EXTRACTS FROM THE AMERICAN JOURNAL OF SCIENCE.
Notice of "A View of the Lead-Mines of Missouri, including some Observations on the Mineralogy, Geology, Geography, Antiquities, Soil, Climate, Population, and Productions, of Missouri and Arkansas, and other sections of the Western Country; accompanied by three Engravings. By Henry R. Schoolcraft, Corresponding Member of the Lyceum of Natural History of New York." 1821.
As this work has been more than a year before the American public, and is already well known, it may seem superfluous to make any remarks upon it at so late a period. It was our purpose to have given it an early notice, but circumstances which could not be controlled, prevented. Still, as it is devoted to subjects which form a prominent object in this Journal, and is, as far as we are informed, the only elaborate and detailed account of a mining district in the United States, we are not disposed to remain silent, especially as the discharge of the duty is not likely to be painful, either to ourselves or to the author. Reviews in form, although within the plan of this Journal, do not constitute one of its most leading objects, and we do not hold ourselves responsible for analyses or even for notices of new American books, unless they appear particularly interesting or important, or hold a very intimate connexion with the great design of our work.
We have already intimated that we regard Mr. Schoolcraft's work in this light. We take it for granted that the statements of facts made by this author, are both faithful and accurate; the information which we have incidentally derived from other sources, certainly countenances this impression, but the whole amount of it is small, compared with the details contained in the present volume.
Mr. Schoolcraft's opportunities for observation were extensive, particularly in relation to the mines of lead in the Missouri region. Among those mines he spent a year. "I have made (says he) a personal examination of every mine of consequence, with a view to ascertain its general character and value and its peculiarities. I have travelled on foot over the whole mine country, exploring its minerals, its geological structure, its geographical position, soil, climate, productions, towns, streams, settlements, and whatever else appeared to me to be necessary to describe, explain and illustrate the subject before me."
Mr. Schoolcraft appears to have made good use of the advantages which he enjoyed, and his countrymen are indebted to him for a great amount of valuable information. He appears also to have studied the observations of preceding writers, and, with their works before him, it was in his power to correct errors and to supply deficiencies.
He has prefixed an historical sketch which we presume will be acceptable to every reader. The French, as is well known, were the original discoverers and settlers of the Missouri, and Illinois regions, which were embraced in their vast scheme of forming a chain of posts and settlements from the mouth of the St. Lawrence, to that of the Mississippi. They did not occupy the country of the Missouri and Illinois till more than a century after the settlement of Quebec, and about a century before the present period. At that time, (1720,) the lead mines were discovered by Philip Francis Renault, and M. La Motte, and by them they were wrought, although they and the adventurers under them were disappointed in their expectations of finding gold and silver.
At the end of about half a century, the country passed into the hands of the Spaniards, and under their dominion, probably about forty years since, the principal mine was discovered by a man of the name of Burton, and from him it has derived the name of Mine à Burton.
It appears that the processes of mining under the Spaniards were very imperfect, as they obtained only fifty per cent. of lead from the ore, threw away the lead ashes, and did not attempt any manufactures of shot or any other articles. They employed only the open log furnace.
In 1797, Moses Austin, Esq., a native of Connecticut, who had been occupied with lead mines in Wythe county, in Virginia, obtained from the Spanish government, a grant of a league square in the mining district in consideration of his introducing a reverberatory furnace. He sunk the first regular shaft—the mining having, till that time, been prosecuted solely by open digging, in the manner of quarries. Mr. Austin also introduced the manufacture of shot, and that of sheet lead soon followed. About the same time several other American families collected at the mines, and infused new spirit and enterprise into the mining operations, so that they were carried on with considerable vigour at the time when (in 1803) the country was transferred to the United States. Mr. Schoolcraft, from whom these facts are taken, remarks, that since 1804, the number of mines has been astonishingly multiplied—population has flowed rapidly in—the processes on the ore have been much improved—better furnaces have been constructed, and "every season is adding to the number of the mines." "Every day is developing to us the vast resources of this country, particularly in lead," and the author expresses his opinion that "the mines of Missouri are paralleled by no other mineral district in the world."
From the specimens which we possess of this ore, and from the documents produced by the author respecting the produce of the mines, we believe his opinion is correct, especially if we consider the fact that "the earth has not yet been penetrated over eighty feet;" "we know not what may be found in the lower strata." "There is reason to believe that the main bodies of ore have not been hit upon, that they lie deeper, and that we have thus far been only engaged upon the spurs and detached masses."
Mr. Schoolcraft informs us that although the mining business is much improved, there is still a great deficiency both of capital and of skill—there is in the whole district but one regular hearth furnace for smelting, and that not the best;—among forty mines, there are only four or five regular shafts—there is among all the mines, no engine of any description for raising water, and some of the richest mines with the best prospects in view, have been in consequence abandoned. Yet, under all these disadvantages, the annual produce of the mines is estimated at three millions of pounds of lead.
The author suggests the expediency of establishing a school of mines and minerals in the midst of the mines themselves; this would, without doubt, be a very proper measure, but in the meantime, skilful practical miners, and captains of mines, such as are found in every mining district in Europe, would supply the immediate demands of the country.
The mining district, formerly called the lead mines of Louisiana, is situate between the 37th and the 38th degree of north latitude, and between the 89th and 92d degree of west longitude, covers three thousand one hundred and fifty square miles—it is from seventy to one hundred miles long by forty or forty-five, extending in width from the Mississippi south-west to the Fourche à Courtois, and in length from the head waters of St. Francis northerly to the Maramec.
Lead ore is found in almost every part of this district. Mr. Schoolcraft says, "the general aspect of the country is sterile, though not mountainous: the lands lie rolling, like a body of water in gentle agitation. In some places the hills rise into abrupt cliffs, where the great rock formations of the country may be seen; in others, they run into level plains—a kind of highland prairie."
"The soil is a reddish colored clay, stiff and hard, and full of fragments of flinty stones, quartz and gravel; this extends to the depth of from ten to twenty feet, and is bottomed on limestone rock. It is so compact in some places, as almost to resist the pick-axe; in others it seems to partake of marl, is less gravelly, and readily penetrated. The country is particularly characterized by quartz, which is strewed in detached pieces over the surface of the ground, and is also found imbedded in the soil at all depths. This is here called blossom of lead. Iron ores and pyrites are also scattered over the surface of the ground, and occasionally lead ore. Such is the general character of the mineral hills, which are invariably covered by a stinted growth of oaks."
Walnut is also found on the hills, and there is a ridge of yellow pine, not more than six or eight miles wide, running nearly south-east and north-west, but it is nearly or quite destitute of lead—the mines lie generally east of it. In summer the flinty aspect of the country is veiled by a luxuriant growth of grass, which gives it a very pleasing and picturesque appearance.
The valleys have a rich alluvial soil, well fitted for cultivation; but our limits will not allow us to mention the vegetable productions of the country. This region is well irrigated, and very healthy, being possessed of a fine climate. Mr. Schoolcraft remarks, that during a residence of ten months he never heard of a death; the country is free from the fevers which infest some of the neighboring regions. It seems, however, that the animals are visited by what is called the mine sickness. "Cows and horses are frequently seen to die without any apparent cause. Cats and dogs are taken with violent fits, which never fail, in a short time, to kill them." It is said that the inhabitants impute these affections to the sulphur exhaled in smelting the lead, as the cattle are often seen licking about the old furnaces. But sulphur is not poisonous either to men or animals. The author imputes it to the sulphate of barytes, with which the district abounds, which he states is a "poison to animals."
The carbonate of barytes is eminently poisonous; but we have never heard that the sulphate is so. May not the licking around the furnaces expose the cattle to receive lead in some of its forms, minutely divided? or, if it be not active in the metallic state, both the oxides and the carbonate, which must of course exist around the furnaces, would be highly active and poisonous. Is it not possible, also, that some of the natural waters of the country may, in consequence of saline or acid impregnations, dissolve some of the lead, and thus obtain saturnine qualities? We must allow, however, that we are not acquainted with the existence of any natural water thus impregnated.
Among the mineral productions of this region, certainly not the least remarkable mentioned by Mr. Schoolcraft, is the Iron Mountain, where the ore is piled in such enormous masses as to constitute the entire southern extremity of a lofty ridge, which is elevated five or six hundred feet above the plain: the ore is the micaceous exide, and is said to yield good malleable iron.
There is another body of iron ore five miles west of the iron mountain, scarcely inferior to that mentioned above, and it appears that several other beds exist in the same vicinity.
Zinc is abundant, but as the ore is the sulphuret, it is not very valuable. It is not mentioned that calamine, which is the useful ore of zinc, has been found.
As to the geological nature of the country, in which the lead mines are situate, he informs us that "Bellevue abounds in granite;" that the only vein of granite rock in the mine country (as far as he had opportunity to observe) passes across the south-western end of Madison county—runs into Bellevue—is four or five miles wide, and twenty or thirty miles in a direction from south-east to north-west.
The granite is spoken of in another place, (p. 170,) as being a geological phenomenon, as containing imbedded in it or lying upon its surface, gneiss, green stone, porphyry, iron ores, &c.; it is spoken of as a red granite, containing very little mica, and as being used for millstones. It is mentioned as the "only mass of granite known to exist between the primitive ranges of the Alleghany and Rocky mountains," and as being surrounded on all sides, and to an almost immeasurable extent, with secondary limestone.
Again, (p. 193,) the granite is cited as the "old red granite in mountain masses, with some veins of green stone, green stone porphyry, and gneiss;" it is said to terminate in very rough and broken high lands. At page 213, it is mentioned, still again, as giving origin to the river St. Francis, whose "springs gush out among these stupendous piles of red granite." Besides the ores of iron, lead and zinc, "quartz, feldspar, shorl, mica, and graphite are among the minerals furnished by that region," and "green stone, gneiss, and green stone porphyry, are among the larger masses of rock." The green stone, it seems, "is found in large isolated fragments, lying promiscuously among the fragments of granite which have tumbled down from the lofty cliffs above, and is rendered porphyritic by crystals of green and flesh-colored feldspar."
We have no right to doubt that the rock described is granite, as the principal features delineated, correspond with that supposition. As it is described as being solitary, the only granite between the Alleghanies and the Rocky mountains, we are led to ask, is it a portion of the nucleus of our globe, covered on every side, for many hundred miles, with secondary rocks, and here heaving its head through the superincumbent strata, and standing alone? But what are we to conclude of the limestone? We should have liked especially to have had the relations of this limestone with that remarkable granite region pointed out. Does this latter repose on the granite, where it dips obliquely under, as it probably does, in order to find its way beneath the other rocks, and to vindicate its claim to a fundamental position? But, perhaps we are asking more than is reasonable, for, it may be that there are no such sections in the strata as would expose all these facts to view, and enable the observer to decide.
These hints we have dropped, not, we trust, from a captious disposition, but because we have found a real difficulty in conceiving clearly of the geological nature of this limestone, which, it seems, is the basis of the lead-mine country, and therefore it is very important that its characters should be indubitably fixed. We have not been so fortunate as to see Mr. Schoolcraft's specimens; possibly a view of them would have rendered the preceding remarks, in part at least, unnecessary.
Leaving the geological features of the lead-mine district, we proceed to cite some interesting and important facts from Mr. Schoolcraft's work:—"The soil," he remarks, "is a reddish colored clay, stiff and hard, and full of fragments of flinty stone, quartz and gravel; this extends to the depth of from ten to twenty feet, and is bottomed on limestone rock. It is so compact in some places as almost to resist the pick-axe; in others it seems to partake of marl, is less gravelly, and readily penetrated. The country is particularly characterized by quartz, which is strewed in detached pieces over the surface of the ground, and is also found imbedded in the soil at all depths. This is here called blossom of lead. Iron ores and pyrites are also scattered over the surface of the ground, and occasionally lead ore. The mineral productions of the country, in addition to lead, are zinc, iron, ochre, red chalk, saltpetre, sulphur, alum and salt."
The ore (the author remarks) is the lead glance, galena, or sulphuret of lead. It is very rich and beautiful, and specimens in our possession fully confirm Mr. Schoolcraft's account; they have a very broad and perfectly foliated fracture, and a high degree of metallic lustre; they break in cubical fragments, and the minutest portions still retain this form.
We have already observed that large fragments are found loose in the earth: they sometimes weigh four or five pounds; we have such specimens from these mines; they are of a cubical form, and are surrounded, except where they have been broken, by an earthy incrustation.
It is observed that the marly earth thrown out from the pits, enriches the ground, so that in a few years it is covered with a very rank growth of trees, vines, &c., and this is a regular characteristic of old diggings. Innumerable portions of radiated quartz, and sharp fragments of flinty stones are mixed with the clay, and form the first stratum of about fourteen inches. The next is of a red clay, and is four or five feet thick, and less mixed with similar siliceous substances. Then comes a layer of gravel and rounded siliceous pebbles, about one foot thick, containing small portions of lead ore. The thickness of the bed of ore is generally a foot; and the lumps of ore appear to have been rounded by attrition, like common gravel. "This is the character of what is called the gravel ore, and no spars are found accompanying it. The greatest proportion of lead ore is, however, found imbedded in, and accompanied by, the sulphate of barytes, resting in a thick stratum of marly clay, bottomed on limestone rock." They invariably arrive at the rock at the depth of from fifteen to twenty, or sometimes thirty feet; a new process by boring and blasting is now necessary, and most diggers abandon their pits rather than prosecute them at this expense. If, however, as there can be little doubt, the limestone is the real matrix of the lead ore, the time will come when the present diggings will be considered as merely superficial beginnings, and the work will be resumed where hitherto it has been abandoned. It seems that the almost invariable practice of the miners is, to persevere till they strike the rock, and then to go and dig elsewhere; they cannot, if disposed, prosecute the business by levels or galleries, for they are not permitted to carry on their mining except immediately under the surface that is covered by their respective leases, or by twelve feet square, which, if unoccupied, an adventurer may cover by occupancy. Among the substances accompanying the lead, blende and the sulphate of barytes are said to be very abundant; the latter in specimens which we have, is particularly brilliant and white;[24] the quartz is often prettily crystallized, and is so invariable a concomitant of the ore, that the miners, as we have before remarked, give it the meaning appellation of mineral blossom.
A curious fact is mentioned by Mr. Schoolcraft, respecting the Elliott's mines. "During the remarkable earthquakes of 1812, a fine spring of water at the mouth of the mines suddenly became warm and foul, and in a few days dried up entirely, and no water has run there since." "Illuminations in the atmosphere are frequently observed in this vicinity on the approach of night."[25]
It seems there is a considerable quantity of a greyish white sublimate collected at the log hearth furnaces, and rejected by the workmen upon the supposition that it is sulphur and arsenic; but Mr. Schoolcraft, by unquestionable experiments, ascertained that it was lead, as would appear, in the form of a carbonated oxide. A considerable loss is in this manner sustained, and in a more advanced state of the metallurgic operations of these mines, the author's valuable suggestions will not be neglected. There is one mine (M'Kain's) where the ore is of the steel-grained variety—it is said to yield less lead, and is inferred to contain more silver than the common ores; we are aware that this is the common impression, but our own experiments on different varieties of lead ore would induce us to think that it cannot be relied upon. We have examined fine steel-grained ore which contained very little silver; in one specimen only one five-thousandth part, and in another, and that a foliated specimen, we found three and a half per cent, of silver.
The methods of digging for the ore are sufficiently simple. "A pick-axe and shovel are the only tools used for removing the earth, and the drill, hammer and priming rod are added when it is necessary to blast." The process is carried on as in digging a common well.
We must refer our readers to the book itself for a clear account of the furnaces and furnace operations, employed for smelting the lead; it will be the more intelligible, as it is accompanied by two good plates containing views and sections of the furnaces. A circumstance which appears very extraordinary is, that the furnaces are most commonly built of limestone, which is of course calcined, and brought to the condition of quicklime by a few blasts, and then it crumbles and the furnaces must be rebuilt.
The ore yields at first fifty per cent., and then the ashes give fifteen per cent, more—sixty-five[26] in the whole.[27]
Custom, says the author, has established a number of laws among the miners, with regard to digging, which have a tendency to prevent disputes. Whenever a discovery is made, the person claiming it is entitled to claim the ground for twenty-five feet, in every direction from his pit, giving him fifty feet square. Other diggers are each entitled to twelve feet square, which is just enough to sink a pit, and afford room for throwing out the earth. Each one measures and stakes off his ground; and though he should not begin his work for several days afterwards, no person will intrude upon it. On this spot he digs down, but is not allowed to run drifts horizontally, so as to break into or undermine the pits of others. If appearances are unpromising, or he strikes the rock, and chooses to abandon his pit, he can go on any unoccupied ground, and, observing the same precautions, begin anew. In such a case, the abandoned pit may be occupied by any other person; and sometimes large bodies of ore are found by the second occupant, by a little work, which would have richly rewarded the labors of the first had he persevered.
Mr. Schoolcraft, from various particulars, infers that the average annual produce of the Missouri lead mines, as mentioned before, is three million pounds per annum, and the lead was worth in 1819, at the mines, four cents per pound. For the last three years, up to 1819 inclusive, the produce of the mines was estimated at three million seven hundred twenty-six thousand six hundred and sixty-six pounds per annum of pig lead, which the author supposes to be not more than one half what the mines are capable of yielding.
The number of miners is between eleven and twelve hundred, and the number of hands employed in labor at different mines is from twenty to two hundred and forty, including in both cases persons of all descriptions.
Many miscellaneous topics connected with the general subject of his work, are introduced by Mr. Schoolcraft, such as the sections relating to the manufactures, and uses of lead, &c., but it is not our object to advert to these topics.
Among the miscellaneous mineral productions of the western regions, there are some that are interesting; and it will be seen from the author's table of minerals, that the list is various. There are several caverns which produce nitrate of potash by the usual treatment; and Ashley's Cave, about eighty miles from Potosi, is said to be one of stupendous size, and to "afford native nitrate of potash in beautiful white crystals."
The novaculite is mentioned as occurring on Washita, as described by Mr. Bringier in the present number.
Steatite exists in abundance at the falls of St. Anthony, on the Mississippi, and is used by the Indians for pipes.
The fluate of lime, near Shawneetown, was described in the first volume of this journal.
Among other minerals, Mr. Schoolcraft mentions chalcedony in several varieties, earthy oxide of lead, native copper, alum, manganese, opalized and agatized wood, opal, jasper, coal, gypsum, native epsom salts, pumice stone, agate, onyx, burr millstone, native iron, &c.; for the localities and descriptions of which, we must refer to the book itself.
Those facts of Mr. Schoolcraft's volume which relate to statistical and political topics, do not come within the plan of these remarks.
During our cursory notice of this work, we have cited a number of the most prominent facts which it contains, both because they are in themselves important, and because we were willing to call the attention of our readers both to them, and to the volume in which they are contained. Both are, in our view, entitled to great respect; and we confess ourselves very much indebted to Mr. Schoolcraft for a great mass of valuable information, which, in a connected form, is, we believe, nowhere else to be found. His statements (as regards the most valuable part) are drawn from his own research and observations, and have evidently been the result of much effort, and of no small share of fatigue and personal privation. We trust that so valuable a work will not stop with a single edition, and perhaps we might venture to suggest to the author, that in a second, he might advantageously condense into one view some facts which are several times repeated in different parts of the volume—such as those respecting the granite and its connected rocks, the lead ore and its associated minerals, &c.
We consider the present work as an acquisition to our means of information respecting our mineral resources, and believe that it must be a regular volume of reference for all those who are interested in the investigation of these subjects.
FOOTNOTES:
[24] It is mentioned by the author, as a chemical test or reagent: it may, by decomposing it by ignition with charcoal, or with an alkaline carbonate, be made to afford its earth for the preparation of barytic tests, but we are not aware that it is itself ever used as a test.
[25] They are attributed by the author to phosphorus. Is it supposed to be in the form of phosphuretted hydrogen? May not these be electrical phenomena?
[26] According to Dr. Meade, the Missouri ore affords only a trace of silver. (See Bruce's Minl. Journal, vol. 1, p. 10.)
[27] Mr. Schoolcraft thinks it may yield seventy per cent.—it gave him by analysis eighty-two per cent.