The Steam Engine Explained and Illustrated (Seventh Edition) / With an Account of Its Invention and Progressive Improvement, and Its Application to Navigation and Railways; Including Also a Memoir of Watt

by Dionysius Lardner

(146.)

When carbon is heated to a temperature of about 700° in an atmosphere of pure oxygen, it will combine chemically with that gas, and the product will be the gas called carbonic acid. The volume of carbonic acid produced by this combination, will be exactly equal to that of the oxygen combined with the carbon, and therefore the weight of a given volume of the gas will be increased by the weight of carbon which enters the combination. It is found that two parts by weight of oxygen combined with three of carbon, form carbonic acid. The weight of the carbonic acid, therefore, produced in the combustion, will be greater than the weight of the oxygen, bulk for bulk, in the proportion of five to two, the volume being the same and the gases being [Pg253] compared at the same temperatures and under equal pressures. In this combination heat is evolved in very large quantities. This effect arises from the heat previously latent in the carbon and oxygen being rendered sensible in the process of combustion. The carbonic acid proceeding from the combustion is by such means raised to a very high temperature, and the carbon during the process acquires a heat so intense as to become luminous; no flame, however, is produced.

Hydrogen, heated to a temperature of about 1000°, in contact with oxygen will combine with the latter, and a great evolution of heat will attend the process; the gases will be rendered luminous, and flame will be produced. The product of this process will be water, which being exposed to the intense heat of combustion, will be immediately converted into steam. Hydrogen combines with eight times its own weight of oxygen, producing nine times its own weight of water.

Hydrogen gas is, however, not usually disengaged from coal in a simple form, but combined chemically with a certain portion of carbon, the combination being called carburetted hydrogen. Pure hydrogen burns with a very faintly luminous blue flame, but carburetted hydrogen gives that bright flame occasionally having an orange or reddish tinge, which is seen to issue from burning coals: this is the gas used for illumination, being expelled from the coal by the process of coking, and conducted to the various burners through proper pipes.

The sulphur, which in a very small proportion is contained in coals, is also combustible, and combines in the process of combustion with oxygen, forming sulphurous acid: it is also sometimes evolved in combination with hydrogen, forming sulphuretted hydrogen.

Atmospheric air consists of two gases, azote and oxygen, mixed together in the proportion of four to one; five cubic feet of atmospheric air consisting of four cubic feet of azote and one of oxygen. Any combustible will combine with the oxygen contained in atmospheric air, if raised to a temperature somewhat higher than that which is necessary to cause its combustion in an atmosphere of pure oxygen.

If coals, therefore, or other fuel exposed to atmospheric [Pg254] air, be raised to a sufficiently high temperature, their combustible constituents will combine with the oxygen of the atmospheric air, and all the phenomena of combustion will ensue. In order, however, that the combustion should be continued, and should be carried on with quickness and activity, it is necessary that the carbonic acid, and other products, should be removed from the combustible as they are produced, and fresh portions of atmospheric air brought into contact with it; otherwise the combustible would soon be surrounded by an atmosphere composed chiefly of carbonic acid to the exclusion of atmospheric air, and therefore of uncombined oxygen, and consequently the combustion would cease, and the fuel be extinguished. To maintain the combustion, therefore, a current of atmospheric air must be constantly carried through the fuel: the quantity and force of this current must depend on the quantity and quality of the fuel to be consumed. It must be such that it shall supply sufficient oxygen to the fuel to maintain the combustion, and not more than sufficient, since any excess would be attended with the effect of absorbing the heat of combustion, without contributing to the maintenance of that effect.

Heat is communicated from body to body in two ways, by radiation and by contact.

Rays of heat issue from a heated body, and are dispersed through the surrounding space in a manner, and according to laws, similar to those which govern the radiation of light. The heat thus radiated meeting other bodies is imparted to them, and penetrates them with more or less facility according to their physical qualities.

A heated body also brought into contact with another body of lower temperature, communicates heat to that other body, and will continue to do so until the temperature of the two bodies in contact shall be equalised. Heat proceeds from fuel in a state of combustion in both these ways: the heated fuel radiates heat in all directions around it, and the heat thus radiated will be imparted to all parts of the furnace which are exposed to the fuel.

The gases, which are the products of the combustion, escape from the fuel at a very high temperature, and consequently, in acquiring that temperature they absorb a considerable [Pg255] quantity of the heat of combustion. But besides the gases actually formed in the process of combustion, the azote forming four fifths of the air carried through the fuel to support the combustion, absorbs heat from the combustible, and rises into the upper part of the furnace at a high temperature. These various gases, if conducted directly to the chimney, would carry off with them a considerable quantity of the heat. Provision should therefore be made to keep them in contact with the boiler such a length of time as will enable them to impart such a portion of the heat which they have absorbed from the fuel, as will still leave them at a temperature sufficient, and not more than sufficient, to produce the necessary draft in the chimney.

(147.)

Fig. 71

The grate and a part of the flues are rendered visible by the removal of a portion of the surrounding masonry in which the boiler is set. The interior of the boiler is also shown by cutting off one half of the semi-cylindrical roof. A longitudinal vertical section is shown in [fig. 72.], and a cross section in [fig. 73.] A horizontal section taken above the level of the grate, and below the level of the water in the boiler, showing [Pg256] the course of the flues, is given in [fig. 74.] The corresponding parts in all the figures are marked by the same letters.

Fig. 72.

The door by which fuel is introduced upon the grate is represented at A, and the door leading to the ash-pit at B. The fire bars at C slope downwards from the front at an angle of about 25°, giving a tendency to the fuel to move from the front towards the back of the grate. The ash-pit D is constructed of such a magnitude, form, and depth, as to admit a current of atmospheric air to the grate-bars, sufficient to sustain the combustion. The form of the ash-pit is usually wide below, contracting towards the top.

The fuel when introduced at the fire-door A, should be laid on that part of the grate nearest to the fire-door, called the dead plates: there it is submitted to the process of coking, by which the gases and volatile matter which it contains are expelled, and being carried by a current of air, admitted [Pg257] through small apertures in the fire-door over the burning fuel in the hinder part of the grate, they are burnt. When the fuel in front of the grate has been thus coked, it is pushed back, and a fresh feed introduced in front. The coal thus pushed back soon becomes vividly ignited, and by continuing this process, the fuel spread over the grate is maintained in the most active state of combustion at the hinder part of the grate. By such an arrangement, the smoke produced by the combustion of the fuel may be burnt before it enters the flues. The flame and heated air proceeding from the burning fuel arising from the grate, and rushing towards the back of the furnace, passes over the fire-bridge E, and is carried through the flue F which passes under the boiler. This flue (the cross section of which is shown in [fig. 73.], by the dark shade put under the boiler) is very nearly equal in width to the bottom of the boiler, the space at the bottom of the boiler, near the corners, being only what is sufficient to give the weight of the boiler support on the masonry forming the [Pg258] sides of the flue. The bottom of the boiler being concave, the flame and heated air as they pass along the flue rise to the upper part by the effects of their high temperature, and lick the bottom of the boiler from the fire-bridge at E to the further end G.

Fig. 73.

At G the flue rises to H, and turning to the side of the boiler at I I, conducts the flame in contact with the side from the back to the front; it then passes through the flue K across the front, and returns to the back by the other side [Pg259] flue L. The side flue is represented, stripped of the masonry, in [fig. 71.], and also appears in the plan in [fig. 74.], and in the cross section in [fig. 73.] The course of the air is represented in [fig. 74.] by the arrows. From the flue L the air is conducted into the chimney at M.

Fig. 74.

By such an arrangement, the flame and heated air proceeding from the grate are made to circulate round the boiler, and the length and magnitude of the flues through which it is conducted should be such, that when it shall arrive at the chimney its temperature shall be reduced, as nearly as is consistent with the maintenance of draught in the chimney, to the temperature of the water with which it is in contact.

The method of feeding the furnace, which has been described above, is one which, if conducted with skill and care, would produce a much more perfect combustion of the fuel than would attend the common method of filling the grate from the back to the front with fresh fuel, whenever the furnace is fed. This method, however, is rarely observed in the management of the furnace. It requires the constant attention of the stokers (such is the name given to those who feed the furnaces). The fuel must be supplied, not in large quantities, and at distant intervals, but in small quantities and more frequently. On the other hand, the more common practice is to allow the fuel on the grate to be in a great degree burned away, and then to heap on a large quantity of fresh fuel, covering over with it the burning fuel from the back to the front of the grate. When this is done, the heat of the ignited coal acting upon the fresh fuel introduced, expels the gases combined with it and, mixed with these, a quantity of carbon, in a state of minute division, forming an opaque black smoke. This is carried through the flues and drawn up the chimney. The consequence is, that not only a quantity of solid fuel is sent out of the chimney unconsumed, but the hydrogen and other gases also escape unburned, and a proportional waste of the combustible is produced; besides which, the nuisance of an atmosphere filled with smoke ensues. Such effects are visible to all who observe the chimneys of steam-vessels, while the engine is in operation. When the furnaces are thus filled with fresh fuel, a large volume of [Pg260] dense black smoke is observed to issue from the chimney. This gradually subsides as the fuel on the grate is ignited, and does not reappear until a fresh feed is introduced.

This method of feeding, by which the furnace would be made to consume its own smoke, and the combustion of the fuel be rendered complete, is not however free from counteracting effects. In ordinary furnaces the feed can only be introduced by opening the fire-doors, and during the time the fire-doors are opened a volume of cold air rushes in, which passing through the furnace is carried through the flues to the chimney. Such is the effect of this in lowering the temperature of the flues, that in many cases the loss of heat occasioned is greater than any economy of fuel obtained by the complete consumption of smoke. Various methods, however, may be adopted by which fuel may be supplied to the grate without opening the fire-doors, and without disturbing the supply of air to the fire. A hopper built into the front of the furnace, with a moveable bottom or valve, by which coals may be allowed to drop in from time to time upon the front of the grate, would accomplish this.