The Results.
| At. Wt. Cd. | At. Wt. Cd. | At. Wt. Cd. | At. Wt. Cd. | |||
|---|---|---|---|---|---|---|
| (O=16) | (O=16) | (O=15.96) | (O=15.96) | |||
| (C=12.001) | (C=12.003) | (C=11.971) | (C=11.973) | |||
| CdC₂O₄ | CdO | |||||
| I | 1.53937 | .98526 | 112.026 | 112.033 | 111.746 | 111.753 |
| II | 1.77483 | 1.13582 | 111.981 | 111.988 | 111.701 | 111.708 |
| III | 1.70211 | 1.08949 | 112.049 | 112.056 | 111.769 | 111.776 |
| IV | 1.70238 | 1.08967 | 112.051 | 112.058 | 111.771 | 111.778 |
| V | 1.74447 | 1.11651 | 112.019 | 112.026 | 111.739 | 111.746 |
| Mean, | 112.025 | 112.032 | 111.745 | 111.752 | ||
| Maximum, | 112.051 | 112.058 | 111.771 | 111.778 | ||
| Minimum, | 111.981 | 111.988 | 111.701 | 111.708 | ||
| Difference, | .070 | .070 | .070 | .070 | ||
The values assigned to carbon in the last two columns were found thus—
| When | O = 16, | C = 12.001, | when | O = 15.96, | C = 11.971. |
| ” | O = 16, | C = 12.003, | ” | O = 15.96, | C = 11.973. |
Calculating the atomic weight directly from all the oxalate used and oxide found it would give:
| At. Wt. Cd. | At. Wt. Cd. | At. Wt. Cd. | At. Wt. Cd. |
|---|---|---|---|
| (O=16) | (O=16) | (O=15.96) | (O=15.96) |
| (C=12.001) | (C=12.003) | (C=11.971) | (C=11.973) |
| 112.025. | 112.032. | 111.745. | 111.752. |
There seems about equal evidence for the two values assigned to carbon when oxygen = 16. The value of cadmium as given by this method is therefore 112.025 or 112.032.
As will be seen at a glance this figure agrees much more closely with that of Lenssen than with that of Partridge.
| Lenssen | Partridge | My work |
|---|---|---|
| 112.043. | 111.816. | 112.025 or |
| 112.032. |
It also agrees fairly well with the figure 112.0706 which I obtained by the first method described.