TRICHROMATIC COLOUR SCREENS.
Table VIII contains the colour measurements of five sets of screens for trichromatic colour work which have come from time to time under the writer’s notice.
The measurements are the tintometrical colour units required to match the screens under daylight conditions, and are classified under the theoretically accepted terms of Red, Green and Violet.
TABLE VIII.
| Set. | Red Screens. | Green Screens. | Violet Screens. | ||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|
| No. | Red. | Or. | Vi. | Light. | Yel. | Green. | Or. | Light. | Blue. | Green. | Black. |
| 1 | 119·0 | — | — | 1·6 | 27·0 | 36·0 | — | 9·0 | 32·0 | 1·4 | 6·6 |
| 2 | 24·2 | +·8 | — | — | 8·9 | — | ·1 | — | 13·0 | — | 3·1 |
| 3 | 26·4 | — | ·8 | — | 7·5 | — | 1·4 | — | 16·6 | — | 3·2 |
| 4 | 22·6 | — | — | — | 7·6 | — | 1·4 | — | 15·3 | — | 3·1 |
| 5 | 21·0 | — | 9·0 | — | 28·0 | 14·0 | — | — | 28·0 | — | 2·8 |
The Red screens are all practically pure except No. 5, which transmits also 30 per cent. Violet. No. 1 is distinguished by its greater colour depth and purity, the degree of which latter is recorded at 1·6 light units brighter than standard.
In the Green division, only Nos. 1 and 5 transmit any green, No. 1 transmitting also 42·8 per cent. yellow and being 9·0 units brighter than standards; No. 4 transmits 66·6 per cent. yellow to 33·3 per cent. green; Nos. 2, 3 and 4 are all yellows tinged with orange.
In the Violet division, Nos. 2, 3, 4 and 5 are all pure blues; No. 1 is tinged with green.
Appendix I
COLOUR EDUCATION
The time has passed when it might have been considered necessary to preface a handbook on the teaching of colour by arguments to prove that it is a legitimate subject of instruction in schools, but it has not hitherto been sufficiently recognized that the early stages of such instruction must be on sound lines and that nothing must be taught which will afterwards have to be unlearned.
Apart from the pleasure its sensations give to all properly constituted persons, the study of colour has an intellectual value in common with other branches of science. It strengthens the judgment by constantly requiring thought and precision in definition, it also develops the faculty of colour perception even to the point of curing some forms of colour blindness. In addition to this, it forms a necessary part of the instruction in all schools in which drawing is properly taught by methods which demand from the pupils faithful representations of the appearances of actual objects in colour as they are seen.
In the past the systematic study of colour has been more or less neglected from two principal causes: first, the want of a comprehensive scheme of colour nomenclature capable of describing all colours in terms precise enough for general understanding and record; and, second, the absence of any reliable means of reproducing any specific colour if lost or faded. Both these conditions may now be secured by the use of the standardized coloured glasses supplied with the Colour Educator, and this work is intended to bring the subject before teachers in such a way as to make each point perfectly easy of demonstration to a class in a systematic manner.
To-day the value and importance of a keen perception of colour and of an apparatus furnishing definite colour standards, though perhaps not much appreciated by the general public, are widely recognized in the industrial and scientific world; and it is evident that in these days of keen commercial competition between nations we cannot afford to neglect any means which will enable us to maintain present industries and to develop new ones.
General Remarks.—It is not advisable to introduce colour theories to pupils before they know the names of the different colours, but, as the glasses used in the apparatus are graded for colour-depth according to a set of scales now generally accepted as of standard value, a short description of the derivation of the colour names will be of service when the pupils are sufficiently advanced.
The names of the six spectrum colours, Red, Orange, Yellow, Green, Blue, and Violet, are accepted by common consent as describing the principal hues into which a beam of white light can be resolved by a diffraction grating or by prismatic refraction. They are also the colours distinguishable in objects of everyday life, and the following Educational Method is based on the fact that they can be separated at will from ordinary daylight. Therefore the first educational step is to associate these six colour rays with their respective names, the pupils being made to understand that there are many degrees of depth in each colour.
The Applications of Colour to the Work of Everyday Life are so universal that a complete list is almost impossible, though some of the most important are mentioned below. In a general way the visual characteristics of every visible object are determined by contrasts of light and colour, outline itself being governed by differences of light intensity.
In Nature, colour is practically universal. There are few objects perfectly white. Most of them have colour of greater or less complexity; even snow under a cloudless sky has a blue tint which is measurable against such white objects as pure lime sulphate, zinc white, etc., the blue tint being manifestly reflected from the cloudless sky, as it disappears under a cloudy overcast.
Some of the Scientific Applications of Colour.—It associates colour sensations with definite names and values; discovers and classifies cases of colour-blindness, and is a preparation for the physical study of light. It is also essential for studying the physiological structure of the organs of vision, for disclosing abnormal conditions of the blood, and for measuring the colour of the hair and skin for the anthropological classification of races. It is used in general laboratory work for analytical and original investigation; and it furnishes standards of value for the petroleum industry, the International Tanning Association, the inter-States Cotton Seed Oil Association, etc. It is also one of the principal factors in all artistic industries; for, besides having an important educational value in questions of harmony, contrast, and taste, it is of direct commercial value in such industries as dyeing, calico printing, all woollen industries, wall-paper printing, paint making, house decoration, etc.
General Instructions for Using the Apparatus.—The apparatus consists of a frame having six little windows, fitted with sliding shutters, and a tray containing eighteen standardized glasses.
The frame must be placed on a table or stand facing the children, with a window or some other source of diffused white light behind it. Care must be taken not to have a coloured background of any kind.
The glasses are in three colours, Red, Yellow, and Blue, of different depths. The depth of colour is marked in figures on each glass, and corresponding numbers in the three colours are of equal intensity. It is of importance that the six spectrum colour terms should be the only ones used in the preliminary stages. The first step in colour teaching must be to develop and train the perceptive faculties of the children so as to enable them to express in words the colour sensations which are excited. For this purpose it is necessary to begin by demonstrating that the six spectrum colours Red, Orange, Yellow, Green, Blue, and Violet, are derived from white light.
Red, Yellow, and Blue should first be dealt with, and for practical work each pupil should be supplied with three water-colour pigments closely corresponding in hue to the standardized glasses, viz., Crimson Lake, Lemon Yellow, and Cobalt Blue; also with a piece of white paper ruled into six small rectangular spaces corresponding to the little windows of the apparatus.
As each colour is demonstrated by means of the glass in the apparatus, each pupil should paint the corresponding pigment in its proper place on the paper.
The little shutters being placed in all the six little windows, remove the top left-hand shutter and insert a deep Red glass, thus showing
Red.—The pupils will name this and then paint the corresponding colour on their papers.
Next, remove the shutter below the first one, and insert a Yellow glass of the same numerical value as the Red one, thus showing
Yellow.—The pupils will name this and then paint the corresponding colour on their papers.
Now remove the shutter next below and insert a Blue glass of the same numerical value as the Red and Yellow ones, thus showing
Blue.—The pupils will name this and then paint the corresponding colour on their papers.
There are now exposed to view the three colours which are by artists commonly called primaries, but it will be found convenient to term Red, Yellow, and Blue the Dominant colours of this system.
The second step is to show how the three secondary or subordinate colours are derived or developed.
Remove the top right-hand shutter and insert a deep Red and a deep Yellow glass of equal depth, showing the pupils that these two colours combined in equal proportions develop
Orange.—The pupils will name this, and will then mix their Red and Yellow pigments to obtain a similar Orange which will be painted in its proper place on their papers.
Now remove the shutter next below and insert a deep Yellow and a deep Blue glass of equal depth, showing the pupils that these two colours combined in equal proportions develop
Green.—The pupils will name this, and will then mix their Blue and Yellow pigments to obtain a similar Green which will be painted in its proper place on their papers.
Remove the last right-hand shutter and insert a deep Red and a deep Blue glass of equal depth, showing that these two colours combined in equal proportions develop
Violet.—The pupils will name this, and mix their Blue and Red pigments to obtain a similar Violet, which will also be painted in its proper place on their papers.
Now are exposed to view on the left-hand side the three primary or dominant colours, and on the right-hand side the three secondary or subordinate colours, and the whole frame is filled with the six spectrum colours in equal colour depth. Corresponding to the colours in the frame, each pupil’s paper should show a similar arrangement of colours, and the pupils can be taught their spectrum order by reading them in rows horizontally—Red, Orange, Yellow, Green, Blue, and Violet.
The teacher should now take out the coloured glasses and replace the shutters, except the two top windows, one of which is left open to show white light, and the other filled with three equally deep glasses in Red, Yellow, and Blue, showing either black or neutral grey, and demonstrating the total or partial absorption of light according to their higher or lower numerical unit value. It is of the utmost importance to bear in mind that the glasses are graded for diffused daylight, and that all artificial lights are more or less coloured and would give a different effect. The same remark applies to light taken direct from coloured objects.
In this set the six windows are in one horizontal line, and should be uncovered in the following order:
{ No. 1 Window for Red.
Dominants { No. 3 Window for Yellow.
{ No. 5 Window for Blue.
{ No. 2 Window for Orange.
Subordinates { No. 4 Window for Green.
{ No. 6 Window for Violet.
One advantage in this method is that when all the colours are in they are arranged in their spectrum order.
Complex Colours.—We have demonstrated that single standard glasses develop the three Dominant colours, Red, Yellow, and Blue, and that pairs of equal standard glasses develop the three Subordinate colours, Orange, Green, and Violet. In order to produce complex colours two standard glasses of unequal value must be used. The degree of inequality does not alter the spectroscopic names of complex colours, variation in proportions being only a statement of degree.
| Complex Name. | High value. Lower. | ||
| To develop a | Red-Orange | insert a | Red and Yellow. |
| " | Yellow-Orange | " | Yellow and Red. |
| " | Yellow-Green | " | Yellow and Blue. |
| " | Blue-Green | " | Blue and Yellow. |
| " | Blue-Violet | " | Blue and Red. |
| " | Red-Violet | " | Red and Blue. |
A reference to the circles, 7, 8, and 9, on the cards supplied with the apparatus will show that all complex colours are members of the same triad group, and experiments have shown that the six combinations above are the only ones distinguishable in Nature, subject, however, to unlimited variations in brightness or dullness. It remains to be shown how these variations are effected.
Variations in brightness are produced by inserting with the two glasses forming a complex colour the third spectrum colour, always bearing in mind that it must be less in value than either of the other two. The addition of the third colour has a dulling or saddening effect, the degree of which is determined by the numerical value of the third colour. The colour produced by the addition of the third colour may be termed a saddened or dingy colour, the appearance being that of a brighter colour seen in shadow.
Reviewing the foregoing, it is demonstrated that primary or dominant colours are transmitted by a single coloured standard glass; the secondary or subordinate colours are transmitted by two equal standard glasses of different colours; the complex colours by two unequal standard glasses of different colours. Saddened pure colours are developed either by one coloured standard glass combined with two equal standard glasses of different colours and lesser value or by two equal standard glasses of different colours and a third of lesser value. Saddened complex colours by three unequal standard glasses of different colours. Greys, which are steps towards blackness, are produced by three equal standard glasses of different colours.
It is well known that Colour Blindness is a defect in the vision often involving the confusion of such utterly distinct colour sensations as Red and Green, Orange and Violet, and many others as widely different. In the cases of Red and Green the confusions are specially disastrous should the subject be a railwayman or a sailor. It is not, however, so well known that many cases of so-called Colour Blindness are in reality cases of Colour Ignorance, and the capacity for distinguishing between colours and shades is often latent, and only waiting to be developed by Education.
When a child persistently misnames colours after having received an amount of instruction sufficient to remove colour ignorance in a normal case, the errors are probably due to some form of colour blindness.
Such cases should be registered for further examination, taking note of the miscalled colours. It would be an additional precaution to change the position of the colours in the windows of the apparatus, in order to prevent the association of colours with their positions as first given in the instructions.
Note.—The paints which most nearly correspond to the colour standards in the Colour Educator are tabulated below, the third column containing their measured colour proportions when they are washed thickly on white paper (Whatman’s).
| Spectrum Names. | Artists’ Names. | Colour Composition in Standard Units. | |||||
| Red. | Orange. | Yellow. | Green. | Blue. | Violet. | ||
| Dominants: | |||||||
| Red | Crimson Lake | 18·0 | 0·4 | — | — | — | — |
| Yellow | Lemon Yellow | — | — | 6·6 | — | — | — |
| Blue | Cobalt | — | — | — | — | 9·0 | — |
| Subordinates: | |||||||
| Orange | Chrome Orange | — | 7·2 | 1·6 | — | — | — |
| Green | Emerald Green | — | — | 0·40 | 5·4 | — | — |
| Violet | Mauve | 3·3 | — | — | — | — | 8·2 |
In mixing two dominant colours (artists’ primaries) to develop subordinates (artists’ secondaries), their relative colour depth must be taken into account; for instance, Crimson Lake has a natural colour depth nearly three times that of Lemon Yellow; therefore, in order to develop a normal Orange nearly three times the quantity of Yellow must be used, presuming that they were originally ground to an equal degree of fineness.
It is desirable that a record of the children’s own painting should be preserved, with a view to discriminating between errors arising from Colour Blindness and Colour Ignorance, the former perpetuating itself, and the latter naturally remedying itself. For this purpose painting books containing sets of diagrams corresponding to the figures in the foregoing pamphlet can be supplied.
Appendix II
THE POSSIBILITIES OF A STANDARD LIGHT AND COLOUR UNIT.[5]
The past attempts to standardize light and colour are mainly limited to those radiant energies which excite light and colour sensations under diffused daylight conditions, because in direct sunlight, and in most artificial lights, there are other colour energies, which, unless sufficiently modified by diffusion, disturb the colour readings. There are also latent colour energies, which only become distinguishable by special means. They do not, however, appear to influence diffused daylight colour work.
The definition of a normal vision is one which agrees with a majority of others. This definition has proved satisfactory up to the present, as the normals are many and the colour blind few.
Light Intensities.—There are two methods of determining light intensities by means of a graded scale of light absorbents.
First. By total absorption of the light, when the intensity is directly represented by the unit value of the absorbents required. This method is applicable for low lights, internal surfaces, such as a desk, etc., where a standard light is not available for comparison.
Second. By the reduction of a standard light by absorption until it equals the light of the object. In this case the standard must be originally brighter than the object.
Constants.—The first requirement in establishing a scale of light and colour units is a means of co-relating visual sensations to a scale of physical colour constants, in order to secure a power of record and recovery. There is no natural scale available for quantitative colour work, but artificial scales can be constructed, and made constants by co-relation at different points with physical colour constants, and by cross-checking the intervals between these.
The scales used in the “tintometer” consist of red, yellow and blue glass, so graded in equivalents that combinations of equal units transmit colourless light. Full details of these have already been placed before the Society (see this Jour., 1887, p. 186, and 1908, p. 36).
Scale of Luminous Intensities. The Light Unit.—The natural terminals in a scale of luminous intensities are black and white, and the first question which arises is what is black, and what is white? as when used in a popular sense each term covers a wide range of differences.
In the author’s sense the term black means total absence of light, and the term white means a diffused daylight of given intensity, as reflected from a lime sulphate surface. In this sense black and white are the terminals of a scale of light intensities; the scale is divided into units and fractions of units. The unit itself is physiological, and is not in progressive accord with the mathematical light unit based on the inverse squares of distance.
The Black Unit.—Ideal black is practically obtained under daylight conditions by viewing a hole in a box with blackened interior, so arranged that no entering light can be reflected back to the vision.
The box used for this purpose is illustrated in [Fig. 3], and has one surface covered with standard white for the purpose of easy comparison with the pigments. The standard black aperture (1) is in the middle. The pigmentary blacks (2 to 10) are arranged over this, and the pigmentary whites and greys (11 to 20) underneath, each being numbered in accord with its intensity as tabulated.
Fig. 3.
The degrees of blackness are the number of absorptive units required to reduce the standard white to equal the pigments in each case.
Light Absorbed by Various Pigments.
| No. | Absorbed Light. | Unabsorbed Light. | Initial Light. | |
| 1 | Black Hole in Box | 36 | — | 36 |
| 2 | Optical Black | 20 | 16 | 36 |
| 3 | Lamp Black | 17 | 19 | 36 |
| 4 | Vegetable Black A | 17 | 19 | 36 |
| 5 | Vegetable Black B | 14 | 22 | 36 |
| 6 | Vegetable Black C | 15 | 21 | 36 |
| 7 | Indian Ink on Paper | 14 | 22 | 36 |
| 8 | Indian Ink Solid | 12 | 24 | 36 |
| 9 | Boot Black | 11 | 25 | 36 |
| 10 | Black Lead | 9 | 27 | 36 |
This gives a working scale of colourless light intensities, the terminals being black and white, with a range of 36 units.
The Standard White.—White is the natural terminal of the luminous end of the scale, and it is necessary to select a physical objective white as a constant. Pure precipitated lime sulphate has been adopted, and departures from the light intensity of this are recorded in units of lessened light intensity throughout the scale, comprising all degrees of colourless whites, greys, and blacks.
Strictly speaking, white is a qualitative term only, until the degree of variation from the zero of the scale has been established. The measured variation then takes its position in the scale of luminous intensities according to its numerical unit value.
Light Absorbed by Various White and Grey Pigments.
| No. | Pigments. | Absorbed Light. | Reflected Light. | Initial Light. |
| 11 | Grey Paint E | 6·0 | 30·0 | 36 |
| 12 | Grey Paint D | 5·0 | 31·0 | 36 |
| 13 | Grey Paint C | 4·0 | 32·0 | 36 |
| 14 | Grey Paint B | 2·0 | 34·0 | 36 |
| 15 | White Paint A | 0·7 | 35·3 | 36 |
| 16 | White Paper D | 0·3 | 35·7 | 36 |
| 17 | White Paper C | 0·2 | 35·8 | 36 |
| 18 | White Paper B | 0·25 | 35·75 | 36 |
| 19 | White Paper A | 0·15 | 35·85 | 36 |
| 20 | Chinese White | 0·006 | 35·994 | 36 |
As the scale is differentiated into hundredths of a unit, there can be 100 variations of white pigments in a single unit, each quite easily distinguishable from the others.
Any definite mixture of black and white finds a position on the diagonal of a chart whose co-ordinates are the black and white scales; for example, the 20 measured pigments are charted on Figs. [4] and [5], the latter being on an enlarged scale, as the whites would be too crowded to be noted on [Fig. 4].
Fig. 4.
The merging of white into grey, and of grey into black is gradual, having no strict lines of demarcation.
An example of this method of determining light intensities is illustrated in [Fig. 6] by the light intensities at which different objects are discernible. The points of most interest are, that colour is indistinguishable as such in lights below 15 units intensity; and that ordinary work, such as reading a newspaper, requires for comfort a minimum of 28 units.
The Colour Unit.—The colour unit is physiological, and its dimensions are determined by the dimensions of the colourless light from which it is derived. This deduction is based on the experimental fact that colourless light is a mixture of the six colour rays—red, orange, yellow, green, blue, and violet—in equal proportion, as illustrated in [Fig. 7], showing that a white light of 20 units light intensity is made up to the six colour rays, each of 20 units colour intensity. This is demonstrated by the fact that any proportion of any colour can be developed at will by means of the glass standard scales already mentioned; it follows that the smallest disturbance of equivalence between the composing rays results in the development of colour.
Fig. 5.
The above remarks apply to both simple and complex colours, and the complex colours are always dichromes, being governed by another physiological fact, which is: That the vision is unable to simultaneously distinguish more than two colours in the same beam of light. The order of their association is definite, and may be described by saying that the combined two are always adjacent in their spectrum order, red and violet being considered adjacent for this purpose. It follows that all complex colours are binaries, and the only possible combinations are as follows:—
Red with Orange.
Orange with Yellow.
Yellow with Green.
Green with Blue.
Blue with Violet.
Violet with Red.
Fig. 6.
In the author’s colour nomenclature, a monochrome is qualitatively described by a single term, and a complex colour by a combination of two single terms. For a quantitative description, it is only necessary to add the measured unit value to each term. When there is excess of brightness, or a saddening factor, these also must be quantitatively estimated.
The colours developed by means of these scales are governed by the same law of selective absorption which governs the development of natural colours, any of which can be matched and reproduced by means of their established ray proportions.
Fig. 7.
The governing law is simple, and may be stated by saying that the colour developed is always complementary to the colour absorbed, not in the generally accepted sense that their mixture necessarily makes white light, but in the sense that they are opposite in the cycle of daylight colours.
The dimensions of the unit are necessarily arbitrary, it was originally selected as being a convenient depth for distinguishing differences, the scale was then constructed by equal additions and sub-divisions; the two essentials of a scientific scale being complied with, in that the divisions were equal and the unit recoverable. The power of recovery lies in the fact that different parts of the scale are co-related to physical colour constants, which can be prepared in any laboratory.
PLATE VIII
ABSORPTION CURVES OF SIX DYES.
To face page 76.[Lovibond, Colour Theories.
Specific Colour.—The relationship of colour increase to intensity increase in substances has hitherto been somewhat obscure. It has been sometimes considered that they were in direct proportion, but in the absence of a means of recording colour sensations, no definite results were obtainable.
Fig. 8.
Sufficient information is now available to warrant the formulation of the following law: “That every substance has its own rate of colour development for regularly increasing intensities, which, when once established, becomes a constant for identifying similar substances in future.” This is the meaning of specific colour, and when a series of measurements at regularly increasing densities of a given substance have been made, the specific colour rate of that substance is established. This can be charted in curves and used as a basis for estimating quantities, properties, changes of condition, differences in value, detecting adulteration, etc.
Applications.—The author has permission to use the names of several gentlemen who have used the tintometrical scales for various purposes.
Sir Arthur H. Church, F.R.S., has employed the tintometrical standards for the purpose of registering the colours of certain wild flowers.
Sir Boverton Redwood has used the scales and system for petroleum investigations. At his instance the specific colour rate of petroleum was established, and the several composing colours plotted in curves, as in [Fig. 8], where the ordinates represent the scale of units irrespective of colour, and the abscissæ the scale of strata thicknesses.
The measurements were made at two-inch intervals, and the four perpendicular lines are at the colour points selected for valuing the four distinguishing marks, technically known as “Water White,” “Superfine,” “Prime,” and “Standard.” Intermediate qualities find their position in the scale of curves according to their measured colour values.
This method of standardizing commercial values has also been adopted by the International Tanners’ Association, the Inter-States Cotton Seed Oil Association, and other oil industries. Also for scale, solid fats, and such substances as can be easily melted and measured by transmitted light.
Varying Effects of Different Lights. Pathological Applications.—The law of specific colour development was made use of by Dr. George Oliver in determining the degrees of hæmoglobin in the blood. The method is fully explained in his Croonian Lecture before the Royal College of Physicians of London, July 11, 1896.
Detection of Forgeries.—The system and apparatus is used by Professor A. S. Osborne, Examiner of Questioned Documents, New York City, for determining the variety of ink, the age of the writing, and the detection of forgeries. A full description of the process will be found in his work entitled Questioned Documents, published by the Lawyers’ Co-operative Society, Rochester, N.Y.
PLATE IX
SIX ANILINE DYES.
CURVES ILLUSTRATING THE RATE OF FADING BY EXPOSURE TO LIGHT.
To face page 78.[Lovibond, Colour Theories.
The application to chemical analysis is too well known to require enlargement here.
Fig. 9.
Dyes.—As an example of the use of the system in the valuation of dyes, [Fig. 9] illustrates the specific colour curves of four samples of Methylene Blue. No. 1 was priced at 5s. 9d. and No. 2 at 5s. per lb., Nos. 3 and 4 were not priced, the solutions were measured in percentages from 0·001 to 0·048 in distilled water. To find the cost per unit of colour in the priced samples is only a question of simple arithmetic, which furnishes data for the valuation of the unpriced samples.
The yield in the dye vat may not be in direct relation to the solutions in water, the establishment of this is a question for the expert, and presents no apparent difficulty.
The use of the scheme in recording the degree of fading of dyes has been previously dealt with in the Journal (q.v., 1908, p. 36).
Limitations and Precautions.—It has been shown that we have analytical control, within certain limits, of light and colour under daylight conditions.
The general limits for colourless light range from total darkness to 28 units, when the unabsorbable red ray comes into evidence.
For colour, the general limits range from 28 to 18 units, between 18 and 15 all colours become indistinct, but at varying rates, below 15, colour is not distinguishable.
The principal disturbing conditions in making observations are want of colour education and insufficient diffusion. In the case of the latter, the first evidence is the disturbance of constancy by the penetrating red ray. A partial remedy is to interpose a white diffusion screen, such as tissue paper.
Time of Observation.—This should not exceed five consecutive seconds, as the keenness of perception decreases by time, but varies for different colours.
Angle of Incidence.—Sixty degrees is safe for most solids, but for bright or polished surfaces, such as varnishes, polished metals, etc., the angle must be lessened as the degree of smoothness increases. For very rough surfaces, such as loosely woven stuffs, etc., care must be taken that the lay of the fibre is uniform.
Distance from the Object.—Ten inches has been adopted for general work, but certain visions require more or less as their focus varies from normal.
PLATE X
COMPARISON CURVES OF HEALTHY AND DISEASED BLOOD.
To face page 80. [Lovibond, Colour Theories.
Unabsorbable Colours.—In addition to the daylight colours already dealt with, there are, in direct lights, colours which do not obey the laws of absorption governing those of diffused daylight.
The work already done on these unabsorbable rays has only been incidental, where they happened to interfere with the standardization of diffused daylight colours. The sensations excited are red and violet. They blend, producing red-violet mixtures, but in unequal proportions, the red being dominant.
The red is developed in intense lights by constant interception of neutral tint absorbents. In the case of a 4-volt incandescent light, the first absorption simply reduces the light intensity without developing colour; the light is colourless up to 14 units. At 16 units the light begins to assume a reddish hue, which rapidly becomes a brilliant intense red by further interceptions of neutral tint absorbents.
Violet is developed by constant absorption by blue standards, which grows in intensity by successive additions up to about 120 units. Beyond this point the brilliancy decreases.
Preliminary experiments point to this ray as fatal to vegetation, and presumably also to lower forms of organic life.
There remains a factor of considerable importance which has not yet received the attention it deserves, the physiological changes resulting from environment.
This aspect of the question has come under the notice of the author by measuring the vision of experts who excelled in given hues. It was generally found that their vision was sensitive to a small increment of their particular colour in harmonies where it was silent to a normal vision.
In seeking an explanation of this phenomenon there are at least three possible lines for working:
First. Is the vision naturally more sensitive to that particular energy?
Second. Is it by careful education?
Third. Is it an unconscious adaptation to surroundings, such as other organs undergo under changes of environment?
PLATE XI
SPECIFIC COLOUR CURVES OF HEALTHY AND DISEASED HUMAN BLOOD
To face page 82.[Lovibond, Colour Theories.
Appendix III
THE APPLICATION OF THE NATURAL LAW OF SPECIFIC COLOUR RATE BY DR. DUDLEY CORBETT TO THE EXACT MEASUREMENT OF X-RAY DOSAGE.
Dr. Dudley Corbett.
The gradations in the tint given by the Sabouraud-Noiré pastille when exposed to X-rays are so fine, especially in that region of the colour scale where lies the erythema dose, that many have felt the want of a more accurate means of reading these tints, as well as a series of reliable standards for comparison. Hitherto the only methods at all generally used have been Hampson’s radiometer and Bordier’s radio-chronometer, the former in this country, and the latter on the Continent. Hampson’s instrument has two disadvantages: it can only be used with electric light, and the standards are made of tinted paper liable to get soiled, and to vary slightly with the changes in the pigment employed. Its advantage is that it may be used as a sliding scale, thus economising the pastilles. Some persons, however, have considerable difficulty in reading the tints, the scale rising only by gradations of 1/4 B.
In the construction of any such instrument, the really important point is to obtain a reliable standard for Tint B—i.e., the normal epilation dose. The tints on the Sabouraud card itself are not always identical, some representing a dose which will only just epilate, others an almost dangerous dose for unfiltered rays. The Tint B, which is the standard, allows a margin of error of 20 per cent. on either side. In other words, 4/5 B will almost always epilate, while 1-1/5 B is nearly the limit of safety. This observation is in accordance with the experience of other workers on this subject. In my instrument Tint B has been obtained by measuring the pastille with Lovibond’s tintometer immediately after exposure to the X-rays. The pastille was turned to a tint corresponding to an epilation dose which was known to be safe, as proved by clinical results. This tint was measured directly both by daylight and by artificial light from an 8-candle power carbon filament lamp with frosted glass shade. I am indebted to Mr. Dean for suggesting the use of Lovibond’s instrument for this purpose.
The methods employed in the experimental work have been described in the British Journal of Dermatology for August, 1913. By using a very constant focus tube and averaging a large number of readings and correlating the results with those obtained in clinical practice, we were able to construct the curves indicating the colour developed by the pastille. In these curves, shown in [Fig. 10], the ordinates are the Lovibond colour units, the abscissa the time during which the current was actually passing. When using an interrupter working at a constant speed, the actual time was taken, otherwise the number of current interruptions as measured by a dipper tachymeter was used.
As was to be expected, the daylight and electric light curves were quite different. In each case the standard yellow glasses employed were kept constant throughout the curve, that for daylight being 15 units, that for electric light 13 units. When these were combined with blue and red glasses in varying units and fractions of a unit, they gave a colour range which matched the pastille exactly in the changes it undergoes from the unexposed condition to the 2 B Tint.
The curves are plotted in accordance with Mr. Lovibond’s practice—that is, not as a direct representation of the standard glasses used, but as showing the colour sensation received by the eye.
Fig. 10.
First, as to the daylight curve: In order to match the unexposed pastille we interpose between the pastille and the observer’s eye a yellow and a blue glass, plus a certain amount of neutral tint (composed of three equal colour units). Thus the colour sensation received is a yellow green, together with a certain amount of white light. As the pastille darkens under irradiation, both the green and the white light disappear, until at a point just below the 1/2 B dose, there is no other colour present but yellow. After this red glasses are required—i.e., the colour sensation is a yellow orange, which gradually deepens owing to an increase in the proportion of red. The yellow curve thus rises till just below the 1/2 B point, and then falls as the orange increases.
Next, as to the electric light curve. The unexposed pastille has but a trace of green, which is soon lost. The orange begins much earlier than in daylight, and thus at Tint B has reached a higher point than in daylight. From this point the orange and yellow parts of both curves run practically parallel with one another up to 2 B. Beyond 2 B the readings become more difficult. I have not determined the point when no more colour develops, as it has no great practical value, though it might well be of interest from a physico-chemical standpoint.
In my radiometer the standards are composed of the Lovibond standard glasses in combination. The apparatus itself consists of an optical instrument or viewing box. This is divided by a central partition, so that on looking through the eyepiece one sees a white background through two small circular apertures. On one side, level with the background, is a fitting to take the pastille in its holder. On the other side is a groove in the instrument itself for the insertion of the standard glasses. A similar groove is fitted on the pastille side of the instrument to take neutral tints if required. The colour of the pastille as seen by reflected light can thus be compared with that obtained by transmitted light through the standard glasses seen against the white background. A difference of 1/5 B or 1 H is quite easily perceivable.
It is usually of no great importance to obtain extremely accurate measurement of the smaller fractions below 1/3 B. Where this is necessary, neutral tints must be used when working with daylight. With electric light these are unnecessary. When required the neutral tints are interposed between the pastille and the eye to absorb the white light reflected from the pastille. The neutral glasses required are 1·5 for the unexposed pastille, 0·6 for 1/4 B, and 0·2 for 1/3 B. These values are subject to slight variations due to changes in the varnish of the pastille emulsion. The difficulty can always be avoided by using electric light, where a trace of neutral tint is needed only when matching the unexposed pastille—an unimportant point.
Method of Use.—The choice of daylight or artificial light is a personal matter, but one should practise reading the scale with both. The use of the instrument shows that the pastille fades very nearly as quickly under electric light as it does under daylight. The following precautions should be observed: In daylight work in a good white light, avoid shadows and yellow light of any kind. With electric light use an 8-candle power carbon-filament lamp with frosted glass and a suitable white shade so arranged that the pastille is 8 inches from the lamp. No other light should be allowed to reach the pastille during examination. A low power metal-filament lamp may be used, but greater accuracy will be obtained with a carbon-filament lamp which was used for the experimental work. The lamp should be discarded as soon as the light becomes yellow from prolonged use. Whether in daylight or electric light, the examination must be rapid to avoid the fading of the pastille. When it is desired to give an accurate 1 B dose, it is better to put up the 4/5 B standard first. It is then easy to calculate how much more exposure is required for the extra 1/5 B. It is important to adjust the pastille carefully so that none of the unirradiated green portion is visible through the small aperture, as this will upset the reading. In very accurate dosage new pastilles should be used, as a bleached pastille never returns exactly to its original tint. When such a bleached pastille is irradiated the colour changes start a little farther down the curve, and thus the tint for a given dose must be taken a little above the normal tint. This increase is very slight, but is nevertheless quite appreciable, and may amount to as much as 5 and 10 per cent. Even then the margin for error is ample in the neighbourhood of the B tint, and if a pastille is not used more than three times, and is well bleached in daylight after each exposure, no serious error is likely to occur. A standard white background should always be used, and discarded for a new one when it gets dirty. The colour standards usually provided are those in common use—namely, 1/4, 1/3, 1/2, 4/5, 1, 1', and 2 B, but it is quite easy to make up standards for any point on the curve. The symbol “B,” as the erythema or epilation dose, has been retained, as it was thought inadvisable to add to the number of such symbols already existing.
To sum up:
1. The experimental work has determined the exact colour changes occurring in the Sabouraud pastille when exposed to X-rays.
2. These experiments have established a permanent standard for Tint B, which matches the pastille exactly, does not fade, is easily kept clean. These coloured glasses can be readily and accurately reproduced, as they are standardized spectroscopically by a firm who specialise in such work. The standard will therefore remain constant so long as the Sabouraud emulsion remains unaltered.
3. Glasses may be prepared of the correct tint for any fraction or multiple of this dose up to 2 B or 10 H.
4. Either daylight or electric light can be used.
5. The optical instrument itself, by cutting off extraneous light, greatly assists the colour comparisons, so that the practical error need never exceed 10 per cent.
INDEX
- Abnormal light, [13]
- Analysis of white light, [11], [13]
- Arbitrary scales, [9]
- Artists and scientists, [1], [2]
- Beam of white light, [7], [11]
- Black units, [16], [23]
- Black, ideal, [15], [11]
- Blood curves, [33]
- Code of laws, [7]
- Colour charts, [31], [39]
- education, [59]
- equivalence, [10]
- nomenclature, [17], [21]
- qualitative, [17], [19], [24]
- quantitative, [24]
- scales, [20], [29]
- standardization, [20], [69]
- theories, [2], [3]
- Coloured surfaces, [44]
- Colours, complex, [18]
- sadder than standards, [25]
- simple, [17]
- Corbett, Dr. Dudley’s, radiometer, [83]
- Daylight colours, [24], [84]
- measurement, [14]
- Diffused light, [10], [43]
- Direct lights, [46]
- Dulled colour, [10], [18-26], [36]
- Equivalent colour units, [7], [9], [29]
- Fog, whiteness of, [10]
- Glass standards, [20]
- Human blood curves, [82]
- Laws of colour, [7]
- Light, [11], [13], [42], [45-46], [81-84]
- abnormal, [8]
- brighter than standards, [14], [27]
- direct, [46]
- for colour work, [42]
- intensities, [42], [43]
- white, [14]
- Lovibond’s new colour theory, [5]
- Matching colours brighter than standards, [18]
- complex colours, [17]
- Measuring and naming colours, [21]
- Monochromes, [17], [19]
- Munro, Dr., [34]
- Neutral tint, [18], [24], [26]
- [90]North light, [15]
- Past theories, [3]
- Photographic energies, [53]
- Physical colour constants, [8]
- Pigmentary black, [15], [71]
- Primary colours, [1]
- Prismatic spectrum colours, [29]
- Qualitative analysis of colour, [17], [19], [24]
- Quantitative analysis of colour, [24]
- Radiometer, [83]
- Rate of colour absorption, [8]
- Rays, six colour, [7]
- Red ray, [41]
- Scales, arbitrary colour, [9]
- coloured, [10], [20]
- cross checking of, [9]
- Scientists and artists, [1], [2]
- Sea fog, [10]
- Specific colour, [32]
- Spectrum colours, [4], [18], [36]
- Three colours, [10], [57]
- Time, appreciation of colour by, [42]
- Ultra violet, [32], [40]
- Unit, checking of, [9]
- Unit, neutral tint, [18], [24], [26]
- Wave length position, [37], [38]
- White light, [11], [13]
Butler & Tanner Frome and London
FOOTNOTES:
[1] It was afterwards found that these colour changes through variations of intensities were due to a natural law to be described under the heading of “Specific colour.” (See [page 32].)
[2] For description of the light and colour units, refer to chap. III, page 9.
[3] It was found that the superimposition of two glasses did not visually disturb equivalence, therefore only two glasses were used for each observation in constructing the scales.
[4] This method of illustration was suggested by Dr. Herbert Munro.
[5] Reprinted from the Journal of the Society of Dyers and Colourists, March, 1913. No. 3, vol. xxix.
Transcriber’s notes:
In the text version, italics are represented by _underscores_, and bold and black letter text by =equals= symbols. Superscripts are represented by ^{} and subscripts by _{}
Missing or incorrect punctuation has been repaired.
Inconsistent spelling and hyphenation have been left,
In the html version, dittos have been replaced by the repeated text so that text aligns for easier reading.
Very wide tables (V and VI and VII)have been split to fit on portrait oriented pages.
The following mistakes have been noted:
- p. 21. NiSO_{4}7H_{2}O, tem." is formatted inconsistently. Left as printed.
- p. 40. Fraunhoper is almost certainly a typo for Fraunhofer. Left as printed.
- p. 46. interpretated changed to interpreted.
- p. 55. In Paper 6 of table, Red screen, yellow entry, from alignment and logic, the 6 should be .6. Left as printed
- p. 61 conditonschanged to conditions.