THE GLASSY ROCKS.
The solid glasses.—The quick cooling of lava-flows into solid glasses is chiefly dependent on their exposure at the surface. Hence it is often the case that the exterior of a lava-flow is glassy in greater or lesser degree, while the interior is more or less crystalline. Quick cooling is sometimes also due to the intrusion of the lava in thin sheets into fissures in cold rocks. When massive bodies of lavas penetrate solid rocks, the lava does not usually cool so fast as to prevent some degree of crystallization, and the crystallization may even become complete; but if the intruded lava sheet be very thin, the lava is liable to be cooled to a nearly perfect glass. The glassy condition is, therefore, subject to indefinite gradations. As a rule, the acid lavas are stiffer at the same temperature than the basic ones, and crystallize more slowly, so that acid glasses are more common than basic ones. The basic rocks usually crystallize pretty thoroughly, except on the immediate surface of the flows.
The first stages of crystallization.—The microscopic study of the volcanic glasses reveals great numbers of minute forms known as crystallites, microlites, globulites, etc., that appear to be first steps in crystallization, though many of them do not take definite geometrical shapes and some do not show the optical characters of crystals. There are minute globules (globulites), needles, and hair-like bodies (trichites) of more or less indeterminate nature, together with other forms that can be seen to be certainly the initial forms of well-known minerals.
Fig. 338.—Flow structure in rhyolite. Nearly natural size. (Photo. by Church.)
The obsidians.—Of the compact glassy rocks, obsidian is the best type. It is essentially a natural glass, formed usually of acid silicates. It has the close texture, conchoidal fracture, and other qualities of glass. It is usually black, but sometimes red, brown, purple, bluish, or gray. While chiefly of glass, it usually contains more or less of the incipient crystals above described, showing that even here the first step in the gradation to the next or the crystalline stage has been taken. These incipient crystals sometimes become so abundant as to change the texture from the vitreous to the stony order. In some cases, the stony texture seems to have been developed in the obsidian after it was formed, the change being a part of a subsequent process of devitrification, but in other cases the crystals seem to be original. Besides these, there are often small globular bodies known as spherulites.
Varieties of glassy rock in which the embryo crystals are more numerous and the glassy texture less perfect, are known as pitchstones. The fresh surfaces of these have rather the aspect of pitch or resin than that of true glass; hence their name. Like the obsidians, they are usually dark, but they take on greenish, brownish, yellowish, and light-colored hues as well. Sometimes glassy rock fractures in small spheroidal forms like pearls, and is known as perlite. Basic glasses are relatively rare, and while usually included under the term obsidian, are sometimes given special names.
Fig. 339.—Flow structure in volcanic glass. About half natural size. (Photo. by Church.)
Fig. 340.—Flow structure in porphyry, shown by the position of the large crystals. About two-thirds natural size. (Photo. by Church.)
Fig. 341.—Scoriaceous texture. About four-fifths natural size. (Photo. by Church.)