| | Page |
| Acknowledgment | [xi] |
| 1. | Introduction | [1] |
| Scope and purpose | [2] |
| Fundamental definitions | [2] |
| Tariff history | [3] |
| Broadening use of synthetic resins | [4] |
| Relation of synthetic resins to their raw materials | [5] |
| Sources of information | [7] |
| 2. | Summary: | |
| Growth of the industry | [7] |
| Raw materials | [8] |
| Resins | [9] |
| The industry abroad | [10] |
| International trade | [10] |
| 3. | Tar-acid resins | [11] |
| The three stages of a tar-acid resin | [13] |
| Classification of tar-acid resins | [13] |
| Processes of resin manufacture | [14] |
| Production in the United States | [15] |
| Imports into the United States | [16] |
| Exports from the United States | [17] |
| Tar-acid resins for molding: | |
| Molding powders and pellets | [18] |
| The molding of tar-acid resins | [19] |
| Production of tar-acid molding resins | [19] |
| Cast phenolic resins: | |
| Process of manufacture | [20] |
| Uses | [20] |
| Patents and licensing | [21] |
| Production of cast phenolic resins | [21] |
| Imports and exports | [21] |
| Tar-acid resins for laminating | [21] |
| Uses of tar-acid resin laminated products | [22] |
| Production of tar-acid resins for laminating | [23] |
| Imports into the United States | [24] |
| Exports from the United States | [24] |
| Tar-acid resins for surface coatings: | |
| Types of resin used and the resultant coatings | [24] |
| Production in the United States | [25] |
| Imports into and exports from the United States | [25] |
| Tar-acid resins in adhesives | [25] |
| Tar-acid resins for other uses | [26] |
| 4. | Alkyd resins: | |
| Description and uses | [26] |
| Development and patents | [27] |
| Classification of alkyd resins: | |
| Unmodified drying alkyd resins | [28] |
| Drying alkyd resins, modified with natural materials | [29] |
| Drying alkyd resins, modified with other synthetic resins | [29] |
| Drying alkyd resins, modified with other synthetic resins and oil extended | [29] |
| Semidrying alkyd resins | [29] |
| Nondrying alkyd resins | [30] |
| Miscellaneous modified alkyd resins | [30] |
| Alkyd resins in water dispersion | [30] |
| Alkyd resins in molding compositions and other uses | [30] |
| Pigments and solvents in alkyd resins | [31] |
| Production in the United States | [31] |
| Imports into and exports from the United States | [32] |
| 5. | Urea resins: | |
| Description and uses | [32] |
| Production in the United States | [34] |
| United States imports and exports | [35] |
| 6. | Acrylate resins: | |
| Properties and uses | [35] |
| Production in the United States | [37] |
| Imports into and exports from the United States | [38] |
| 7. | Coumarone and indene resins: | |
| Description and uses | [38] |
| Production in the United States | [39] |
| Imports into and exports from the United States | [39] |
| 8. | Petroleum resins: | |
| Properties and uses | [39] |
| Production | [41] |
| Imports and exports | [41] |
| 9. | Polystyrene resins: | |
| Properties and uses | [41] |
| Production in the United States | [42] |
| Imports into and exports from the United States | [42] |
| 10. | Vinyl resins | [43] |
| Description and uses: | |
| Polyvinyl acetate resins | [44] |
| Copolymers of vinyl acetate and vinyl chloride | [46] |
| Polyvinyl chloride resins | [47] |
| Polyvinyl chloroacetate resins | [47] |
| Divinyl acetylene and synthetic rubber | [47] |
| Production in the United States | [48] |
| Imports into the United States | [48] |
| Exports from the United States | [50] |
| 11. | Other synthetic resins: | |
| Adipic acid resins | [50] |
| Aniline resins | [50] |
| Citric acid resins | [50] |
| Diphenyl resins | [51] |
| Furfural resins | [51] |
| Resins from sugar | [51] |
| Sulphonamide resins | [51] |
| 12. | The organization of the synthetic resin industry: | |
| Horizontal relationships between resin producers | [52] |
| Vertical relationships between resin producers: | |
| Tar-acid resins for molding | [53] |
| Tar-acid resins for laminating | [54] |
| Cast phenolic resins | [54] |
| Tar-acid resins for coatings | [55] |
| Tar-acid resins for miscellaneous uses | [55] |
| Alkyd resins made from phthalic anhydride | [55] |
| Alkyd resins made from maleic anhydride | [55] |
| Urea resins for molding | [56] |
| Urea resins for other uses | [56] |
| Coumarone and indene resins | [56] |
| Other resins | [56] |
| Relationship of the resin industry to other industries: | |
| The chemical industry | [56] |
| The surface-coating industry | [57] |
| The electric industry | [57] |
| The auto industry | [57] |
| 13. | The United States tariff and international trade in synthetic resins | [58] |
| Rapid expansion in home markets | [59] |
| The effect of patents on international trade | [59] |
| The United States tariff on resins and resin products: | |
| Synthetic resins | [60] |
| Articles made of synthetic resin | [61] |
| 14. | Synthetic resin prices, properties, and uses: | |
| Synthetic resins as substitutes | [62] |
| Motives for substitution | [63] |
| Materials displaced by synthetic resins | [63] |
| Competition between synthetic resins | [63] |
| Resins classified by cost | [64] |
| The physical properties of a resin and its uses | [65] |
| 15. | Synthetic resins in other countries: | |
| Germany: | |
| Production | [75] |
| Tar-acid resins | [75] |
| Alkyd resins | [76] |
| Urea resins | [76] |
| Polystyrene and vinyl resins | [76] |
| Uses of synthetic resins | [76] |
| Organization | [77] |
| Foreign trade | [77] |
| Great Britain: | |
| Production | [78] |
| Tar-acid resins | [79] |
| Urea resins | [79] |
| Acrylate resins | [79] |
| Aniline resin | [79] |
| Organization | [79] |
| Foreign trade | [80] |
| France: | |
| Producers | [80] |
| Foreign trade | [81] |
| Czechoslovakia | [82] |
| Italy | [82] |
| Japan | [83] |
| Production | [83] |
| Canada | [84] |
| Union of Soviet Socialist Republics | [85] |
| Netherlands | [85] |
| Denmark | [86] |
| Poland | [86] |
| 16. | Raw materials for alkyd resins | [86] |
| Naphthalene: | |
| Recovery of naphthalene | [87] |
| Description and uses | [87] |
| United States production | [88] |
| Organization of the industry | [89] |
| Trend of production | [89] |
| World production | [90] |
| Germany | [91] |
| Great Britain | [92] |
| Belgium | [93] |
| Czechoslovakia | [93] |
| France | [94] |
| Poland | [94] |
| Netherlands | [94] |
| Canada | [94] |
| Union of Soviet Socialist Republics | [94] |
| Japan | [94] |
| United States imports: | |
| Rates of duty | [95] |
| Import statistics | [96] |
| United States exports | [98] |
| Competitive conditions | [98] |
| Phthalic anhydride: | |
| Description and uses | [98] |
| United States production | [100] |
| Production in other countries | [101] |
| United States foreign trade | [101] |
| Competitive conditions | [101] |
| Polybasic acids other than phthalic anhydride: | |
| Maleic acid and anhydride | [102] |
| Malic acid and malomalic acid | [102] |
| Adipic acid | [102] |
| Succinic acid and anhydride | [102] |
| Fumaric acid | [102] |
| Glycerin: | |
| Description and uses | [103] |
| United States production | [103] |
| Production in other countries | [104] |
| International trade | [104] |
| United States imports | [105] |
| United States exports | [107] |
| Competitive conditions | [108] |
| 17. | Raw materials for tar-acid resins: | |
| The tar acids | [109] |
| Phenol: | |
| Description and uses | [110] |
| United States production | [111] |
| Grades produced for resins | [112] |
| Producers | [112] |
| World production | [113] |
| United States imports: | |
| Rates of duty | [114] |
| Import statistics | [114] |
| United States exports | [116] |
| Competitive conditions | [116] |
| The cresols, xylenols, and cresylic acid: | |
| Description and uses: | |
| The cresols | [117] |
| Metacresol | [118] |
| Orthocresol | [118] |
| Paracresol | [118] |
| Metaparacresol | [118] |
| Cresol | [118] |
| The xylenols | [118] |
| Other high-boiling tar acids | [119] |
| Cresylic acid | [119] |
| United States production: | |
| The cresols | [120] |
| The xylenols | [120] |
| Other high-boiling tar acids | [120] |
| Cresylic acid | [120] |
| Foreign production | [122] |
| United States imports: | |
| Rates of duty | [124] |
| Import statistics | [125] |
| United States exports | [131] |
| Competitive conditions | [131] |
| Synthetic tar acids other than phenol | [132] |
| Para tertiary amyl phenol | [133] |
| Para tertiary butyl phenol | [133] |
| Phenyl phenols | [133] |
| Resorcinol | [133] |
| Formaldehyde: | |
| Description and uses | [133] |
| United States production | [134] |
| Production in other countries | [134] |
| United States imports and exports | [134] |
| Competitive conditions | [135] |
| Hexamethylenetetramine: | |
| Description and uses | [136] |
| United States production | [136] |
| Production in other countries | [136] |
| United States imports and exports | [136] |
| Competitive conditions | [137] |
| Furfural | [137] |
| 18. | Raw materials for urea resins: | |
| Urea | [138] |
| Thiourea | [139] |
| 19. | Raw materials for vinyl resins: | |
| Description and uses | [140] |
| United States production | [140] |
| United States imports | [141] |
| Competitive conditions | [141] |
| APPENDIXES |
| Appendix A. Statistical tables on foreign trade in raw material for synthetic resins | [144] |
| Appendix B. Trade names for synthetic resins made in the United States | [153] |
| Appendix C. Trade names for synthetic resins made in Great Britain | [155] |
| Appendix D. Trade names for synthetic resins made in Germany | [156] |
| Appendix E. List of United States manufacturers of raw materials for synthetic resins | [158] |
| Appendix F. Glossary | [160] |
| TABLES |
| No. | | |
| 1. | Synthetic resins: United States production and sales, 1921-37 | [8] |
| 2. | Tar-acid resins: United States production and sales, by type of raw material, 1933-37 | [14] |
| 3. | Tar-acid resins: United States production and sales, 1927-37 | [15] |
| 4. | Synthetic resins of coal-tar origin: United States imports for consumption, 1919-37 | [16] |
| 5. | Synthetic resins of coal-tar origin: United States imports for consumption, by principal sources, in specified years 1929-37 | [17] |
| 6. | Cast phenolic resins: United States production and sales, 1934-37 | [21] |
| 7. | Alkyd resins from phthalic and maleic anhydride: United States production and sales, 1933-37 | [31] |
| 8. | Urea resins: United States production and sales, 1933-37 | [35] |
| 9. | Resoglas and Trolitul: United States imports for consumption, 1933-37 | [43] |
| 10. | Synthetic resins classified under paragraph 11: United States imports for consumption, 1931-37 | [49] |
| 11. | Vinyl acetate resins: United States imports for consumption, 1934-37 | [49] |
| 12. | Mowilith resins: United States imports for consumption, 1932-37 | [49] |
| 13. | Synthetic resins: United States production and imports, 1934-37 | [58] |
| 14. | Comparison of the international trade of the United States in synthetic resins and in certain raw materials for resins, 1934-37 | [58] |
| 15. | Tariff classification and rates of duty in Tariff act of 1930 upon certain articles made of synthetic resin | [61] |
| 16. | Manufactured articles n. s. p. f. in which synthetic resin is the chief binding agent: United States imports for consumption, 1931-37 | [62] |
| 17. | Synthetic resins and other plastics: Properties that affect appearance | [66] |
| 18. | Synthetic resins and other plastics: Molding properties | [68] |
| 19. | Synthetic resins and other plastics: Strength properties | [70] |
| 20. | Synthetic resins and other plastics: Heat properties | [71] |
| 21. | Synthetic resins and other plastics: Electrical properties | [72] |
| 22. | Synthetic resins and other plastics: Specific gravity, specific volume, and resistance to other substances | [73] |
| 23. | Synthetic resins: German exports, 1930-37 | [77] |
| 24. | Synthetic resins: German exports, by countries, 1934-37 | [78] |
| 25. | Synthetic resins: Production in Great Britain, 1934 and 35 | [78] |
| 26. | Synthetic resins: Imports into the United Kingdom, 1930-36 | [80] |
| 27. | Synthetic resins: Exports from the United Kingdom, 1930-36 | [80] |
| 28. | Synthetic resins: French imports, by types, and countries, 1931 and 1933-37 | [81] |
| 29. | Synthetic resins: French exports, 1931 and 1933-37 | [82] |
| 30. | Manufactures of tar-acid resins: Production in Japan, 1929-35 | [84] |
| 31. | Prices of gums and resins in the Netherlands, 1936 | [86] |
| 32. | Synthetic resins: Netherland imports by countries 1931 and 1933-37 | [86] |
| 33. | Crude naphthalene: United States production, 1918-37 | [88] |
| 34. | Refined naphthalene: United States production and sales, 1917-37 | [89] |
| 35. | Naphthalene (all grades): World production, by countries, 1933 and 1935 | [90] |
| 36. | Naphthalene: German production, imports, exports, and apparent consumption, 1928-37 | [92] |
| 37. | Naphthalene: Production in Great Britain, in specified years | [92] |
| 38. | Naphthalene: Exports from the United Kingdom, 1928-36 | [93] |
| 39. | Naphthalene: Belgian production, 1928-35 | [93] |
| 40. | Naphthalene: Czechoslovak production, 1928-35 | [93] |
| 41. | Crude naphthalene: Polish production, 1928-36 | [94] |
| 42. | Naphthalene: Rates of duty upon imports into the United States, 1916-38 | [95] |
| 43. | Crude naphthalene (solidifying at less than 79° C.): United States imports for consumption, 1919-37 | [96] |
| 44. | Refined naphthalene (solidifying at or above 79° C.): United States imports for consumption, 1919-37 | [96] |
| 45. | Crude naphthalene (solidifying under 79° C.): United States imports for consumption from principal sources, in specified years | [97] |
| 46. | Crude naphthalene: United States production, imports, and apparent consumption, in specified years | [98] |
| 47. | Phthalic anhydride: United States production and sales, 1917-37 | [100] |
| 48. | Glycerin: United States production, 1919-37 | [103] |
| 49. | Glycerin: United States production for sale, 1919-35 | [104] |
| 50. | Glycerin: Imports and exports of principal countries, 1931 and 1933-37 | [105] |
| 51. | Glycerin: United States imports for consumption, 1919-20 and 1923-37 | [106] |
| 52. | Crude glycerin: United States imports for consumption from Cuba, 1919-37 | [107] |
| 53. | Crude glycerin: United States imports for consumption from Philippine Islands, 1925-37 | [107] |
| 54. | Glycerin: United States exports, 1919-37 | [108] |
| 55. | Refined glycerin: United States production, imports, exports, and apparent consumption, in specified years | [108] |
| 56. | Tar acids: Commercial and chemical names, boiling points, and average percent in coal tar | [109] |
| 57. | Tar acids available in coal tar produced and distilled in 1936 | [110] |
| 58. | Phenol: Estimated consumption by industries, 1936-37 | [111] |
| 59. | Phenol: United States production and sales, in specified years, 1918-37 | [112] |
| 60. | Phenol: Estimated annual production, by countries, 1933-35 | [113] |
| 61. | Phenol: Rates of duty upon imports into the United States, 1916-37 | [114] |
| 62. | Phenol: United States imports for consumption, 1910-37 | [115] |
| 63. | All distillates of tar yielding below 190° C., an amount of tar acids equal to or more than 5 percent: United States imports for consumption, 1918-37 | [115] |
| 64. | Phenol: United States exports, 1918-24 | [116] |
| 65. | Phenol: United States exports, 1934-36 | [116] |
| 66. | Phenol: United States production, imports, exports, and apparent consumption, in specified years, 1918-37 | [117] |
| 67. | Meta, ortho, and para cresols: United States production and sales, 1934 | [120] |
| 68. | Refined cresylic acid: United States production and sales, 1929-37 | [121] |
| 69. | Cresol: German production, in specified years | [122] |
| 70. | Cresol: German imports and exports in specified years | [122] |
| 71. | Cresol: Production in Czechoslovakia in specified years | [123] |
| 72. | Cresylic acid: British exports, by countries, 1933-37 | [123] |
| 73. | The cresols: Rates of duty upon United States imports, 1916-37 | [124] |
| 74. | Cresylic acid: Rates of duty upon United States imports, 1916-37 | [125] |
| 75. | Metacresol, orthocresol, and paracresol, 90 percent or more pure: United States imports for consumption, 1920 and 1923-37 | [125] |
| 76. | Metacresol: United States imports for consumption by principal sources, in specified years | [126] |
| 77. | Orthocresol: United States imports for consumption by principal sources, in specified years | [127] |
| 78. | Paracresol: United States imports for consumption by principal sources, in specified years | [128] |
| 79. | Crude cresylic acid: United States imports for consumption, 1924-37 | [129] |
| 80. | Refined cresylic acid: United States imports for consumption, in specified years, 1919-37 | [129] |
| 81. | Crude cresylic acid: United States imports for consumption by principal sources, in specified years, 1929-37 | [130] |
| 82. | Refined cresylic acid: United States imports for consumption by principal countries, in specified years | [130] |
| 83. | The cresols: Comparison of production and imports, 1934 | [132] |
| 84. | Formaldehyde: United States production and sales, in specified years | [134] |
| 85. | Formaldehyde: United States exports to principal markets, in specified years | [135] |
| 86. | Hexamethylenetetramine: United States production and sales, 1923 and 1925-37 | [136] |
| 87. | Hexamethylenetetramine: United States imports for consumption, 1923-37 | [137] |
| 88. | Urea: United States imports for consumption, 1919-20 and 1923-37 | [138] |
| 89. | Urea: United States imports for consumption, by countries, 1931 and 1933-37 | [139] |
| 90. | Thiourea: United States imports through the New York customs district, 1931-37 | [140] |
| 91. | Vinyl acetate, unpolymerized: United States imports for consumption, 1931-37 | [141] |
| 92. | Naphthalene: German imports and exports, by countries, 1929 and 1932-37 | [144] |
| 93. | Crude naphthalene: Belgian imports and exports, 1932-37 | [146] |
| 94. | Refined naphthalene: Belgian imports and exports, 1932-37 | [147] |
| 95. | Crude and refined naphthalene: Netherland imports and exports, by countries, 1929 and 1932-37 | [148] |
| 96. | Refined naphthalene: Canadian imports, by countries, 1928-29 and 1932-37 | [150] |
| 97. | Naphthalene: Japanese imports by countries, 1928-29 and 1932-36 | [150] |
| 98. | Crude glycerin: United States imports for consumption, by countries, 1929 and 1931-37 | [151] |
| 99. | Refined glycerin: United States imports for consumption, by countries, 1929 and 1931-37 | [152] |
| ILLUSTRATIONS |
| Chart. Derivation of certain synthetic resins | [6] |
| Preform press making pellets for use in molding | [18] |
| Vacuum cleaner parts of tar-acid resin illustrating the intricate molded shapes possible | [19] |
| Radio cabinet and telephone sets of molded tar-acid resin | [19] |
| Cast phenolic resins. Standard shapes and small articles fabricated from them | [20] |
| Laminating sheet press | [22] |
| Gears made of laminated tar-acid resin | [22] |
| Cocktail lounge using tar-acid laminated decorative materials | [23] |
| Thermostat case of molded urea resin | [33] |
| Scales case of molded urea resin | [33] |
| Airplane cockpit enclosures of cast acrylate resin | [36] |
| Spectacle lenses molded to optical prescription from acrylate resin | [37] |
| Molded polystyrene resins | [42] |