ACETIC ACID, OR WOOD VINEGAR.
Acetic acid forms a considerable article of commerce. It is not only used in medicine and the culinary art, but is extensively employed in forming acetate of iron for dyeing and calico printing. To prepare it, large iron cylinders, about eight feet long and three in diameter, are embedded in brickwork in a row, and in such a manner that furnaces placed below may heat them red-hot; these cylinders have a tube leading from each into a main tube, where the liquid products from each cylinder are received for condensation; the other end of the cylinder has a plate of iron fitting closely to it. The cylinders are filled with logs of wood, either oak, beech, birch, or ash, the door is closely fastened and the joints smeared with clay; the fires are now lighted and kept up all day, till the cylinders are red-hot; at night they are allowed to cool. About seven or eight hundred weight of wood is put into each cylinder. In the morning, the charcoal, into which the wood is now converted, is withdrawn, and a fresh charge supplied; from this charge of wood about thirty or forty gallons of liquid is condensed in the main tube from each cylinder, the remainder being charcoal and gases which pass off; the liquid is acid, brown, and very offensive, and contains acetic acid, tar, and several other ingredients, among which may be named creasote; it is from this source all the creasote, so famous for the cure of toothache, is obtained. The next process is to purify this liquid; it is first distilled, and this separates much tar, it is then mixed with lime, evaporated to dryness, and heated to expel the remaining tar and other impurities; it is next mixed with sulphate of soda and water and the whole stirred together, the soda, now in unison with the acetic acid, is washed out from the lime and strained quite clear; it is afterwards evaporated till it crystallizes, and vitriol (sulphuric acid) then added; finally, the acetic acid is distilled over, and the acid left in unison with the soda, forming sulphate of soda, to be used in a similar process for the next batch of acid; the acetic acid is now quite colorless, transparent, and very sour, possessing a fragrant and agreeable smell. This acid is not pure acetic acid, but contains a considerable quantity of water. The acetic acid of commerce, mixed with seven times its bulk of water, forms an acid of about the strength of malt vinegar, perfectly wholesome, and, to many, more agreeable as a condiment.
Pure acetic acid may be made by mixing dry acetate of potash with oil of vitriol in a retort, and distilling the acetic acid into a very cold receiver; this, when flavored with various volatile oils, forms the aromatic vinegar sold by druggists. It is a very strong acid, and if applied to the skin will quickly blister it.