1. Salt-acid Tan, or Pickle
This is one of the most extensively used methods for tanning furs, and is also very cheap and easily applied. A typical formula for this tan is the following: A solution of salt is prepared containing about 10% of common salt, sodium chloride, and to this is added 1⁄2–3⁄4 ounce of sulphuric acid for each gallon of tanning liquor. The proportions may be varied within certain limits, but the figures here given are those which have proven successful in practise. The solution should be made in a wooden or earthenware container, free from any metal, as it would be attacked by the acid. The liquor is then applied to the flesh-side of the fleshed skins by means of a brush, making sure to touch all parts of the pelt. They are then placed in a pile and allowed to remain thus until tanned, an operation which occupies a time ranging from a few hours to two or three days depending on the thickness of the skins. When the corium has lost its translucence and has become of a milky-white color throughout the entire thickness of the skin, as can be seen by viewing a cross-section, the skin may be considered tanned. In some instances, where the hair of the fur can stand immersion without injury, the skins are entered into the pickling solution and allowed to remain for 12 to 24 hours, which is generally a sufficient time to tan them in this manner.
The acid of the pickle causes the skin to swell, the salt then penetrating between the fibres of the corium, and at the same time reducing the swelling of the skin. The acid also neutralizes the alkaline products of decomposition which may form, while the salt acts as a deterrent to the progress of the putrefactive processes. When the skin is dried after tanning, and stretched and finished, a soft white leather is obtained which is permanent as long as it is kept dry. It is the salt which causes the fibres of the skin to be completely differentiated and thus prevents their adhesion.
It is interesting to note that other acids besides sulphuric can be used for the pickle, organic as well as mineral, formic acid in 1⁄4% solution being especially effective and giving excellent results, but is more expensive than the mineral acid. A method, which in principle is identical with the pickle, but carried out in an entirely different manner, is the lactic acid fermentation process, or “Schrot-beize” as it is called in German. The procedure is in general as follows: “The fleshed skins are placed on tables, flesh-side up, and covered with a layer of bruised barley grains, or a mixture of 3 parts of wheat bran and 2 parts of rye flour. Then the head, tail and legs are turned inward, and the skins rolled up in little cushions, hair-side out, and placed in a vat. When this is filled with the skins a solution of common salt is poured over them, and they are allowed to remain thus in a moderately cool place for 24 hours. After this time, the skins are carefully unrolled, so as not to remove any of the adhering solid materials, and turning the skins hair-side inward, they are laid flat together in pairs and placed in an empty vat. After another 24 hours they are again unpacked and replaced in another vat, care being taken each time to keep all the solid particles adhering to the flesh-side. This operation is continued and repeated until the skins are properly tanned, which takes from 10 to 14 days, depending on the weather and the temperature. The skins are then removed, rinsed free of the tanning substances, pressed, dried and finished.” A somewhat modified form of this process is the so-called Russian tan, which is usually done in the following manner: 5 parts of bruised barley grains are mixed with ten parts of luke-warm water in a vat, which is then covered up. A small quantity of brewers’ yeast is also added to aid in the fermentation. As soon as the mixture develops a slight heat, one part of fresh whey is added, and the fleshed skins entered into the tanning liquor in which they remain for about 12 hours. They are then tramped in the mixture so as to effect greater penetration, and left until the tanning process is complete. Whey is the milk fluid left after the casein and most of the fat have been removed from the milk by coagulation, and consists practically of a solution of all the milk-sugar or lactose, and the lactic acid of the milk, together with a small percentage of mineral salts, and a slight amount of fat. By fermentation, the milk-sugar is converted into lactic acid, which helps to effect the tan by swelling the skin.
The effectiveness of the fermentation processes depends to a considerable degree on the action of certain bacteria and yeasts. Bacteria are one-celled organisms belonging to the vegetable kingdom, and some are so small as to be scarcely visible under a microscope, while some indeed cannot be seen by any means, their existence being inferred from their effects. As they vary in size, bacteria also vary in shape, some being spherical, others in the form of long, thin rods, while still others are of a spiral shape; another common form is the dumb-bell shaped bacterium. Some types are provided with what are known as flagella, which resemble fine hairs attached to the body of the organism, and which enable it to move about actively in liquids. The food of bacteria is always in liquid form, as only in this condition can it be absorbed. However, some kinds of bacteria attack solid substances from which they obtain their nourishment, but this is done in an indirect way, by secreting certain fluids known as enzymes, which dissolve or digest the material and convert it into a form that can easily be absorbed by the bacteria. The enzymes are non-living chemical substances, which possess the peculiar property of bringing about the chemical change of an almost indefinite amount of material upon which they act, without themselves being in any way changed. Yeasts also act in a manner similar to the bacteria in causing various chemical changes, particularly inducing fementations. In the simple “Schrot-beize,” the starch contained in the bran or barley grains is first converted to a soluble sugar by means of enzymes secreted by the bacteria which are always present. This sugar then undergoes an acid fermentation, with the formation of lactic and acetic acids, due in this case to organisms known as the bacterium furfuris A and B. The action of the Russian tan is similar, but quicker. In this case, the sugar is already present in soluble form, and the yeast cells cause its fermentation with the production of lactic acid. In both cases, the acids as they form swell and loosen up the skin fibres slowly, the salt penetrating between them, and keeping them separated on drying. Both methods give results which are equally good, but by the Russian tan the skins acquire a disagreeable odor, which makes this method of dressing objectionable.
The lactic acid fermentation processes have an advantage over the pickle, in that the slow formation of weak organic acids with their gradual action produce a softer leather, with a gentler ‘feel,’ the presence of the flour and the grains of the tan, aside from their tanning action, contributing to the fullness and softness of the leather. There is also less likelihood of the leather being subsequently affected by the presence of the acid in it, as lactic and acetic acids are much less injurious than sulphuric acid to leather. These disadvantages of the pickle can to a large degree, be overcome without any great difficulty. On the other hand, the matter of the length of time of the tanning process, shows the acid pickle at a great advantage, and so, especially for furs other than those obtained from sheep and goats, the pickle is in most cases used as the principle method of tanning. In Austria, Russia, and to a certain extent in Germany also, the “Schrot-beize” is still considerably employed, chiefly for dressing sheep and lamb skins. The dressing of the various kinds of Persian lambs, caraculs, astrachans, etc., in the native center of the industry in Buchara and surrounding districts, is also a “Schrot-beize,” barley, rice flour or rye flour, and salt water being used to prepare the skins, the manipulations being essentially the same as those described above, although carried out in cruder and more primitive fashion.