II.
On Haze and Dust.
Solar light in passing through a dark room reveals its track by illuminating the dust floating in the air. “The sun,” says Daniel Culverwell, “discovers atomes, though they be invisible by candle-light, and makes them dance naked in his beams.”
In my researches on the decomposition of vapors by light, I was compelled to remove these “atomes” and this dust. It was essential that the space containing the vapors should embrace no visible thing; that no substance capable of scattering the light in the slightest sensible degree should, at the outset of an experiment, be found in the “experimental tube” traversed by the luminous beam.
For a long time I was troubled by the appearance there of floating dust, which, though invisible in diffuse daylight, was at once revealed by a powerfully condensed beam. Two tubes were placed in succession in the path of the dust: the one containing fragments of glass wetted with concentrated sulphuric acid; the other, fragments of marble wetted with a strong solution of caustic potash. To my astonishment it passed through both. The air of the Royal Institution, sent through these tubes at a rate sufficiently slow to dry it and to remove its carbonic acid, carried into the experimental tube a considerable amount of mechanically-suspended matter, which was illuminated when the beam passed through the tube. The effect was substantially the same when the air was permitted to bubble through the liquid acid and through the solution of potash.
Thus, on the 5th of October, 1868, successive charges of air were admitted through the potash and sulphuric acid into the exhausted experimental tube. Prior to the admission of the air the tube was optically empty; it contained nothing competent to scatter the light. After the air had entered the tube, the conical track of the electric beam was in all cases clearly revealed. This, indeed, was a daily observation at the time to which I now refer.
I tried to intercept this floating matter in various ways; and on the day just mentioned, prior to sending the air through the drying apparatus, I carefully permitted it to pass over the tip of a spirit-lamp flame. The floating matter no longer appeared, having been burnt up by the flame. It was, therefore, organic matter. When the air was sent too rapidly through the flame, a fine blue cloud was found in the experimental tube. This was the smoke of the organic particles. I was by no means prepared for this result; for I had thought, with the rest of the world, that the dust of our air was, in great part, inorganic and non-combustible.
Mr. Valentin had the kindness to procure for me a small gas-furnace, containing a platinum tube, which could be heated to vivid redness. The tube also contained a roll of platinum gauze, which, while it permitted the air to pass through it, insured the practical contact of the dust with the incandescent metal. The air of the laboratory was permitted to enter the experimental tube, sometimes through the cold, and sometimes through the heated tube of platinum. The rapidity of admission was also varied. In the first column of the following table the quantity of air operated on is expressed by the number of inches which the mercury gauge of the air-pump sank when the air entered. In the second column the condition of the platinum tube is mentioned, and in the third the state of the air which entered the experimental tube.
Quantity of Air. | State of Platinum Tube. | State of Experimental Tube. |
|---|---|---|
| 15 inches | Cold | Full of particles. |
| 15 inches | Red-hot | Optically empty. |
| 15 inches | Cold | Full of particles. |
| 15 inches | Red-hot | Optically empty. |
| 15 inches | Cold | Full of particles. |
| 15 inches | Red-hot | Optically empty. |
The phrase “optically empty” shows that when the conditions of perfect combustion were present, the floating matter totally disappeared. It was wholly burnt up, leaving not a trace of residue. From spectrum analysis, however, we know that soda floats in the air; these organic dust particles are, I believe, the rafts that support it, and when they are removed it sinks and vanishes.
When the passage of the air was so rapid as to render imperfect the combustion of the floating matter, instead of optical emptiness a fine blue cloud made its appearance in the experimental tube. The following series of results illustrate this point:
| Quantity. | Platinum Tube. | Experimental Tube. |
|---|---|---|
| 15 inches, slow | Cold | Full of particles. |
| 15 inches, slow | Red-hot | Optically empty. |
| 15 inches, quick | Red-hot | A blue cloud. |
| 15 inches, quick | Intensely hot | A fine blue cloud. |
The optical character of these clouds was totally different from that of the dust which produced them. At right angles to the illuminating beam they discharged perfectly polarized light The cloud could be utterly quenched by a transparent Nicol’s prism, and the tube containing it reduced to optical emptiness.
The particles floating in the air of London being thus proved to be organic, I sought to burn them up at the focus of a concave reflector. One of the powerfully convergent mirrors employed in my experiments on combustion by dark rays was here made use of, but I failed in the attempt. Doubtless the floating particles are in part transparent to radiant heat, and are so far incombustible by such heat. Their rapid motion through the focus also aids their escape. They do not linger there sufficiently long to be consumed. A flame it was evident would burn them up, but I thought the presence of the flame would mask its own action among the particles.
In a cylindrical beam, which powerfully illuminated the dust of the laboratory, was placed an ignited spirit-lamp. Mingling with the flame, and round its rim, were seen wreaths of darkness resembling an intensely black smoke. On lowering the flame below the beam the same dark masses stormed upwards. They were at times blacker than the blackest smoke that I have ever seen issuing from the funnel of a steamer, and their resemblance to smoke was so perfect as to lead the most practiced observer to conclude that the apparently pure flame of the alcohol lamp required but a beam of sufficient intensity to reveal its clouds of liberated carbon.
But is the blackness smoke? The question presented itself in a moment. A red-hot poker was placed underneath the beam, and from it the black wreaths also ascended. A large hydrogen flame was next employed, and it produced those whirling masses of darkness far more copiously than either the spirit-flame or poker. Smoke was, therefore, out of the question.
What, then, was the blackness? It was simply that of stellar space; that is to say, blackness resulting from the absence from the track of the beam of all matter competent to scatter its light. When the flame was placed below the beam the floating matter was destroyed in situ; and the air, freed from this matter, rose into the beam, jostled aside the illuminated particles and substituted for their light the darkness due to its own perfect transparency. Nothing could more forcibly illustrate the invisibility of the agent which renders all things visible. The beam crossed, unseen, the black chasm formed by the transparent air, while at both sides of the gap the thick-strewn particles shone out like a luminous solid under the powerful illumination.
But here a difficulty meets us. It is not necessary to burn the particles to produce a stream of darkness. Without actual combustion, currents may be generated which shall exclude the floating matter, and therefore appear dark amid the surrounding brightness. I noticed this effect first on placing a red-hot copper ball below the beam, and permitting it to remain there until its temperature had fallen below that of boiling water. The dark currents, though much enfeebled, were still produced. They may also be produced by a flask filled with hot water.
To study this effect a platinum wire was stretched across the beam, the two ends of the wire being connected with the two poles of a voltaic battery. To regulate the strength of the current a rheostat was placed in the circuit. Beginning with a feeble current the temperature of the wire was gradually augmented, but before it reached the heat of ignition, a flat stream of air rose from it, which when looked at edgeways appeared darker and sharper than one of the blackest lines of Fraunhofer in the solar spectrum. Right and left of this dark vertical band the floating matter rose upwards, bounding definitely the non-luminous stream of air. What is the explanation? Simply this. The hot wire rarefied the air in contact with it, but it did not equally lighten the floating matter. The convection current of pure air therefore passed upwards among the particles, dragging them after it right and left, but forming between them an impassable black partition. In this way we render an account of the dark currents produced by bodies at a temperature below that of combustion.
Oxygen, hydrogen, nitrogen, carbonic acid, so prepared as to exclude all floating particles, produce the darkness when poured or blown into the beam. Coal-gas does the same. An ordinary glass shade placed in the air with its mouth downwards permits the track of the beam to be seen crossing it. Let coal-gas or hydrogen enter the shade by a tube reaching to its top, the gas gradually fills the shade from the top downwards. As soon as it occupies the space crossed by the beam, the luminous track is instantly abolished. Lifting the shade so as to bring the common boundary of gas and air above the beam, the track flashes forth. After the shade is full, if it be inverted, the gas passes upwards like a black smoke among the illuminated particles.
The air of our London rooms is loaded with this organic dust, nor is the country air free from its pollution. However ordinary daylight may permit it to disguise itself, a sufficiently powerful beam causes the air in which the dust is suspended to appear as a semi-solid rather than as a gas. Nobody could, in the first instance, without repugnance place the mouth at the illuminated focus of the electric beam and inhale the dirt revealed there. Nor is the disgust abolished by the reflection that, although we do not see the nastiness, we are churning it in our lungs every hour and minute of our lives. There is no respite to this contact with dirt; and the wonder is, not that we should from time to time suffer from its presence, but that so small a portion of it would appear to be deadly to man.
And what is this portion? It was some time ago the current belief that epidemic diseases generally were propagated by a kind of malaria, which consisted of organic matter in a state of motor-decay; that when such matter was taken into the body through the lungs or skin, it had the power of spreading there the destroying process which had attacked itself. Such a spreading power was visibly exerted in the case of yeast. A little leaven was seen to leaven the whole lump, a mere speck of matter in this supposed state of decomposition being apparently competent to propagate indefinitely its own decay. Why should not a bit of rotten malaria work in a similar manner within the human frame? In 1836 a very wonderful reply was given to this question. In that year Cagniard de la Tour discovered the yeast plant, a living organism, which, when placed in a proper medium, feeds, grows, and reproduces itself, and in this way carries on the process which we name fermentation. Fermentation was thus proved to be a product of life instead of a process of decay.
Schwann, of Berlin, discovered the yeast plant independently, and in February, 1837, he also announced the important result, that when a decoction of meat is effectually screened from ordinary air, and supplied solely with air which has been raised to a high temperature, putrefaction never sets in. Putrefaction, therefore, he affirmed to be caused by something derived from the air, which something could be destroyed by a sufficiently high temperature. The experiments of Schwann were repeated and confirmed by Helmholtz and Ure. But as regards fermentation, the minds of chemists, influenced probably by the great authority of Gay-Lussac, who ascribed putrefaction to the action of oxygen, fell back upon the old notion of matter in a state of decay. It was not the living yeast plant, but the dead or dying parts of it, which, assailed by oxygen, produced the fermentation. This notion was finally exploded by Pasteur. He proved that the so-called “ferments” are not such; that the true ferments are organized beings which find in the reputed ferments their necessary food.
Side by side with these researches and discoveries, and fortified by them and others, has run the germ theory of epidemic disease. The notion was expressed by Kircher, and favored by Linnæus, that epidemic diseases are due to germs which float in the atmosphere, enter the body, and produce disturbance by the development within the body of parasitic life. While it was still struggling against great odds, this theory found an expounder and a defender in the President of this Institution. At a time when most of his medical brethren considered it a wild dream, Sir Henry Holland contended that some form of the germ theory was probably true. The strength of this theory consists in the perfect parallelism of the phenomena of contagious disease with those of life. As a planted acorn gives birth to an oak competent to produce a whole crop of acorns, each gifted with the power of reproducing its parent tree, and as thus from a single seedling a whole forest may spring, so these epidemic diseases literally plant their seeds, grow, and shake abroad new germs, which, meeting in the human body their proper food and temperature, finally take possession of whole populations. Thus Asiatic cholera, beginning in a small way in the Delta of the Ganges, contrived in seventeen years to spread itself over nearly the whole habitable world. The development from an infinitesimal speck of the virus of small-pox of a crop of pustules, each charged with the original poison, is another illustration. The reappearance of the scourge, as in the case of the Dreadnought at Greenwich, reported on so ably by Dr. Budd and Mr. Busk, receives a satisfactory explanation from the theory which ascribes it to the lingering of germs about the infected place.
Surgeons have long known the danger of permitting air to enter an open abscess. To prevent its entrance they employ a tube called a cannula, to which is attached a sharp steel point called a trocar. They puncture with the steel point, and by gentle pressure they force the pus through the cannula. It is necessary to be very careful in cleansing the instrument; and it is difficult to see how it can be cleansed by ordinary methods in air loaded with organic impurities, as we have proved our air to be. The instrument ought, in fact, to be made as hot as its temper will bear. But this is not done, and hence, notwithstanding all the surgeon’s care, inflammation often sets in after the first operation, rendering necessary a second and a third. Rapid putrefaction is found to accompany this new inflammation. The pus, moreover, which was sweet at first, and showed no trace of animal life, is now fetid, and swarming with active little organisms called vibrios. Prof. Lister, from whose recent lecture this fact is derived, contends, with every show of reason, that this rapid putrefaction and this astounding development of animal life are due to the entry of germs into the abscess during the first operation, and their subsequent nurture and development under favorable conditions of food and temperature. The celebrated physiologist and physicist, Helmholtz, is attacked annually by hay-fever. From the 20th of May to the end of June he suffers from a catarrh of the upper air-passages; and he has found during this period, and at no other, that his nasal secretions are peopled by these vibrios. They appear to nestle by preference in the cavities and recesses of the nose, for a strong sneeze is necessary to dislodge them.
These statements sound uncomfortable; but by disclosing our enemy they enable us to fight him. When he clearly eyes his quarry the eagle’s strength is doubled, and his swoop is rendered sure. If the germ theory be proved true, it will give a definiteness to our efforts to stamp out disease which they could not previously possess. And it is only by definite effort under its guidance that its truth or falsehood can be established. It is difficult for an outsider like myself to read without sympathetic emotion such papers as those of Dr. Budd, of Bristol, on cholera, scarlet-fever, and small-pox. He is a man of strong imagination, and may occasionally take a flight beyond his facts; but without this dynamic heat of heart, the stolid inertia of the free-born Briton cannot be overcome. And as long as the heat is employed to warm up the truth without singeing it overmuch; as long as this enthusiasm can overmatch its mistakes by unequivocal examples of success, so long am I disposed to give it a fair field to work in, and to wish it God speed.
But let us return to our dust. It is needless to remark that it cannot be blown away by an ordinary bellows; or, more correctly, the place of the particles blown away is in this case supplied by others ejected from the bellows, so that the track of the beam remains unimpaired. But if the nozzle of a good bellows be filled with cotton wool not too tightly packed, the air urged through the wool is filtered of its floating matter, and it then forms a clean band of darkness in the illuminated dust. This was the filter used by Schroëder in his experiments on spontaneous generation, and turned subsequently to account in the excellent researches of Pasteur. Since 1868 I have constantly employed it myself.
But by far the most interesting and important illustration of this filtering process is furnished by the human breath. I fill my lungs with ordinary air and breathe through a glass tube across the electric beam. The condensation of the aqueous vapor of the breath is shown by the formation of a luminous white cloud of delicate texture. It is necessary to abolish this cloud, and this may be done by drying the breath previous to its entering into the beam; or still more simply, by warming the glass tube. When this is done the luminous track of the beam is for a time uninterrupted. The breath impresses upon the floating matter a transverse motion, but the dust from the lungs makes good the particles displaced. But after some time an obscure disc appears upon the beam, the darkness of which increases, until finally, towards the end of the expiration, the beam is, as it were, pierced by an intensely black hole, in which no particles whatever can be discerned. The air, in fact, has so lodged its dirt within the lungs as to render the last portions of the expired breath absolutely free from suspended matter. This experiment may be repeated any number of times with the same result. It renders the distribution of the dirt within the lungs as manifest as if the chest were transparent.
I now empty my lungs as perfectly as possible, and placing a handful of cotton wool against my mouth and nostrils, inhale through it. There is no difficulty in thus filling the lungs with air. On expiring this air through the glass tube, its freedom from floating matter is at once manifest. From the very beginning of the act of expiration the beam is pierced by a black aperture. The first puff from the lungs abolishes the illuminated dust and puts a patch of darkness in its place, and the darkness continues throughout the entire course of the expiration. When the tube is placed below the beam and moved to and fro, the same smoke-like appearance as that obtained with a flame is observed. In short, the cotton wool, when used in sufficient quantity, completely intercepts the floating matter on its way to the lungs.
And here we have revealed to us the true philosophy of a practice followed by medical men, more from instinct than from actual knowledge. In a contagious atmosphere the physician places a handkerchief to his mouth and inhales through it. In doing so he unconsciously holds back the dirt and germs of the air. If the poison were a gas it would not be thus intercepted. On showing this experiment with the cotton wool to Dr. Bence Jones, he immediately repeated it with a silk handkerchief. The result was substantially the same, though, as might be expected, the wool is by far the surest filter. The application of these experiments is obvious. If a physician wishes to hold back from the lungs of his patient, or from his own, the germs by which contagious disease is said to be propagated, he will employ a cotton wool respirator. After the revelations of this evening, such respirators must, I think, come into general use as a defence against contagion. In the crowded dwellings of the London poor, where the isolation of the sick is difficult, if not impossible, the noxious air around the patient may, by this simple means, be restored to practical purity. Thus filtered, attendants may breathe the air unharmed. In all probability the protection of the lungs will be protection of the entire system. For it is exceedingly probable that the germs which lodge in the air-passages, and which, at their leisure, can work their way across the mucous membrane, are those which sow in the body epidemic disease. If this be so, then disease can certainly be warded off by filters of cotton wool. I should be most willing to test their efficacy in my own person. And time will decide whether in lung diseases also the woolen respirator cannot abate irritation, if not arrest decay. By its means, so far as the germs are concerned, the air of the highest Alps may be brought into the chamber of the invalid.