The Results.

The following table contains the results of ten successive determinations.

At. Wt. Cd. At. Wt. Cd.
Wt. of Cd. Wt. of CdO. (O = 16)(O = 15.96)
I 1.778912.03288112.070111.790
II 1.824922.08544112.078111.798
III 1.746881.99626112.078111.798
IV 1.570001.79418112.053111.773
V 1.984812.26820112.061111.781
VI 2.272972.59751112.059111.779
VII 1.756952.00775112.086111.806
VIII 1.700281.94305112.059111.779
IX 1.922372.19679112.083111.803
X 1.920812.19502112.078111.798
Mean, 112.0705.111.7905.
Maximum, 112.086.111.806.
Minimum, 112.053.111.773.
Difference,    .033.   .033.

Calculating the atomic weight of cadmium from the total amount of metal used and oxide found, we have:

At. Wt. of Cd.At. Wt. of Cd.
(O = 16)(O = 15.96)
112.0706.111.7904.

These results agree more closely with those of von Hauer and Lenssen than with those of any other experimenter. The following table gives a comparison of the work of these investigators with that herein described:

von Hauer.Lenssen.Work here described.
9 determinations.3 determinations.10 determinations.
(O = 16)(O = 16)(O = 16)
Mean 111.940112.067112.0705
Max. 112.121112.304112.086
Min. 111.796111.911112.053
Diff.   .325  .393  .033

A difference of three or four tenths of a unit between the different results of a series leaves considerable doubt as to the accuracy of the method employed and to the value obtained.

The figure selected by Ostwald,[5] as most probable for the atomic weight of cadmium is 112.08. This is the mean of the results on von Hauer and Huntington. My own work leads me to believe that this number is very close to the true value when oxygen is taken as 16.