SODA.
The Soda of commerce is a carbonate of soda, and it is made from sea salt. It is used in large quantities for the general purposes of washing and cleansing, and very extensively in bleaching and soap making. Soda occurs in two forms—soda ash and in crystals; the first is the crude soda before crystallization. To make soda, oil of vitriol (sulphuric acid) is poured, by degrees, on a layer of sea salt, in a sort of funnel connected with a tall chimney; on the addition of the vitriol, copious fumes of the hydrochloric acid are given off; this is the acid formerly called spirit of salt. When the furnace is heated and all the acid driven off, the dried residue is taken out, it is sulphate of soda. It was formerly the custom to allow the hydrochloric acid to pass up a very tall chimney so that it may be dispersed in the air; but such an injurious effect was produced on the surrounding vegetation that this could no longer be allowed; the plan adopted was, to cause the acid to be condensed by filling the chimney with coke, and causing water to trickle through it; the acid vapours, coming into contact with this porous wet surface, is condensed into a liquid, which runs down into a cistern placed to receive it. The sulphate of soda, when taken from the furnace and cooled, is next ground in a mill with rather more than its weight of chalk, and about half its weight of coal. This mixture is placed in a furnace and raised to a sufficient heat to partly fuse it, during which time it is stirred about; the black mass which results is called by the workmen “black ball.” It is taken out and put into a cistern; water is then poured over it, and after stirring, it is drained off and evaporated to a dry mass; this is impure soda. It is mixed with coal-dust, again burnt, again washed and evaporated, by this second process the soda ash is produced, which, being dissolved, filtered and evaporated, produces large crystals of soda. The large quantity of hydrochloric acid produced in the first part of the process, is used in the of making chloric of lime. A few years back, soda was got from the ashes of the plant called “salsola soda,” and sold in the form of an impure carbonate called “barilla.”