Thus stray hues from other parts of the spectrum tend to neutralize the yellow sensation, which would be strong if each of the pigments were pure in the spectral sense. Pigment absorption affects all palette mixtures, and, failing to obtain a satisfactory yellow by mixture of red and green, painters use original yellow pigments,—such as aureolin, cadmium, and lead chromate,—each of them also impure but giving a dominant sensation of yellow. Did the eye discriminate, as does the ear when it analyzes the separate tones of a chord, then we should recognize that yellow pigments emit both red and green rays.
White light dispersed into a colored band by one prism, may have the process reversed by a second prism, so that the eye sees again only white light. But this would not be so, did not the balance of red, green, and violet-blue sensations remain undisturbed. All our ideas of color harmony are based upon this fundamental relation, and, if pigments are to render harmonious effects, we must learn to control their impurities so as to preserve a balance of red, green, and violet-blue.
Otherwise, the excessive chroma and value of red and yellow pigments so overwhelm the lesser degrees of green and blue pigments that no balance is possible, and the colorist of fine perception must reject not alone the theoretical, but also the practical outcome of a “red-yellow-blue” theory.
Some of the points raised in this discussion are rather subtle for students, and may well be left until they arise in a study of optics, but the teacher should grasp them clearly, so as not to be led into false statements about primary and complementary hues.
[ Chapter IV.]
PRISMATIC COLOR.
Pure color is seen in the spectrum of sunlight.
[(87)] The strongest sensation of color is gained in a darkened room, with a prism used to split a beam of sunlight into its various wave lengths. Through a narrow slit there enters a straight pencil of light which we are accustomed to think of as white, although it is a bundle of variously colored rays (or waves of ether) whose union and balance is so perfect that no single ray predominates.