Before proceeding to the general description of the atmospheric machine (§ [10]), it is desirable to consider one or two features of gaseous reaction which have a somewhat important bearing on its working. Let it be assumed that a mass of gaseous material is confined within the lower portion of a narrow tube ABCD ([Fig. 8]) assumed to be thermally non-conducting; the upper portion of the tube is in free communication with the atmosphere. The gas within the tube is assumed to be isolated from the atmosphere by a movable piston EF, free to move vertically in the tube, and for the purpose of illustration, assumed also frictionless and weightless. With these assumptions, the pressure on the confined gas will simply be that due to the atmosphere. If heat energy be now applied to the gas, its temperature will rise and expansion will ensue. This expansion will be carried out at constant atmospheric pressure; the gaseous material, as it expands, must lift with it the whole of the superimposed atmospheric column against the downward attractive force of the earth's gravitation on that column. Work is thus done by the expanding gas, and in consequence of this work done, a definite quantity of atmospheric material gains energy of position or potential energy relative to the earth's surface. At the same time, the rise of temperature of the gas will indicate an accession of heat energy to its mass. These familiar phenomena of expansion under constant pressure serve to illustrate the important fact that, when heat energy is applied to a gaseous mass, it really manifests itself therein in two aspects, namely, heat energy and work energy. The increment of heat energy is indicated by the increase in temperature, the increment of work energy by the increase in pressure. In the example just quoted, however, there is no increase in pressure, because the work energy, as rapidly as it is applied to the gas, is transformed or worked down in displacing the atmospheric column resting on the upper side of the moving piston. The energy applied, in the form of heat from the outside source, has in reality been introduced into a definite energy machine, a machine in this case adapted for the complete transformation of work energy into energy of position. As already indicated, when the expansive movement is completed, the volume and temperature of the gaseous mass are both increased but the pressure remains unaltered. While the increase in temperature is the measure and index of a definite increase in the heat energy of the gas, it is important to note that, so far as its work energy is concerned, the gas is finally in precisely the same condition as at the commencement of the operation. Work energy has been, by the working of this energy machine, as it were passed through the gaseous mass into the surrounding atmosphere. The pressure of the gas is the true index of its work energy properties. So long as the pressure remains unaltered, the inherent work energy of the material remains absolutely unaffected. A brief consideration of the nature of work energy as already portrayed (§ [31]) will make this clear. Work energy has been defined as "that form of energy transmitted by matter in motion," and it is clear that pressure is the essential factor in any transmission of this nature. Temperature has no direct bearing on it whatever. It is common knowledge, however, that in the application of heat energy to a gaseous substance, the two aspects of pressure and temperature cannot be really dissociated. They are mutually dependent. Any increment of heat energy to the gas is accompanied by an increment of work energy, and vice versa. The precise mode of action of the work energy will, of course, depend on the general circumstances of the energy machine in which it operates. In the case just considered the work energy does not finally reside in the gaseous mass itself, but, by the working of the machine, is communicated to the atmosphere. If, on the other hand, heat energy were applied in the same fashion to a mass of gas in a completely enclosed vessel, that is to say at constant volume instead of at constant pressure, the general phenomena are merely altered in degree according to the change in the precise nature of the energy machine. In the former case, the nature of the energy machine was such that the work energy communicated was expended in its entirety against gravitation. Under what is usually termed constant volume conditions, only a portion of the total work energy communicated is transformed, and the transformation of this portion is carried out, not against gravitation, but against the cohesive forces of the material of the enclosing vessel which restrains the expansion. No matter how great may be the elastic properties of this material, it will be distorted, more or less, by the application of work energy. This distortional movement is the external evidence of the energy process of transformation. Energy is stored in the material against the forces of cohesion (§ [15]). But the energy thus stored is only a small proportion of the total work energy which accrues to the gas in the heating process. The remainder is stored in the gas itself, and the evidence of such storage is found simply in the increase of pressure. Different energy machines thus offer different facilities for the transformation or the storage of the applied energy. In every case where the work energy applied has no opportunity of expending itself, its presence will be indicated by an increase in the pressure or work function of the gas.
Fig. 8
The principles which underlie the above phenomena can readily be applied to other cases of gaseous expansion. It is a matter of common experience that if a given mass of gaseous material be introduced into a vessel which has been exhausted by an air-pump or other device for the production of a vacuum, the whole space within the vessel is instantly permeated by the gas, which will expand until its volume is precisely that of the containing vessel. Further phenomena of the operation are that the expanding gas suffers a decrease in temperature and pressure corresponding to the degree or ratio of the expansion. Before the expansive process took place the gaseous mass, as indicated by its initial temperature and pressure, is endowed with a definite quantity of energy in the form of heat and work energy. After expansion, these quantities are diminished, as indicated by its final and lower temperature and pressure. The operation of expansion has thus involved an expenditure of energy. This expenditure takes place in virtue of the movement of the gaseous material (§ [4]). It is obvious that if the volume of the whole is to be increased, each portion of the expanding gas requires to move relatively to the remainder. This movement is carried out in the lines of the earth's gravitative attraction, and to a certain extent over the surface of the containing vessel. In some respects, it thus corresponds simply to the movement of a body over the earth's surface (§ [16]). It is also carried out against the viscous or frictional forces existing throughout the gaseous material itself (§ [29]). Assuming no influx of energy from without, the energy expended in the movement of the gaseous material must be obtained at the expense of the inherent heat and work energy of the gas, and these two functions will decrease simultaneously. The heat and work energy of the gas or its inherent energy is thus taken to provide the energy necessary for the expansive movement. This energy, however, does not leave the gas, but still resides therein in a form akin to that of energy of position or separation. It will be clear also, that the reverse operation cannot, in this case, be carried out; the gas cannot move back to its original volume in the same fashion as it expanded into the vacuum, so that the energy utilised in this way for separation cannot be directly returned.
The expansion of the gas has been assumed above to take place into a vacuous space, but a little consideration will show that this condition cannot be properly or even approximately fulfilled under ordinary experimental conditions. The smallest quantity of gas introduced into the exhausted vessel will at once completely fill the vacuous space, and, on this account, the whole expansion of the gas does not in reality take place in vacuo at all. To study the action of the gas under the latter conditions, it is necessary to look on the operation of expansion in a more general way, which might be presented as follows.
34. Gravitational Equilibrium of Gases
Consider a planetary body, in general nature similar to the earth, but, unlike the earth, possessing no atmosphere whatever. The space surrounding such a celestial mass may then be considered as a perfect vacuum. Now let it be further assumed that in virtue of some change in the conditions, a portion of the material of the planetary mass is volatilised and a mass of gas thereby liberated over its surface. The gas is assumed to correspond in temperature to that portion of the planet's surface with which it is in contact. It is clear that, in the circumstances, the gas, in virtue of its elastic and energetic properties, will expand in all directions. It will completely envelop the planet, and it will also move radially outwards into space. In these respects, its expansion will correspond to that of a gas introduced into a vacuous space of unlimited extent.
The question now arises as to the nature of the action of the gaseous substance in these circumstances. It is clear that the radial or outward movement of the gas from the planetary surface is made directly against the gravitative attraction of the planet on the gaseous mass. In other words, matter or material is being moved in the lines or field of this gravitative force. This movement, accordingly, will be productive of an energy transformation (§ [4]). In its initial or surface condition each portion of the gaseous mass is possessed of a perfectly definite amount of energy indicated by and dependent on that condition. As it moves upwards from the surface, it does work against gravity in the raising of its own mass. But as the mass is thus raised, it is gaining energy of position (§ [20]), and as it has absolutely no communication with any external source of energy in its ascent, the energy of position thus gained can only be obtained at the expense of its initial inherent heat and work energy. The operation is, in fact, a simple transformation of this inherent energy into energy of position, a transformation in which gravity is the incepting agency. The external evidence of transformation will be a fall in temperature of the material. Since the action is exactly similar for all ascending particles, it is evident that as the altitude of the gaseous mass increases the temperature will correspondingly diminish. This diminution will proceed so long as the gaseous particles continue to ascend, and until an elevation is finally attained at which their inherent energy is entirely converted into energy of position. The expansion of the gas, and the associated transformation of energy, thus leads to the erection of a gaseous column in space, the temperature of which steadily diminishes from the base to the summit. At the latter elevation, the inherent energy of the gaseous particles which attain to it is completely transformed or worked out against gravity in the ascent; the energy possessed by the gas at this elevation is, therefore, entirely energy of position; the energy properties of heat and work have entirely vanished, and the temperature will, therefore, at this elevation, be absolute zero. It is important to note also that in the building of such a column or gaseous spherical envelope round the planet, the total energy of any gaseous particle of that column will remain unchanged throughout the process. No matter where the particle may be situated in the column, its total energy must always be expressed by its heat and work energy properties together with its energy of position. This sum is always a constant quantity. For if the particle descends from a higher to a lower altitude, its total energy is still unchanged, because a definite transformation of its energy of position takes place corresponding to its fall, and this transformed energy duly appears in its original form of heat and work energy in accordance with the decreased altitude of the particle. Since the temperature of the column remains unchanged at the base surface and only decreases in the ascent, it is clear that the entire heat and work energy of the originally liberated gaseous mass is not expended in the movement against gravity. Every gaseous particle—excepting those on the absolute outer surface of the gaseous envelope—has still the property of temperature. It is evident, therefore, that in the constitution of the column, only a portion of the total original heat and work energy of the gaseous substance is transformed into energy of position.
The space into which the gas expands has been referred to as unlimited in extent. But although in one sense it may be correctly described thus, yet in another, and perhaps in a truer sense, the space is very strictly limited. It is true there is no enclosing vessel or bounding surface, but nevertheless the expansion of the gas is restrained in two ways or limited by two factors. The position of the bounding surface of the spherical gaseous envelope depends, in the first place, on the original energy of the gas as deduced from its initial temperature and its other physical properties, and secondly on the value of the gravitative attraction exerted on the gas by the planetary body. Looking at the first factor, it is obvious that since the gaseous mass initially possesses only a limited amount of energy, and since only a certain portion of this energy is really available for the transformation, the whole process is thereby limited in extent. The complete transformation and disappearance of that available portion of the gaseous energy in the process of erection of the atmospheric column will correspond to a definite and limited increase of energy of position of gaseous material. Since the energy of position is thus restricted in its totality, and the mass of material for elevation is constant, the height of the column or the boundary of expansion of the gas is likewise rigidly defined. In this fashion, the energy properties of the gaseous material limit the expansive process.