MAGNESITE.
Magnesite is pure carbonate of magnesia—that is, magnesia = 47.6, and carbonic acid 52.4 per cent. It usually occurs massive or fibrous, but sometimes granular, and its fine rhombohedral crystals are well known. Like dolomite, its prevailing tint is yellow or light brown, but, when very pure, is as white as snow. It is usually associated with serpentine rocks. In the kiln it is highly refractory, and behaves very much in the same way as lime—forming fusible compounds with silica and silicates. For the higher grades of basic bricks it is at this moment largely exploited in the few localities where it occurs in paying quantities. A few years since, investigation to determine the best basic refractory material was actively prosecuted in Germany, and magnesia, preheated at the highest white heat, was awarded the palm. Magnesite, when calcined, yields magnesia, which, however, still contains the impurities that might have been present in the raw material. An average percentage composition of the magnesite of commerce shows it to contain magnesia 45, carbonic acid 50, lime 1.5, protoxide of iron 1.6, the remainder being silica, alumina, and protoxide of manganese. The presence of silica in magnesite is an objection, because it is liable to have a fluxing effect at high temperatures.
Magnesite has been found in paying quantities in California, Styria, and recently in Greece. In Eubœa, in the last-mentioned country, the mineral occurs in lodes which, near Krimasi, are worked on two levels 30 to 40 feet from the top, and dipping at an angle of about 70 degrees. The general average of the lode gives 88 per cent. of carbonate of magnesia, and the substance is peculiarly suitable for the manufacture of basic bricks. A novelty with the raw material is that the proprietors sell either by guaranteed degree, or degree of analysis, the former being 95 per cent. of pure magnesia, whilst the latter often gives as much as 97.8 per cent. In inferior grades the principal increase is in the proportion of silica.