fresh examination of this agglomerated sand, that it is not irregularly cemented, but consists of thin layers of sand of different tints of colour, alternating with excessively fine parallel layers of salt, I conclude that it is not of alluvial origin. M. d’Orbigny observed analogous saline beds extending from Cobija for five degrees of latitude northward, and at heights varying from six hundred to nine hundred feet (“Voyage” etc. page 102. M. d’Orbigny found this deposit intersected, in many places, by deep ravines, in which there was no salt. Streams must once, though historically unknown, have flowed in them; and M. d’Orbigny argues from the presence of undissolved salt over the whole surrounding country, that the streams must have arisen from rain or snow having fallen, not in the adjoining country, but on the now arid Cordillera. I may remark, that from having observed ruins of Indian buildings in absolutely sterile parts of the Chilian Cordillera (“Journal” 2nd edition page 357), I am led to believe that the climate, at a time when Indian man inhabited this part of the continent, was in some slight degree more humid than it is at present.): from finding recent sea- shells strewed on these saliferous beds, and under them, great well-rounded blocks, exactly like those on the existing beach, he believes that the salt, which is invariably superficial, has been left by the evaporation of the sea-water. This same conclusion must, I now believe, be extended to the superficial saliferous beds of Iquique, though they stand about three thousand feet above the level of the sea.
Associated with the salt in the superficial beds, there are numerous, thin, horizontal layers of impure, dirty-white, friable, gypseous and calcareous tuffs. The gypseous beds are very remarkable, from abounding with, so as sometimes to be almost composed of, irregular concretions, from the size of an egg to that of a man’s head, of very hard, compact, heavy gypsum, in the form of anhydrite. This gypsum contains some foreign particles of stone; it is stained, judging from its action with borax, with iron, and it exhales a strong aluminous odour. The surfaces of the concretions are marked by sharp, radiating, or bifurcating ridges, as if they had been (but not really) corroded: internally they are penetrated by branching veins (like those of calcareous spar in the septaria of the London clay) of pure white anhydrite. These veins might naturally have been thought to have been formed by subsequent infiltration, had not each little embedded fragment of rock been likewise edged in a very remarkable manner by a narrow border of the same white anhydrite: this shows that the veins must have been formed by a process of segregation, and not of infiltration. Some of the little included and CRACKED fragments of foreign rock are penetrated by the anhydrite, and portions have evidently been thus mechanically displaced: at St. Helena, I observed that calcareous matter, deposited by rain water, also had the power to separate small fragments of rock from the larger masses. (“Volcanic Islands” etc. page 87.) I believe the superficial gypseous deposit is widely extended: I received specimens of it from Pisagua, forty miles north of Iquique, and likewise from Arica, where it coats a layer of pure salt. M. d’Orbigny found at Cobija a bed of clay, lying above a mass of upraised recent shells, which was saturated with sulphate of soda, and included thin layers of fibrous gypsum. (“Voyage Geolog.” etc. page 95.) These widely extended, superficial, beds of salt and gypsum, appear to me an interesting geological phenomenon, which could be presented only under a very dry climate.
The plain or basin, on the borders of which the famous bed of nitrate of soda lies, is situated at the distance of about thirty miles from the sea, being separated from it by the saliferous district just described. It stands at a height of 3,300 feet; its surface is level, and some leagues in width; it extends forty miles northward, and has a total length (as I was informed by Mr. Belford Wilson, the Consul-General at Lima) of 420 miles. In a well near the works, thirty-six yards in depth, sand, earth, and a little gravel were found: in another well, near Almonte, fifty yards deep, the whole consisted, according to Mr. Blake, of clay, including a layer of sand two feet thick, which rested on fine gravel, and this on coarse gravel, with large rounded fragments of rock. (See an admirable paper “Geological and Miscellaneous Notices of Tarapaca” in “Silliman’s American Journal” volume 44 page 1.) In many parts of this now utterly desert plain, rushes and large prostrate trees in a hardened state, apparently Mimosas, are found buried, at a depth from three to six feet; according to Mr. Blake, they have all fallen to the south-west. The bed of nitrate of soda is said to extend for forty to fifty leagues along the western margin of the plain, but is not found in its central parts: it is from two to three feet in thickness, and is so hard that it is generally blasted with gunpowder; it slopes gently upwards from the edge of the plain to between ten and thirty feet above its level. It rests on sand in which, it is said, vegetable remains and broken shells have been found; shells have also been found, according to Mr. Blake, both on and in the nitrate of soda. It is covered by a superficial mass of sand, containing nodules of common salt, and, as I was assured by a miner, much soft gypseous matter, precisely like that in the superficial crust already described: certainly this crust, with its characteristic concretions of anhydrite, comes close down to the edge of the plain.
The nitrate of soda varies in purity in different parts, and often contains nodules of common salt. According to Mr. Blake, the proportion of nitrate of soda varies from 20 to 75 per cent. An analysis by Mr. A. Hayes, of an average specimen, gave:—
Nitrate of Soda.... 64.98
Sulphate of Soda.... 3.00
Chloride of Soda... 28.69
Iodic Salts......... 0.63
Shells and Marl..... 2.60
99.90
The “mother-water” at some of the refineries is very rich in iodic salts, and is supposed to contain much muriate of lime. (“Literary Gazette” 1841 page 475.) In an unrefined specimen brought home by myself, Mr. T. Reeks has ascertained that the muriate of lime is very abundant. With respect to the origin of this saline mass, from the manner in which the gently inclined, compact bed follows for so many miles the sinuous margin of the plain, there can be no doubt that it was deposited from a sheet of water: from the fragments of embedded shells, from the abundant iodic salts, from the superficial saliferous crust occurring at a higher level and being probably of marine origin, and from the plain resembling in form those of Chile and that of Uspallata, there can be little doubt that this sheet of water was, at least originally, connected with the sea. (From an official document, shown me by Mr. Belford Wilson, it appears that the first export of nitrate of soda to Europe was in July 1830, on French account, in a British ship:—
In year, the entire export was in Quintals.
1830............................ 17,300
1831............................ 40,885
1832............................ 51,400
1833............................ 91,335
1834........................... 149,538
The Spanish quintal nearly equals 100 English pounds.)