The Corpuscular Theory of Matter.

§ 79. We must now turn our attention to those recent views of the constitution of matter which originated to a great extent in the investigations of the passage of electricity through gases at very low pressures. It will be possible, however, on the present occasion, to give only the very briefest account of the subject; but a fuller treatment is rendered unnecessary by the fact that these and allied investigations and the theories to which they have given rise have been fully treated in several well-known works, by various authorities on the subject, which have appeared during the last few years.[95]


[95] We have found Prof. Harry Jones’ The Electrical Nature of Matter and Radioactivity (1906), Mr. Soddy’s Radioactivity (1904), and Mr. Whetham’s The Recent Development of Physical Science (1909) particularly interesting. Mention, of course, should also be made of the standard works of Prof. Sir J. J. Thomson and Prof. Rutherford.


When an electrical discharge is passed through a high-vacuum tube, invisible rays are emitted from the kathode, generally with the production of a greenish-yellow fluorescence where they strike the glass walls of the tube. These rays are called “kathode rays.” At one time they were regarded as waves in the ether, but it was shown by Sir William Crookes that they consist of small electrically charged particles, moving with a very high velocity. Sir J. J. Thomson was able to determine the ratio of the charge carried by these particles to their mass or inertia; he found that this ratio was constant whatever gas was contained in the vacuum tube, and much greater than the corresponding ratio for the hydrogen ion (electrically charged hydrogen atom) in electrolysis. By a skilful method, based on the fact discovered by Mr. C. T. R. Wilson, that charged particles can serve as nuclei for the condensation of water-vapour, he was further able to determine the value of the electrical charge carried by these particles, which was found to be constant also, and equal to the charge carried by univalent ions, e.g., hydrogen, in electrolysis. Hence, it follows that the mass of these kathode particles must be much smaller than the hydrogen ion, the actual ratio being about 1 : 1700. The first theory put forward by Sir J. J. Thomson in explanation of these facts, was that these kathode particles (“corpuscles” as he termed them) were electrically charged portions of matter, much smaller than the smallest atom; and since the same sort of corpuscle is obtained whatever gas is contained in the vacuum tube, it is reasonable to conclude that the corpuscle is the common unit of all matter.