LEACHING OF IGNEOUS ROCKS.
The arguments against the theory that mineral veins have been produced by the leaching of superficial igneous rocks are in part the same as those already cited against the general theory of lateral secretion. They may be briefly summarized as follows:
1. Thousands of mineral veins in this and other countries occur in regions remote from eruptive rocks. Into this category come most of those of the eastern half of the Continent, viz., Canada, New England, the Alleghany belt, and the Mississippi Valley. Among those I will refer only to a few selected to represent the greatest range of character, viz., the Victoria lead mine, near Sault Ste. Marie, the Bruce copper mine on Lake Huron, the gold-bearing quartz veins of Madoc, the Gatling gold vein of Marmora, the Acton and the Harvey Hill copper mines of Canada, the copper veins of Ely, Vermont, and of Blue Hills, Maine, the silver-bearing lead veins of Newburyport, Mass.; most of the segregated gold veins of the Alleghany belt, the lead veins of Rossie, Ellenville, and at other localities farther South; the copper bearing veins of Virginia, North Carolina, and Tennessee; the veins carrying argentiferous galena in Central Kentucky and in Southern Illinois; the silver, copper, and antimony veins of Arkansas; and the lead and zinc deposits of Missouri and the Upper Mississippi.
In these widely separated localities are to be found fissure, segregated, and gash veins, and a great diversity of ores, which have been derived, sometimes from the adjacent rocks--as in the segregated veins of the Alleghany belt and the gash veins of the Mississippi region--and in other cases--where they are contained in true fissure veins--from a foreign source, but all deposited without the aid of superficial igneous rocks, either as contributors of matter or force.
2. In the great mineral belt of the Far West, where volcanic emanations are so abundant, and where they have certainly played an important part in the formation of ore deposits, the great majority of veins are not in immediate contact with trap rocks, and they could not, therefore, have furnished the ores.
A volume might be formed by a list of the cases of this kind, but I can here allude to a few only, most of which I have myself examined, viz.:
(a.) The great ore chambers of the San Carlos Mountains in Chihuahua, the largest deposits of ore of which I have any knowledge. These are contained in heavy beds of limestone, which are cut in various places by trap dikes, which, as elsewhere, have undoubtedly furnished the stimulus to chemical action that has resulted in the formation of the ore bodies, but are too remote to have supplied the material.
(b.) The silver mines of Santa Eulalia, in Chihuahua, from which during the last century one hundred and twelve millions of dollars were taken, opened on ore deposits situated in Cretaceous limestones like those of San Carlos, and apparently similar ore-filled chambers; an igneous rock caps the hills in the vicinity, but is nowhere in contact or even proximity to the ore bodies. (See Kimball, Amer. Jour. Sci,. March, 1870.)
(c.) The great chambers of Tombstone, and the copper veins of the Globe District, the Copper Queen, etc., in Arizona.
(d.) The large bodies of silver-ore at Lake Valley, New Mexico; chambers in limestone, like c.
(e.) The Black Hawk group of gold mines, the Montezuma, Georgetown, and other silver mines in the granite belt of Colorado.
(f.) The great group of veins and chambers in the Bradshaw, Lincoln, Star, and Granite districts of Southern Utah, where we find a host of veins of different character in limestone or granite, with no trap to which the ores can be credited.
(g.) The Crismon Mammoth vein of Tintic.
(h.) The group of mines opened on the American Fork, on Big and Little Cottonwood, and in Parley's Park, including the Silver Bell, the Emma, the Vallejo, the Prince of Wales, the Kessler, the Bonanza, the Climax, the Piñon, and the Ontario. (The latter, the greatest silver mine now known in the country, lies in quartzite, and the trap is near, but not in contact with the vein.)
(i.) In Nevada, the ore deposits of Pioche, Tempiute, Tybo, Eureka, White Pine, and Cherry Creek, on the east side of the State, with those of Austin, Belmont, and a series too great for enumeration in the central and western portions.
(j.) In California, the Bodie, Mariposa, Grass Valley, and other mines.[1]
(k.) In Idaho, those of the Poor Man in the Owyhee district, the principal veins of the Wood River region, the Ramshorn at Challis, the Custer and Charles Dickens, at Bonanza City, etc.
[Footnote 1: See Redmond's Report (California Geol. Survey Mining Statistics, No 1), where seventy-seven mines are enumerated, of which three are said to be in "porphyritic schist," all the others in granite, mica schist, clay, slate, etc.]
In nearly all these localities we may find evidence not only that the ore deposits have not been derived from the leaching of igneous rocks, but also that they have not come from those of any kind which form the walls of the veins.
The gold-bearing quartz veins of Deadwood are so closely associated with dikes of porphyry, that they may have been considered as illustrations of the potency of trap dikes in producing concentration of metals. But we have conclusive evidence that the gold was there in Archæan times, while the igneous rocks are all of modern, probably of Tertiary, date. This proof is furnished by the "Cement mines" of the Potsdam sandstone. This is the beach of the Lower Silurian sea when it washed the shores of an Archæan island, now the Black Hills. The waves that produced this beach beat against cliffs of granite and slate containing quartz veins carrying gold. Fragments of this auriferous quartz, and the gold beaten out of them and concentrated by the waves, were in places buried in the sand beach in such quantity as to form deposits from which a large amount of gold is now being taken. Without this demonstration of the origin and antiquity of the gold, it might very well have been supposed to be derived from the eruptive rock.
Strong arguments against the theory that the leaching of superficial igneous rocks has supplied the materials filling mineral veins, are furnished by the facts observed in the districts where igneous rocks are most prevalent, viz.: (1.) Such districts are proverbially barren of useful minerals. (2.) Where these occur, the same sheet of rock may contain several systems of veins with different ores and gangues.
The great lava plain of Snake River, the Pedrigal country of eastern Oregon, Northern California and Mexico are without valuable ore deposits. The same may be said of the Pancake Range and other mountain chains of igneous rock in Nevada, while the adjacent ranges composed of sedimentary rocks are rich in ore deposits of various kinds. A still stronger case is furnished by the Cascade Mountains, which, north of the California line, are composed almost exclusively of erupted material, and yet in all this belt, so far as now known, not a single valuable mine has been opened. In contrast with this is the condition of things in California, where the Sierra Nevada is composed of metamorphic rocks which have been shown to be the repositories of vast quantities of gold, silver, and copper. Cases belonging to this category may be found at Rosita and Silver Cliff, where the diversity in the ores of the mines already enumerated can hardly be reconciled with the theory of a common origin. At Lake City the prevailing porphyry holds the veins of the Ute and Ulay and the Ocean Wave mines, which are similar, and the Hotchkiss, the Belle, etc., entirely different.
We have no evidence that any volcanic eruption has drawn its material from zones or magmas especially rich in metals or their ores, and on the contrary, volcanic districts, like those mentioned, and regions, such as the Sandwich Islands, where the greatest, eruptions have taken place, are poorest in metalliferous deposits.
All the knowledge we have of the subject justifies the inference that most of the igneous rocks which have been poured out in our Western Territories are but fused conditions of sediments which form the substructure of that country. Over the great mineral belt which lies between the Sierra Nevada and the front range of the Rocky Mountains, and extends not only across the whole breadth of our territory, but far into Mexico, the surface was once underlain by a series of Palaeozoic sedimentary strata not less than twenty to thirty thousand feet in thickness; and beneath these, at the sides, and doubtless below, were Archæun rocks, also metamorphosed sediments. Through these the ores of the metals were generally though sparsely distributed. In the convulsions which have in recent times broken up this so long quiet and stable portion of the earth's crust (and which have resulted in depositing in thousands of cracks and cavities the ores we now mine), portions of the old table-land were in places set up at high angles forming mountain chains, and doubtless extending to the zone of fusion below. Between these blocks of sedimentary rocks oozed up through the lines of fracture quantities of fused material, which also sometimes formed mountain chains; and it is possible and even probable that the rocks composing the volcanic ridges are but phases of the same materials that form the sedimentary chains There is, therefore, no a priori reason why the leaching of one group should furnish more ore than the other; but, as a matter of fact, the unfused sediments are much the richer in ore deposits. This can only be accounted for, in my judgment, by supposing that they have been the receptacles of ore brought from a foreign source; and we can at least conjecture where and how gathered. We can imagine, and we are forced to conclude, that there has been a zone of solution below, where steam and hot water, under great pressure, have effected the leaching of ore-bearing strata, and a zone of deposition above, where cavities in pre-existent solidified and shattered rocks became the repositories of the deposits made from ascending solutions, when the temperature and pressure were diminished. Where great masses of fused material were poured out, these must have been for along time too highly heated to become places of deposition; so long indeed that the period of active vein formation may have passed before they reached a degree of solidification and coolness that would permit their becoming receptacles of the products of deposition. On the contrary, the masses of unfused and always relatively cool sedimentary rocks which form the most highly metalliferous mountain ranges (White Pine, Toyabe, etc.) were, throughout the whole period of disturbance, in a condition to become such repositories. Certainly highly heated solutions forced by an irresistible vis a tergo through rocks of any kind down in the heated zone, would be far more effective leaching agents than cold surface water with feeble solvent power, moved only by gravity, percolating slowly through superficial strata.
Richthofen, who first made a study of the Comstock lode, suggests that the mineral impregnation of the vein was the result of a process like that described, viz., the leaching of deep-seated rocks, perhaps the same that inclose the vein above, by highly heated solutions which deposited their load near the surface. On the other hand, Becker supposes the concentration to have been effected by surface waters flowing laterally through the igneous rocks, gathering the precious metals and depositing them in the fissure, as lateral secretion produces the accumulation of ore in the limestone of the lead region. But there are apparently good reasons for preferring the theory of Richthofen: viz., first, the veinstone of the Comstock is chiefly quartz, the natural and common precipitate of hot waters, since they are far more powerful solvents of silica than cold. On the contrary, the ores deposited from lateral secretion, as in the Mississippi lead region, at low temperature contain comparatively little silica; second, the great mineral belt to which reference has been made above is now the region where nearly all the hot springs of the continent are situated. It is, in fact, a region conspicuous for the number of its hot springs, and it is evident that these are the last of the series of thermal phenomena connected with the great volcanic upheavals and eruptions, of which this region has been the theater since the beginning of the Tertiary age. The geysers of Yellowstone Park, the hot springs of the Wamchuck district in Oregon, the Steamboat Springs of Nevada, the geysers of California, the hot springs of Salt Lake City, Monroe, etc., in Utah, and the Pagosa in Colorado, are only the most conspicuous among thousands of hot springs which continue in action at the present time. The evidence is also conclusive that the number of hot springs, great as it now is in this region, was once much greater. That these hot springs were capable of producing mineral veins by material brought up in and deposited from their waters, is demonstrated by the phenomena observable at the Steamboat Springs, and which were cited in my former article as affording the best illustration of vein formation.
The temperature of the lower workings of the Comstock vein is now over 150°F., and an enormous quantity of hot water is discharged through the Sutro Tunnel. This water has been heated by coming in contact with hot rocks at a lower level than the present workings of the Comstock lode, and has been driven upward in the same way that the flow of all hot springs is produced. As that flow is continuous, it is evident that the workings of the Comstock have simply opened the conduits of hot springs, which are doing to-day what they have been doing in ages past, but much less actively, i.e., bringing toward the surface the materials they have taken into solution in a more highly heated zone below. Hence it seems much more natural to suppose that the great sheets of ore-bearing quartz now contained in the Comstock fissure were deposited by ascending currents of hot alkaline waters, than by descending currents of those which were cold and neutral The hot springs are there, though less copious and less hot than formerly, and the natural deposits from hot waters are there. Is it not more rational to suppose with Richthofen that these are related as cause and effect, rather than that cold water has leached the ore and the silica from the walls near the surface? Mr. Becker's preference for the latter hypothesis seems to be due to the discovery of gold and silver in the igneous rocks adjacent to the vein, and yet, except in immediate contact with it, these rocks contain no more of the precious metals than the mere trace which by refined tests may be discovered everywhere. If, as we have supposed, the fissure was for a long time filled with a hot solution charged with an unusual quantity of the precious metals, nothing would be more natural than that the wall rocks should be to some extent impregnated with them.
It will perhaps illuminate the question to inquire which of the springs and water currents of this region are now making deposits that can be compared with those which filled the Comstock and other veins. No one who has visited that country will hesitate to say the hot and not the cold waters. The immense silicious deposits, carrying the ores of several metals, formed by the geysers of the Yellowstone, the Steamboat Springs, etc., show what the hot waters are capable of doing; but we shall search in vain for any evidence that the cold surface waters have done or can do this kind of work.
At Leadville the case is not so plain, and yet no facts can be cited which really prove that the ore deposits have been formed by the leaching of the overlying porphyry rather than by an outflow of heated mineral solutions along the plane of junction between the porphyry and the limestone. Near this plane the porphyry is often thoroughly decomposed, is somewhat impregnated with ore, and even contains sheets of ore within itself; but remote from the plane of contact with the limestone, it contains little diffused and no concentrated ore. It is scarcely more previous than the underlying limestones, and why a solution that could penetrate and leach ores from it should be stopped at the upper surface of the blue limestone is not obvious; nor why the plane of junction between the porphyry and the blue limestone should be the special place of deposit of the ore.
If the assays of the porphyry reported by Mr. Emmons were accurately made, and they shall be confirmed by the more numerous ones necessary to settle the question, and the estimates he makes of the richness of that rock be corroborated, an unexpected result will be reached, and, as I think, a remarkable and exceptional case of the diffusion of silver and lead through an igneous rock be established.
It is of course possible that the Leadville porphyries are only phases of rocks rich in silver, lead, and iron, which underlie this region, and which have been fused and forced to the surface by an ascending mass of deeper seated igneous rock; but even if the argentiferous character of the porphyry shall be proved, it will not be proved that such portions of it as here lie upon the limestone have furnished the ore by the descending percolation of cold surface waters. Deeper lying masses of this same silver, lead, and iron bearing rock, digested in and leached by hot waters and steam under great pressure, would seem to be a more likely source of the ore. If the surface porphyry is as rich in silver as Mr. Emmous reports it to be, it is too rich, for the rock that has furnished so large a quantity of ores as that which formed the ore bodies which I saw in the Little Chief and Highland Chief mines, respectively 90 feet and 162 feet thick, should be poor in silver and iron and lead, and should be rotten from the leaching it had suffered, but except near the ore-bearing contact it is compact and normal.
Such a digested, kaolinized, desilicated rock as we would naturally look for we find in the porphyry near the contact; and its condition there, so different from what it is remote from the contact, seems to indicate an exposure to local and decomposing influences, such indeed as a hot chemical solution forced up from below along the plane of contact would furnish.
It is difficult to understand why the upper portions of the porphyry sheet should be so different in character, so solid and homogeneous, with no local concentrations or pockets of ore, if they have been exposed to the same agencies as those which have so changed the under surface.
Accepting all the facts reported by Mr. Emmons, and without questioning the accuracy of any of his observations, or depreciating in any degree the great value of the admirable study he has made of this difficult and interesting field, his conclusion in regard to the source of the ore cannot yet be insisted on as a logical necessity. In the judgment of the writer, the phenomena presented by the Leadville ore deposits can be as well or better accounted for by supposing that the plane of contact between the limestone and porphyry has been the conduit through which heated mineral solutions coming from deep seated and remote sources have flowed, removing something from both the overlying and underlying strata, and by substitution depositing sulphides of lead, iron, silver, etc., with silica.
The ore deposits of Tybo and Eureka in Nevada, of the Emma, the Cave, and the Horn Silver [1] mines in Utah, have much in common with those of Leadville, and it is not difficult to establish for all of the former cases a foreign and deep seated source of the ore. The fact that the Leadville ore bodies are sometimes themselves excavated into chambers, which has been advanced as proof of the falsity of the theory here advocated, has no bearing on the question, as in the process of oxidation of ores which were certainly once sulphides, there has been much change of place as well as character; currents of water have flowed through them which have collected and redeposited the cerusite in sheets of "hard carbonate" or "sand carbonate," and have elsewhere produced accumulations of kerargyrite, perhaps thousands of years after the deposition of the sulphide ores had ceased and the oxidation had begun. In the leaching and rearrangement of the ore bodies, nothing would be more natural than that accumulations in one place should be attended by the formation of cavities elsewhere.
[Footnote 1: The Horn Silver ore body lies in a fault fissure between a footwall of limestone and a hanging wall of trachyte, and those who consider the Leadville ores as teachings of the overlying porphyry would probably also regard the ore of the Horn Silver mine as derived from the trachyte hanging wall; but three facts oppose the acceptance of this view, viz., let, the trachyte, except in immediate contact with the ore body, seems to be entirely barren; 2d, the Horn Silver ore "chimney," perhaps fifty feet thick, five hundred feet wide, and of unknown depth, is the only mass of ore yet found in a mile of well marked fissure; and 3d, the Carbonate mine opened near by in a strong fissure with a bearing at right angles to that of the Horn Silver, and lying entirely within the trachyte, yields ore of a totally different kind. Both are opened to the depth of seven hundred feet with no signs of change or exhaustion. If the ore were derived from the trachyte, it should be at least somewhat alike in the two mines, should be more generally distributed in the Horn Silver fissure, and might be expected to give out at, no great depth.
If deposited by solutions coming from deep and different sources, the observed differences in character would be natural; it would accumulate as we find it in the channels of outflow, and would be as time will probably prove it, perhaps variable in quantity, but indefinitely continuous in depth.]
Another question which suggests itself in reference to the Leadville deposits is this: If the Leadville ore was once a mass of sulphides derived from the overlying porphyry by the percolation of surface waters, why has the deposit ceased? The deposition of galena, blende, and pyrite in the Galena lead mines still continues. If the leaching of the Leadville porphyry has not resulted in the formation of alkaline sulphide solutions, and the ore has come from the porphyry in the condition of carbonate of lead, chloride of silver, etc., then the nature of the deposition was quite different from that of the similar ones of Tybo, Eureka, Bingham, etc., which are plainly gossans, and indeed is without precedent. But if the process was similar to that in the Galena lead region, and the ores were originally sulphides, their formation should have continued and been detected in the Leadville mines.
For all these reasons the theory of Mr. Emmons will be felt to need further confirmation before it is universally adopted.
From what has gone before it must not be inferred that lateral secretion is excluded by the writer from the list of agencies which have filled mineral veins, for it is certain that the nature of the deposit made in the fissure has frequently been influenced by the nature of the adjacent wall rock. Numerous cases may be cited where the ores have increased or decreased in quantity and richness, or have otherwise changed character in passing from one formation to another; but even here the proof is generally wanting that the vein materials have been furnished by the wall rocks opposite the places where they are found.
The varying conductivity of the different strata in relation to heat and electricity may have been an important factor. Trap dikes frequently enrich veins where they approach or intersect them, and they have often been the primum mobile of vein formation, but chiefly, if not only, by supplying heat, the mainspring of chemical action. The proximity of heated masses of rock has promoted chemical action in the same way as do the Bunsen burners or the sand baths in the laboratory; but no case has yet come under my observation where it was demonstrable that the filling of a fissure vein had been due to secretion from igneous or sedimentary wall rocks.
In the Star District of Southern Utah the country rock is Palæozoic limestone, and it is cut by so great a number and variety of mineral veins that from the Harrisburg, a central location, a rifle shot would reach ten openings, all on as many distinct and different veins (viz., the Argus, Little Bilk, Clean Sweep, Mountaineer, St. Louis, Xenia, Brant, Kannarrah, Central, and Wateree). The nearest trap rock is half a mile or more distant, a columnar dike perhaps fifteen feet in thickness, cutting the limestone vertically. On either side of this dike is a vein from one to three feet in thickness, of white quartz with specks of ore. Where did that quartz come from? From the limestone? But the limestone contains very little silica, and is apparently of normal composition quite up to the vein. From the trap? This is compact, sonorous basalt, apparently unchanged; and that could not have supplied the silica without complete decomposition.
I should rather say from silica bearing hot waters that flowed up along the sides of the trap, depositing there, as in the numerous and varied veins of the vicinity, mineral matters brought from a zone of solution far below.
To summarize the conclusions reached in this discussion. I may repeat that the results of all recent as well as earlier observations has been to convince me that Richthofen's theory of the filling of the Comstock lode is the true one, and that the example and demonstration of the formation of mineral veins furnished by the Steamboat Springs is not only satisfactory, but typical.
[NATURE.]