CHAPTER VII.
THE ORIGIN AND DESCENT OF ROCKS.
It has been the current opinion that the earth was once in a molten state, and thence cooled to a solid condition, and hence that all the primitive rocks were igneous. Even those who think that the earth may never have passed through a molten state agree that the oldest known rocks are either true igneous rocks, or rocks of very similar nature. A molten magma may, therefore, be taken as the mother state of the rocks. Starting with this conception, the natural order of events suggests the inquiries (1) how rocks are formed from molten magmas, (2) what natures they assume, (3) how other rocks are derived from them, (4) how still other rocks are derived from these derivatives, and so on. To answer these inquiries is to trace out the generations of rocks and learn the general history of rock-formation.
(1) The process by which igneous rocks are formed from lavas is actually taking place in existing volcanoes. As these are widely scattered over the face of the earth, the material poured out by them represents different parts of the interior and varies in nature accordingly. This affords the means of studying the differences that arise from differences of material. This is a radical consideration, for variations in composition give rise to the most fundamental distinctions between rocks, though by no means the only ones. Rocks which have the same composition often differ greatly in texture or structure, owing to the varying conditions under which they were formed. In the solidification of rocks from the molten state, the rate of cooling causes many differences. A means of studying this is afforded by the various lava flows that are now being poured out on the surface under different conditions; but a more important means is afforded by extinct volcanoes, especially by those which have been deeply cut open by erosion. In certain very ancient volcanoes, not only have the solidified lava streams of the surface been cut across by erosion, but the lava that remained in the crater, or in the neck that led up from below, is laid bare for inspection. Exposures of even more profound nature have been made by the great disruptions which the outer part of the crust has suffered. In certain tracts there have been profound fractures, and the formations on one side of these have settled down and on the other side have been pushed up (faulted), so as to expose parts that were once much below the surface. Sometimes also the crust has been folded and crumpled, and the wrinkles thus formed have afterwards been worn away or cut open by deep valleys, and rocks that were once deeply buried have been laid bare. By the revelations made in these and other ways, it has been learned that at various times in the history of the earth molten matter has been thrust into fissures or intruded between layers of the crust and cooled there, without coming to the surface. Sometimes the lava appears to have forced its way into the rocks, and sometimes to have lifted the upper beds and formed great subterranean layers or tumor-like aggregates, called bathyliths and laccoliths ([Fig. 334]). Such intruded bodies of molten rock, solidifying under the varying conditions of such subterranean situations, are a fruitful source of instruction respecting the influence of varying rates and modes of cooling, as well as of other attendant conditions.
Fig. 334.—Diagram of a laccolith. (Gilbert.)
It will thus be readily seen that the rate of cooling of the various molten rocks must have differed very greatly. In the portions poured out upon the surface there were sometimes narrow streams and thin sheets, giving large exposure in proportion to the mass ([Fig. 335]), and sometimes thick flows and deep pondings in basins and choked valleys, giving massive bodies with relatively small surface exposure. There were explosions of the lava into minute particles with almost instantaneous cooling, and there were eruptions beneath the sea the peculiar effects of which are rather matters of inference than of positive knowledge. In the portions underground there were insinuations into thin fissures, on the one hand, and in-thrustings of thick bodies, on the other. Some intrusions entered the upper part of the crust where the rocks were cold and wet, and some were thrust into the deeper portions where the rocks were warmer and less penetrated by water. Sometimes the lava rose rapidly and was little cooled in passage, sometimes slowly with more cooling en route, and sometimes there were long halts between eruptions, with much opportunity to cool. An almost infinite variety of conditions is thus presented, and with it a rich field for the study of the modes of solidification.
Fig. 335.—Fresh lava flow, with large surface exposure. Holemaumau, Hawaii. (Libbey.)
In the underground intrusions the additional factor of high pressure was also present, and this is the third important condition in determining the nature of igneous rocks.
The three factors, composition, rate of cooling, and degree of pressure, require special consideration.
Composition of Igneous Rocks.
All or nearly all the chemical elements known on the earth are found in greater or less amounts in igneous rocks, and in a broad sense are constituents of them. If there are any exceptions, they are most likely to be found in the rarer elements in the atmosphere. Oxygen, nitrogen, hydrogen, aqueous vapor, and carbonic acid, which make up the mass of the present atmosphere, are all found in lavas and in their cooled products. Probably all the rarer elements also occur in igneous rocks. Helium is known to be given forth by springs.
Leading elements.—But although nearly or quite all the known chemical elements enter into the igneous rocks, only a few of them are abundant. These are regarded as normal or essential constituents, while the rarer substances are regarded as incidental. By combining a large number of the most trustworthy analyses of rocks of all sorts, F. W. Clarke[199] has estimated the relative amounts of the more abundant elements in the crust of the earth with the following result:
| Element. | Symbol. | Percent. in the Solid Crust. |
|---|---|---|
| Oxygen | (O) | 47.02 |
| Silicon | (Si) | 28.06 |
| Aluminum | (Al) | 8.16 |
| Iron | (Fe) | 4.64 |
| Calcium | (Ca) | 3.50 |
| Magnesium | (Mg) | 2.62 |
| Sodium | (Na) | 2.63 |
| Potassium | (K) | 2.32 |
| Titanium | (Ti) | .41 |
| Hydrogen | (H) | .17 |
| Carbon | (C) | .12 |
| Phosphorus | (P) | .09 |
| Manganese | (Mn) | .07 |
| Sulphur | (S) | .07 |
| Barium | (Ba) | .05 |
| Strontium | (Sr) | .02 |
| Chromium | (Cr) | .01 |
| Nickel | (Ni) | .01 |
| Lithium | (Li) | .01 |
| Chlorine | (Cl) | .01 |
| Fluorine | (Fl) | .01 |
——— | ||
100.00 | ||
It will be seen that only eight of the elements hold a high rank in quantity. Many that are of the utmost importance in the history of the earth and the affairs of men are low in the list, or do not even appear in it at all, because their quantity is too small to be estimated in percentages. The precious metals, and even some of the more common metals, as lead, zinc, and copper, are too scarce to form an appreciable percentage.
Union of elements.—In a general study of the igneous rocks we may for the present neglect all but the first eight of these elements. Out of these elements spring various chemical combinations, and out of these combinations spring the various minerals, and out of the combinations of minerals come the various rocks. The union of oxygen with the other seven elements may be taken as a fundamental step in this series of combinations. The result is the following oxides: Silica (SiO2), alumina (Al2O3), ferrous, ferric, and magnetic oxide (FeO, Fe2O3, and Fe3O4), magnesia (MgO), calcium oxide or lime (CaO), soda (Na2O), and potash (K2O). The oxygen sometimes unites in proportions different from those here given, but such exceptions may be neglected in a general study. We thus have nine leading oxides. Of these, silica acts as an acid, or more strictly according to the newer chemical view, as an acid anhydride. All the rest, except the magnetic oxide of iron, and sometimes the oxide of aluminum, act as basic oxides.
In the older chemical philosophy these oxides were supposed to combine by the simple union of an acid oxide with a basic oxide, and to remain as oxide joined to oxide; thus silica (SiO2) and lime (CaO) formed silicate of lime (CaO,Si2). The symbols express the idea better than the words. This method is used in the older geological works and in some of the later. But in the newer chemical doctrine, the oxides are not believed to remain so distinct after their union, and the symbols are written CaSiO3, and the compound is named calcium silicate. According to the modern doctrine of solution, some of the calcium, silicon, and oxygen may exist as free ions in molten rock. The precise way in which the elements are related to each other in these compounds can scarcely be said to be known. For the general purposes of geology it is most convenient to think of these oxides as uniting in the simple fashion first named, and this involves no apparent geological error in general studies, since they are oxides when they enter the compound, and if the compound is decomposed they usually come forth again as oxides; but in closer studies more complex unions, attended by dissociations (ionization), must be recognized.
Formation of minerals.—As but one of the leading oxides that abound in an average magma plays the part of an acid, the silica, a very simple conception of the general nature of igneous rocks may be reached by noting that they are mostly silicates of the seven leading basic oxides—alumina, potash, soda, lime, magnesia, and the iron oxides. This general idea is a very useful one and represents a most important truth; but in its use we must not forget that there are many exceptions. Sulphur, phosphorus, chlorine, and other elements unite with the bases to form sulphates, sulphides, phosphates, phosphides, chlorides, etc. So also there are many minor bases that form silicates; and these minor bases unite with the minor acids to form many more or less rare minerals. Again, there are native metals in some igneous rocks. But altogether these hardly reach more than one or two percent. of the whole.
There are, however, two exceptions of more importance. In the molten magma the acid and basic elements are not always evenly matched. When there is an excess of silica, a portion remains free and takes the form of quartz (SiO2). If there is an excess of the basic oxides, the weakest one is usually left out of the combination. This is commonly the iron oxide, which then usually takes the form of magnetite (Fe3O4). It is a singular fact that quartz often forms when there is no excess of silica, and magnetite when there is no excess of base. Quartz (free acid anhydride) and magnetite (free basic oxide) sometimes occur in the same rock. The explanation for this is yet to be found. These form rather important exceptions to the generalization that the igneous rocks are mostly made up of silicates, but, thus qualified, it expresses the essential truth, and has the merit of embodying the central chemical fact relative to these rocks.
Sources of complexity.—But here simplicity ends. As we pass on to the specific silicates that are formed, we encounter several sources of complexity. In the first place, the silica unites with the bases in different ratios and thus gives rise to unisilicates or orthosilicates (ratio of oxygen of bases to oxygen of silica, 1:1), subsilicates (ratio more than 1), bisilicates (ratio 1:2), trisilicates or polysilicates (ratio 1:3 or higher), and combinations of these. All the bases are not known to combine in all these ways, but many do in more than one of them. Still, if the silica were content to unite with each of the bases by itself alone, the results would remain comparatively simple; but instead of this it unites with two or more at the same time; and, more than that, it unites with them in varying amounts. The case would still remain measurably simple if these chemical compounds always crystallized out by themselves, each compound forming one mineral, and but one; but the different silicates have the confusing habit of crystallizing together in the same mineral. A crystal may thus sometimes be seen, under the microscope, to be made up of alternating layers of different silicates; e.g., a microscopic layer of an aluminum-calcium silicate may be overlain by a microscopic layer of an aluminum-sodium silicate, and the alternation may be repeated throughout the crystal, giving it a banded structure. There is reason to believe that this is true in many cases where the microscope fails to detect it, and that less symmetrical comminglings of silicates may take place. As such alternations or mixtures are not governed by any known mathematical law, as is the case in chemical compounds, there is no determinate limit to the number of combinations that may arise. As a matter of fact, new ones are still being discovered in the progress of research, and the total number that may ultimately be found can scarcely be prophesied.
As a result of all this fertility of combination, the total number of silicious minerals in igneous rocks is large. It is the function of the mineralogist to treat of these minerals as such. The geologist deals with them as constituents of the earth and as factors in its history. Only a few of them are so abundant as to require special individual notice in a general study of the earth. It may be remarked also that only a few of them can be identified by simple inspection as they occur in the rocks, partly because of the delicacy of the distinctions between many of them, and partly because of their minuteness and intricate intermixture. The resources of the polarizing microscope are necessary for safe determination in most cases. The student need not feel embarrassment or discouragement if he is often unable to recognize the constituents of the intimately crystalline rocks. Their determination has grown to be a profession by itself.
The leading minerals of igneous rocks.—Fortunately for the simplicity of geological study, a few minerals make up the great mass of the igneous rocks. These few are quartz, the feldspathic minerals, the ferromagnesian minerals, and the iron oxides. Quartz (silica, SiO2) is the free acid already mentioned. The feldspathic and ferromagnesian minerals are the leading silicates of the earth’s crust, and vastly surpass all others in abundance. The feldspathic group embraces minerals formed by silica in union with alumina, together with either potash, soda, or lime, or two or more of these together. The ferromagnesian group embraces minerals formed by the union of silica with iron, magnesia, and lime, together with more or less of the other basic oxides. These statements are only true in a very general sense. Admixtures, replacements, and impurities are so frequent as to break down all sharp, simple definitions. The feldspathic minerals are normally light in color, ranging from white to red or gray. The ferromagnesian minerals are normally dark (commonly greenish) from the presence of iron, the great coloring element of rocks. But these color distinctions do not hold good in detail and cannot be much trusted as a means of identification.
The feldspathic minerals ([p. 462]) embrace the potash feldspars, orthoclase and microcline; the soda feldspar, albite; the lime feldspar, anorthite; and the mixed feldspars intermediate between albite and anorthite, viz., the soda-lime feldspar, oligoclase, the lime-soda feldspar, andesine, in which lime and soda are nearly equal, and the lime-soda feldspar, labradorite, in which the lime predominates; together with leucite, a potash silicate higher in alkali than orthoclase, and nephelite, a soda silicate higher in soda than albite. Leucite and nephelite are usually classified as feldspathoids, not as feldspars. It is to be understood that alumina is normally present in all these. Additional details respecting these minerals may be found in the reference list, [p. 460].
Among the ferromagnesian minerals the most important are the pyroxenes, the amphiboles, and the biotite type of mica. Olivine is of subordinate importance. The pyroxenes ([p. 465]) and amphiboles ([p. 460]) have nearly the same chemical composition, but differ in crystallization and physical properties. Hornblende (an amphibole) has been melted, and on cooling under proper conditions found to take on the form of augite (a pyroxene). Pyroxene is sometimes altered into uralite, one of the amphiboles. The pyroxenes and amphiboles are the most abundant of the dark minerals in crystalline rocks. The leading members of the pyroxene group are augite, diallage, hypersthene, enstatite, and soda pyroxene. The chief members of the amphibole group are hornblende and the soda amphiboles. All are essentially silicates of magnesia and iron oxide, with or without the addition of lime, soda, and alumina. Details respecting these may be found in the reference list.
The two leading micas are the iron-magnesia mica, biotite, and the potash mica, muscovite, the familiar “isinglass” of the stove-door. Chemically, muscovite should go with the potash feldspars, but it is distinguished from them by its crystalline habit and physical properties. The biotite should go chemically with the pyroxenes and amphiboles, which it closely resembles except in its crystalline properties. Details respecting the micas may be found in the reference list, [p. 464].
Two iron oxides, magnetite (Fe3O4) and hematite (Fe2O3) are widely disseminated in igneous rocks. They constitute the free bases already mentioned.
Summary of salient facts.—The salient facts are, therefore, (1) that out of the seventy-odd chemical elements in the earth, eight form the chief part of it; (2) that one of these elements uniting with the rest forms nine leading oxides; (3) that one of these oxides acts as an acid and the rest as bases; (4) that by their combination they form a series of silicates of which a few are easily chief; (5) that these silicates crystallize into a multitude of minerals of which again a few are chief; and (6) that these minerals are aggregated in various ways to form rocks. Possessed of these leading ideas, we are prepared to turn to the consideration of some of the conditions under which these combinations take place in the formation of rocks from molten magmas.