We now know that the decomposable inactive variety, racemic acid, may be readily obtained by· dissolving equal weights of the ordinary dextro and lævo varieties in water and crystallising the solution by slow evaporation at the ordinary temperature. For further investigation has fully borne out the conclusion of Pasteur, that racemic acid simply consists of a molecular compound of the two active varieties. It is thus itself inactive because it is externally compensated, the two kinds of enantiomorphous molecules being alternately regularly distributed throughout the whole crystal structure, the very case which von Fedorow, Schönflies, and Barlow assumed to be possible, and which Sohncke only tardily admitted. The crystalline form of racemic acid is, as was to be expected, quite different from the monoclinic form of the active tartaric acids, being triclinic; and indeed it is not crystallographically comparable with the active form, inasmuch as the crystals of racemic acid contain a molecule of water of crystallisation, whereas the active varieties crystallise anhydrous.
Ordinary dextro and lævo tartaric acids crystallise in identical forms of the sphenoidal or monoclinic-hemimorphic class of the monoclinic system, the class which is only symmetrical about a digonal axis, the unique symmetry plane of the monoclinic system, which also operates when full monoclinic symmetry is developed, being absent in this class. Hence the interfacial crystal angles, the monoclinic axial angle, and the axial ratios are identical for the two varieties. But the crystals are hemimorphic, owing to the absence of the symmetry plane, and complementarily so, the dextro variety being distinguished by the presence of only the right clino-prism {011}, while the lævo variety is characterised by the presence only of the left-clino-prism {0̄11}, these two complementary forms, each composed of only two faces and which on a holohedral crystal exhibiting the full symmetry of the monoclinic system would both be present as a single form of four faces, being never both developed on the same optically active crystal.
This hemimorphism of the two kinds of crystals will be rendered clear by Figs. 63 and 64, representing typical crystals of dextro and lævo tartaric acids which are obviously the mirror images of each other.
Fig. 63.
Fig. 64.
Crystals of Dextro and Lævo Tartaric Acids.
A remarkable discovery was made by Pasteur in connection with one of the salts of racemic acid, sodium ammonium racemate, Na(NH4)C4H4O6, or
COONH4
|