Graphite
Intermediate between soft carbon and diamond come the graphites. The name graphite is given to a variety of carbon, generally crystalline, which in an oxidising mixture of chlorate of potassium and nitric acid forms graphitic oxide. This varies in colour from green to brown or yellow, or it is almost without colour, according to the completeness of the reaction. Graphites are of varying densities, from 2·0 to 3·0, and generally of crystalline aspect. Graphite and diamond pass insensibly into one another. Hard graphite and soft diamond are near the same specific gravity. The difference appears to be one of pressure at the time of formation.
Some forms of graphite exhibit the remarkable property by which it is possible to ascertain approximately the temperature at which they were formed, or to which they have subsequently been exposed. Sprouting graphite is a form, frequently met with in nature, which on moderate heating swells up to a bulky, very light mass of amorphous carbon. Moissan has found it in blue ground from Kimberley; my own results verify his. When obtained by simple elevation of temperature in the arc or the electric furnace graphites do not sprout; but when they are formed by dissolving carbon in a metal at a high temperature and then allowing the graphite to separate out on cooling, the sprouting variety appears. The phenomenon of sprouting is easily shown. If a few grains are placed in a test-tube and heated to about 170° C., the grains increase enormously in bulk and fill the tube with a light form of amorphous carbon.
The resistance of a graphite to oxidising agents is greater the higher the temperature to which it has previously been exposed. Graphites which are easily attacked by a mixture of fuming nitric acid and potassium chlorate are rendered more resistant by strong heat in the electric furnace.
I have already signified that there are various degrees of refractoriness to chemical reagents among the different forms of graphite. Some dissolve in strong nitric acid; other forms of graphite require a mixture of highly concentrated nitric acid and potassium chlorate to attack them, and even with this intensely powerful agent some graphites resist longer than others. M. Moissan has shown that the power of resistance to nitric acid and potassium chlorate is in proportion to the temperature at which the graphite was formed, and with tolerable certainty we can estimate this temperature by the resistance of the specimen of graphite to this reagent.