LESSON XXVI
ALTERATION OF THE COLOR OF PRECIOUS STONES
Many gem minerals change color when more or less strongly heated. Extreme heat whitens many colored materials completely.
"Pinked Topaz." John Ruskin advises us to "seek out and cast aside all manner of false or dyed or altered stones" but, in spite of his advice, perhaps the most justifiable use of heat treatment is that which alters the color of true topaz from a wine-yellow to a fine pink. It would appear that the wine-yellow is a composite color composed of pink and yellow and that the pink constituent is less easily changed by heat than is the yellow one. If too high a temperature is used both colors disappear and white topaz results. As the latter is abundant in nature and of little value, such a result is very undesirable. Pink topaz, however, is very rare, and until recently, when pink tourmaline from California and Madagascar, and pink beryl (morganite) from Madagascar, became available in quantity, the "pinked" topazes had but few competing gems, and thus commanded a higher price than the natural topazes. Of course, care has to be taken in heating a mineral to raise and lower the temperature slowly, in order to avoid sudden and unequal expansion or contraction, which would crack and ruin the specimen, as the writer learned to his sorrow with the first topaz that he tried to "pink."
Spanish Topaz. Another material that gains a more valuable color by heat treatment is the smoky quartz of Spain, which, on being gently heated, yields the so-called Spanish topaz. Some amethysts are altered to a yellow color by mild heating. Too great a temperature completely decolorizes colored quartz. Some dark quartz yields a nearly garnet red product, after heating.
Zircon. Slight increase in temperature causes many of the zircons from Ceylon to change markedly in color. An alcohol flame serves admirably to effect the change, care being taken to warm up the stone very gradually and to cool it slowly. Drafts should be prevented, as they might suddenly cool the stone and crack it. Some zircons become completely whitened by this treatment. At the same time they increase markedly in density and in refractive index and thus become even more snappy and brilliant than when colored. One is tempted to suspect that the "space lattice" of the crystal has had its strata drawn closer together during the heating and left permanently in a closer order of arrangement. Other zircons merely become lighter colored and less attractive. Some of the whitened stones again become more or less colored on exposure to strong light. Ultra-violet light will sometimes restore these to a fine deep color in a short time.
The whitened zircon, when finely cut in the brilliant form, with truly flat facets and sharp edges and with a top angle of about 39 degrees and a back angle of about 44 degrees, so closely resembles a diamond that it will deceive almost anyone on casual inspection. The expert, even, may be deceived, if caught off his guard. The writer has a fine specimen of a little over one carat, with which he has deceived many jewelers and pawnbrokers, and even an importer or two. If it is presented as a stone that closely resembles diamond your expert will say: "Yes, it is pretty good, but it would never fool me." If, however, you catch him off his guard by suggesting, perhaps, "Did you ever see a diamond with a polished girdle?", then he will look at it with interest, remark on its fine color and "make," and never think of challenging its character.
The refractive index of the dense type of zircon is so high (1.92-1.98) that it lights up well over most of the surface of the brilliant when cut, as above indicated, and does not show markedly the weak dark center shown by white sapphire, white topaz, colorless quartz, colorless beryl, and paste, when seen from the side. Moreover, the luster of zircon is nearly adamantine, so the expert does not miss the cold metallic glitter as he would with any other white stone. The color dispersion, too, is so high (86% as great as in diamond) that the zircon has considerable "fire," and thus the casual handler is again deceived. A fine white zircon is really prettier than a poor diamond. It cannot compare, however, with a fine diamond. It would never do to let an expert see your zircon beside even a fair diamond. The zircon would look "sleepy." It is only when no direct comparison is possible, and when the expert is not suspicious, that a zircon can deceive him. Of course, the use of the scientific tests of the earlier lessons will, at once, detect the character of a whitened zircon. The hardness is but 7.5, the refraction so strongly double that the edges of the back facets appear double-lined when viewed through the table with a lens, and the specific gravity is 4.69. Double spots of light appear on the card when the sunlight-card test is applied. Hence, it is easy to detect zircon by any of these tests if there is reason to suspect that it has been substituted for diamond.
Corundum Gems. Rubies of streaky color are said to be improved by careful heating. Usually ruby undergoes a series of color changes on being heated, but returns through the same series in reverse order on being cooled, and finally resumes its original color. Strong heating will whiten some yellow sapphire. The author thus obtained a white sapphire from a crystal of light yellow material.
It is interesting to note that the corundum gems undergo marked change in color under the influence of radium. A regular series of changes is said to be produced in white sapphire by this means, the final color being yellow. This color may then be removed by heat and the series run through again. It is not stated that a fine red has ever been thus obtained. Perhaps Nature, by her slower methods, using the faint traces of radio-active material in the rocks, reddens the corundum of Burmah at her leisure, and finally arrives at the much sought "pigeon blood" color. It is said that the natives of India have a legend to the effect that the white sapphires of the mines are "ripening rubies," and that one day they will mature. Perhaps they are not far wrong.
Diamond. Diamonds of yellowish tint may be improved in color by the use of high-power radium. At present the latter is so rare and costly that there is no evidence of its commercial use for this purpose. Scientists have brought about the change to a light blue as an experiment. It is not yet known whether the change will be permanent. Perhaps here again Nature has anticipated man's discovery and made the fine bluish-violet Brazilian diamonds (which fluoresce to a deep violet under an arc light, and which shine for a few moments in the dark after exposure to light) by associating them for ages with radio-active material. Some of the African stones also have these characteristics.
Aside from the change in the color of diamond that may be brought about by means of radium, the mineral is extremely reluctant to alter its color. Many experimenters besides the author have tried in vain a host of expedients in the hope of finding some way to improve the color of diamond. About the only noticeable alteration that the author has been able to bring about was upon a brown diamond, the color of which was made somewhat lighter and more ashen by heating it in a current of hydrogen gas to a low red heat.