SMOKELESS GUNPOWDER.
By HUDSON MAXIM.
During the last forty years leading chemists have continued to experiment with a view to the production of a gunpowder which should be smokeless. But not until the last few years has any considerable degree of success been attained.
To be smokeless, a gunpowder must yield only gaseous products of combustion. None of the so-called smokeless powders are entirely smokeless, although some of them are very nearly so.
The smoke of common black gunpowder is largely due to minute particles of solid matter which float in the air. About one-half of the total products of combustion of black gunpowder of ordinary composition consists of potassium carbonate in a finely divided condition and of potassium sulphate, which is produced chiefly by the burning in the air of potassium sulphide, another production of combustion, as on the outrushing gases it is borne into the air in a fine state of division.
Another cause for the smoke of gunpowder is the formation of small liquid vesicles which condense from some of the products of combustion thrown into the air in a state of vapor, in the same manner as vesicles of aqueous vapor form in the air on the escape of highly heated steam from the whistle of a locomotive.
Broadly speaking, an explosive compound is one which contains, within itself, all the elements necessary for its complete combustion, and whose heated gaseous products occupy vastly more space than the original compound. Such compound usually consists of oxygen, associated with other elements, for which it has great affinity, and from which it is held from more intimate union, or direct chemical combination, under normal conditions, by being in combination as well with other elements for which it has less affinity, but which it readily gives up for the stronger affinities when explosion takes place, the other elements either combining with one another to form new compounds or being set free in an uncombined state.
An explosive is said to detonate when the above changes take place instantaneously, the action being transmitted with the speed of electricity by a sort of molecular rhythm from molecule to molecule throughout the entire substance of the compound.
An explosive is said to explode when the above changes do not occur instantaneously throughout the whole substance, but whose combustion takes place from the surface inward of the particles or grains of which it is composed, thus requiring some definite lapse of time.
The elements of an explosive compound may be associated chemically as in nitro-glycerine and gun-cotton, which are chemical compounds, being the results of definite reactions. Or, an explosive may be a mere mechanical mixture of different substances comprising the necessary elements, as is ordinary black gunpowder, which is a compound of charcoal, sulphur and saltpeter, the saltpeter supplying the necessary oxygen.
No gunpowder can be smokeless in which saltpeter or any oxygen-bearing salt having a metallic base is employed, for when the salt gives up its oxygen, the base combines with other elements to produce a sulphate, a carbonate, or other salt, which, being solid, produces smoke. Therefore, to be smokeless, a gunpowder must contain no other elements than oxygen, hydrogen, nitrogen, and carbon, and in such proportions that the products of combustion shall be wholly gaseous. The nitric ethers--gun-cotton and nitro-glycerine--constitute such explosive compounds. These substances were formerly thought to be nitro-substitution compounds, but are now known to belong to the compound ethers of nitric acid.
Gun-cotton, discovered by Schonbein, in 1845, has since been looked upon as the most promising material for a smokeless gunpowder, it being a very powerful explosive and burning with practically no smoke. To-day, gun-cotton, in some form or other, constitutes the base of substantially all of the smokeless powders with which have been attained any considerable degree of success.
Gun-cotton alone and in its fibrous state has been found to be too quick, or violent, for propulsive purposes, such as use in firearms; as under such conditions of confinement it is very likely to detonate and burst the gun. However, if gun-cotton be dissolved in a suitable solvent, which is capable of being evaporated out, such as acetone, or acetate of ethyl, which are very volatile, it becomes, when thus dissolved and dried, a very hard, horn-like, amorphous substance, which may be used for a smokeless gunpowder. But this substance taken alone is very difficult to mould or granulate, and the loss of expensive solvents must necessarily be quite considerable.
When gun-cotton is reduced to a collodial solid, as above, and used as a smokeless gunpowder, the grains must be made comparatively small to insure prompt and certain ignition, and consequently the pressures developed in the gun are apt to be too great when charges sufficiently large are used to give desired velocities.
If, however, a compound be made of gun-cotton and nitro-glycerine, in about equal parts, by means of a volatile solvent or combining agent, such as one of the before mentioned, and the solvent evaporated out, we obtain practically a new substance and one which, as regards its explosive nature, is quite unlike either of its two constituents taken alone. The nitro-glycerine, furthermore, being itself a solvent of gun-cotton, much less of the volatile ether is necessary to render the compound of an amorphous character. Being quite plastic this substance may be wrought or moulded into any desired size or form of grain.
This simple compound of nitro-glycerine and gun-cotton, or with some slight modifications, has been found, when properly granulated, to be the most smokeless powder that has yet been discovered or invented. If pure chemicals are employed in the manufacture, and the gun-cotton and nitro-glycerine be made of the highest nitration and best quality, we have a smokeless powder which will possess the following desirable qualities:
1st. It is absolutely smokeless, that is, its products of combustion are entirely gaseous.
2d. Its products of combustion are in no way deleterious or unpleasant.
3d. It is perfectly safe to manufacture, handle and transport. There is no more danger of its exploding accidentally than there would be of an explosion of shavings or sawdust; for, unless well confined and set off with a strong primer, it will not explode at all. In the open its combustion is so slow as to in no way resemble or partake of the nature of an explosion.
4th. It is perfectly stable, and will keep any length of time absolutely without undergoing any change whatever, under all conditions of temperature or exposure to which gunpowder would ever be subjected.
5th. It is not hygroscopic, and may be soaked in water without being at all affected by it.
6th. It will not corrode the cartridge case.
7th. It will not foul the gun.
8th. It is sure of ignition with a good primer, and may be made to burn as slowly as desired by varying the character and size of the grains. Indeed, it may be made to burn so slowly as to fail of complete combustion before the bullet leaves the gun, and after firing several rounds, partly burned pieces of the powder may be picked up in front of the gun.
9th. In a shoulder arm, a velocity of 2,000 feet per second may be imparted to the bullet with this powder, and with a pressure in the chamber of the gun of not more than fifteen English tons. This is, of course, when the gun, cartridge case, primer, and projectile are adapted to the use of smokeless powder, and the granulation of the powder is adapted to them.
If what I have here claimed for the above smokeless powder be true, it would appear that it may be taken as really an ideal smokeless powder. Why, then, has it not already been universally adopted? Surely such a powder is just what every government is seeking. In reply to this, let me say that, in order for the above compound to be an effective and successful smokeless powder, with the manifestation of the many desirable qualities which I have recited, a great many other conditions are necessary, some of which I will mention. To arrive at the knowledge that this compound would constitute the best smokeless powder has required a great deal of experimenting. It was first thought that gun-cotton colloid, without any nitro-glycerine, that is, gun-cotton dissolved and dried, would burn more slowly, keep better, and give better ballistics than it would if combined with nitro-glycerine. It was also thought that gun-cotton of a high degree of nitration when made into colloidal form would even then burn too quickly to be suitable for use in firearms. Consequently, the first experiments were with low grade gun-cotton, what is called collodion cotton, such as is employed in the manufacture of celluloid. But, as this would not explode without the addition of some oxygen-bearing element, various oxygen-bearing salts were combined with it, such as nitrate of potassium, nitrate of ammonia, nitrate of baryta, etc. Also a great many of the first smokeless powders were made of low grade gun-cotton combined with nitro-glycerine in varying proportions. These powders would often give very good results when first made; but low grade gun-cotton or di-nitro-cellulose, as it is called, is a very unstable compound, and these powders, after giving very promising results, were found to be constantly undergoing change, sooner or later resulting in complete decomposition.
When nitro-glycerine was first combined with gun-cotton in small quantities, camphor was often added, to lessen the rapidity of combustion which the nitro-glycerine was supposed to impart and also to render the compound more plastic, and to tend to prevent the decomposition of the low grade gun-cotton. But camphor being volatile, would, by its evaporation, cause the powder to constantly change in character. Castor oil has been found to be a better diluent, as this will not evaporate.
As all of the smokeless powders made of a low grade gun-cotton were found to deteriorate and spoil, experiments were made with gun-cotton of the highest degree of nitration, both alone and in combination with nitro-glycerine. These experiments were first conducted in England by private parties and by the British government, when it was found that high grade gun-cotton would give excellent results if made into a colloidal solid and used alone, or in combination with certain other constituents. With a view to saving the large quantity of solvents necessary to reduce the gun-cotton, and to get a more prompt and certain ignition with a larger grain, experiments were cautiously made by the admixture of varying proportions of nitro-glycerine to the gun-cotton when dissolved, or rather along with other solvents in the process of dissolving it.
It was soon found that nitro-glycerine added in quantities, even equal in weight to the gun-cotton itself, did not materially increase the rapidity of the explosion of the compound. And it was also found that high grade gun-cotton, when combined with nitro-glycerine, gave very much better results than low grade gun-cotton.
I have spoken here of high and low grade gun-cotton, when in fact the word gun-cotton should be applied only to the highest nitro-compound of cellulose. The word gun cotton has always been rather loosely used. Pyroxyline would be a better word, as this applies to all grades. When cotton fiber is soaked in a large excess of a mixture of the strongest nitric and sulphuric acids, gun-cotton proper, or that of the highest grade, is produced. When weaker acids are used, lower grades of nitro-cellulose are formed.
The first mentioned or highest grade gun-cotton, when thoroughly freed from its acids, has always proved to be a perfectly stable compound. The lower grades have always been found to be unstable and subject to spontaneous decomposition. Nitro-glycerine has also been erroneously thought to be a very unstable compound. But experiments have proved that, when made pure, it is perfectly stable.
Having now explained how the knowledge came to be arrived at that the aforementioned compound of highest grade nitro-glycerine and highest grade gun-cotton would constitute the best basis for a smokeless powder, I will now mention a few of the other conditions necessary to success with its use, without assuming that smokeless powder has yet passed its experimental stage, and is beyond further improvement. Nevertheless, such is the compound which has come to stay as the basis of all smokeless powders; and any smokeless powder, if a successful one, may be counted upon as being made of this compound of gun-cotton and nitro-glycerine, or of a colloid of gun-cotton, either alone or combined with diluents, oxygen-bearing salts, or inert matter. The fact that smokeless powder may still be said to be in somewhat of an experimental stage is not to admit that it is not a success. Firearms, cartridge cases, and projectiles are also still in an experimental stage, for they are constantly being improved; yet their use has been a great success for a good many years.
The question of success of a smokeless powder does not rest alone with the powder itself. The gun, the cartridge case, primer, and bullet have been as much the subjects of experiments in adapting them to the use of smokeless powder as has the smokeless powder in being adapted to them. To impart a velocity of 2,000 feet per second to a rifle ball, with corresponding long range and accuracy of flight, has been a question as much of improvement in rifles and projectiles as in the powder. To give a velocity of 2,000 feet per second to a bullet, requires a pressure of at least 15 English tons in the chamber of a gun. This would be a dangerous pressure in an old-fashioned shoulder arm; while a bullet made only of lead would strip on striking the rifling and pass right through the barrel of the gun without taking any rotary motion whatever. It might at first seem that the powder is the only thing to be considered; but high ballistics can only be obtained when everything else is adapted to its use.
The projectile, the cartridge case, the fulminating cap, and the gun have had to be all built up together, and a very large amount of experimenting has been necessary to determine what would constitute the best projectile, best cartridge case, best fulminating cap, and what should be the character of the rifling and the quality and temper of the steel of the gun barrel.
It has been necessary first to conduct experiments to test the smokeless powders for velocities and pressures, and then with the powders test various kinds of projectiles and guns. In order to obtain the high ballistics which have been secured, it has been found necessary to cover the bullet with something harder than lead and to rifle the gun in a special manner.
The French, who were the first to definitely adopt smokeless powder, were the first also to make a rifle, projectile, cartridge case and primer suited to its use.
To obtain long range with a small long bullet such as is now used, it should rotate at a very high speed. It is well known to artillerists that a projectile of four or more calibers in length has to be rotated at a much higher speed than one of half that length, in order to keep the projectile stiff in the air, and to prevent it from ending over in its flight. To communicate this very high rotary movement to the bullet in the instant of time during which it is passing through the barrel, the rifling of the gun has to exert an enormous torsion on the bullet. Lead, no matter how hardened, is not sufficiently strong, as it will not only strip and pass straight through the gun without taking any rotary movement whatever, but under such very high pressures it behaves like wax, and is thrown from the gun in a distorted mass.
The French cover their bullets with German silver, a substance made of nickel, zinc and copper; and in order to put as little strain upon the rifling and projectile as possible, the rifling of the gun is made with an increasing twist, and has no sharp edges. The French rifle is made very strong at the breech and is of tempered steel throughout. In this way the French have made smokeless powder a success--a smokeless powder made substantially of a character such as I have herein described. With smokeless powder, the French rifle imparts a muzzle velocity of 2,000 feet per second to the bullet, with a range of about 2,400 meters.
If smokeless powder be divided into sufficiently small grains to be ignited by an ordinary fulminating cap, it would burn too quickly, thereby causing the pressure to mount too high, and without giving the desired velocity. Consequently very large and strong fulminating caps have to be employed. Smokeless powder is not ignited in the same manner as black powder. Something besides ignition is necessary. Black powder simply requires to be set on fire; while a smokeless powder, on the contrary, not only requires that it be set on fire, but that a certain degree of pressure be set up inside of the cartridge case. For instance, if a primer of a certain size should be found to operate perfectly well, giving prompt ignition in the cartridge case of a rifle of small caliber, it would be found that the same primer would not ignite a charge of the same powder if loaded into a gun of one inch caliber. In the latter case a few grains only lying near the primer would be ignited, and these would soon become extinguished by sudden release of pressure bringing about a cooling effect due to expansion of the gases. In small cartridges a large fulminating cap is all that is required, but in large cartridges it is necessary to resort to additional means of ignition.
In France, where experiments were conducted with a 37 millimeter Maxim gun, it was found to be impracticable to use a fulminating cap sufficiently large to ignite the powder and cause it to burn. Therefore, a small ignition charge of black powder was employed, it being put in a capsule or bag and placed next the primer. On firing at the rate of 300 rounds per minute, the black powder, though small in quantity, produced a cloud of smoke through which it was quite impossible to see. The inventor of the gun then prepared for the French some wafers of pyroxyline canvas, which were placed next to the primer, securing thereby prompt ignition without the production of any smoke.
Smokeless powder, made as I have described, cannot be detonated by a fulminating cap of any size or by any means whatever. A large charge of fulminate of mercury placed inside the cartridge case next the primer will not detonate the powder, it serving only to ignite it and cause it to explode. But even this would not cause the powder to explode except it be confined behind a projectile, that sufficient pressure may be run up to make it burn in its own gases.
Some curious experiments with smokeless powder may be tried with a shot gun. If the fulminating cap be large, the powder fine, the wads numerous and hard and the charge of shot heavy, all being well rammed down, and the paper case well spun over the last pasteboard wad, a charge of smokeless powder about equal in weight to one-half of what would be employed of black powder would give about the same results as black powder. But if the charge of shot be omitted, the primer will only ignite the powder, and there will be set up sufficient pressure merely to throw the wads about half way up the barrel of the gun, when the powder will go out. Now if this same charge of powder be collected and reloaded into a new cartridge case and well confined behind wads and a charge of shot, as above explained, it will all burn, giving the same results as black powder.
Attempts have been made to use this powder in pistols and revolvers, but here it has proved a failure, as the pressure is not great enough to cause the powder to be consumed, unless it be in the form of very fine grains or dust, in which case the pressure mounts too high. However, this might be overcome to a degree by making the powder porous. The chemical conditions of the powder might be the same, but the physical conditions must be different. A powder suitable for shot guns and pistols would not be suitable for rifles.
One not familiar with the characteristics of smokeless powder would be almost certain to fail in his first attempt to fire it. Many persons have been convinced by their first experiments that this powder would not burn at all in a gun, any more than so much sand.
Smokeless powder is consumed with a rapidity which accords with the conditions of its confinement. Therefore, the bullets which have been experimented with by different governments have been the cause of much of the varying pressures attributed to the smokeless powders.
The Austrians use the Mannlicher steel jacketed bullet. The steel casing or jacket is first tinned on the inside and then the lead is cast in, thus melting the tin and adhering firmly to the jacket. This projectile sets up enormous friction in the barrel of the gun when used with smokeless powder; as the smokeless powder leaves the gun barrel perfectly clean and the two steel surfaces being in absolute contact cause tremendous friction; and as the coefficient of friction varies with every shot, the pressure in the gun constantly varies greatly.
The German silver covered bullet used by the French has the disadvantage that when firing rapidly the chamber of the barrel becomes nickel plated and great friction is caused, mounting up the pressures and causing the muzzle velocities to fall off.
The Austrians, in order to prevent their steel cased bullets from rusting and to lessen the friction in the barrel of the gun, cover them with a heavy lubricant, which gives the cartridges an unsightly appearance and causes them to gather dust and sand. The French employ a lubricant at the base of the projectile, with a small copper disk between the same and the powder.
Col. A.R. Buffington, commander of the National Armory at Springfield, Mass., has made a steel covered projectile which he prevents from rusting by blackening by a niter process. Several grooves are pressed in the base of the bullet which carry a lubricant, and when the bullet is inserted in the cartridge case the grooves are covered by it. Furthermore, these grooves prevent the lead filling from bursting through the steel casing, leaving the latter in the barrel, as often occurs with the Austrian and French projectiles when using smokeless powder.
A new projectile has lately come out, the invention of Captain Edward Palliser, of the British army. This bullet consists of a jacket made of very soft Swedish wrought iron, coated with zinc and filled with lead, the lead being pressed into this jacket. The bullet is corrugated at its base, after the manner of the one made by Colonel Buffington. This projectile has been experimented with very extensively by the British government, and at the works of the Maxim-Nordenfelt Guns and Ammunition Company, in England. The zinc coating of the bullet is too soft to stick to the barrel of the gun, and also in a measure acts as a lubricant. This projectile has given better results than any other that has been experimented with. The great velocities and the most uniform pressures by the use of smokeless powder have been attained with this Palliser bullet.