The Nature of Electricity.
The earlier conceptions of a one or two-fluid explanation of the phenomena of electricity appear now in a new light. We are led to think of a neutral atom as consisting of one mass charged with positive electricity together with as many electrons negatively charged as are sufficient to neutralize the positive. If the atom loses one, two or three electrons, it becomes positive with a charge of one, two or three elementary quanta of electricity, or for the sake of simplicity and brevity we say that the atom has one, two or three “charges.” If, on the other hand, it takes up one, two or three extra electrons it has one, two or three negative charges. [Fig. 18] can give help in understanding these ideas, but it must not be thought that the electrons are arranged in the way indicated. The substances, which appear as electropositive in electrolysis—i.e. hydrogen and metals—should then be such that their atoms easily lose one or more electrons, while the electronegative elements should, on the other hand, easily take up extra electrons. Elements should be monovalent or divalent according as their atoms are apt to lose or to take up one or two electrons. From investigations with the vacuum tube it appears, however, that the atoms of the same element can in this respect behave in more ways than would be expected from electrolysis or chemical valence.
Fig. 18.—Provisional representation (according to the electron theory) of
A, a neutral atom; B, the same atom with two positive charges (a divalent positive ion)
and C, the same atom with two negative charges (a divalent negative ion).
When an electric current passes through a metal wire, it must be assumed that the atoms of the metal remain in place, while the electrical forces carry the electrons in a direction opposite to that which usually is considered as the direction of the current ([cf. p.70]). The motion of the electrons must not be supposed to proceed without hindrance, but rather as the result of a complicated interplay, by no means completely understood, whereby the electrons are freed from and caught by the atoms and travel backwards and forwards, in such a way that through every section of the metal wire a surplus of electrons is steadily passing in the direction opposite to the so-called direction of the current. The number of surplus electrons which in every second passes through a section of the thin metal wire in an ordinary twenty-five candle incandescent light, at 220 volts, amounts to about one trillion (10¹⁸), or 1000 million (10⁹) in 0·000,000,001 of a second. If the metal conducting wire ends in the cathode of a vacuum tube, the electrons carried through the wire pass freely into the tube as cathode rays from the cathode.
This motion of electricity agrees best with the one-fluid theory, since the electrons, which here alone accomplish the passage of the electricity, may be considered as the fundamental parts of electricity. In this respect the choice of the terms positive and negative is very unfortunate, since a body with a negative charge actually has a surplus of electrons. Moreover, the electrons really have mass; but since the mass of a single electron is only ¹/₁₈₃₅ that of the atom of the lightest element, hydrogen, and since in an electrified body which can be weighed by scale there is always but an infinitesimal number of charged atoms, it is easy to understand that, formerly, electricity seemed to be without weight.
In electrolysis, where the motion of electricity is accomplished by positive and negative ions, we have a closer connection with the two-fluid theory. In motions of electricity through air the situation suggests both the one-fluid and the two-fluid theories, since the passage of electricity is sometimes carried on exclusively by the electrons, and sometimes partly by them and partly by larger positive and negative ions, i.e., atoms or molecules with positive and negative charges.