It is rather difficult to give a detailed, and consistent chronological account of his scientific activities,—they are so variegated, and cover such a wide field. The first work which gained him distinction was an investigation on Brownian Movement. An admirable account will be found in Perrin’s book ‘The Atoms.’ Starting from Boltzmann’s theorem connecting the entropy, and the probability of a state, he deduced a formula on the mean displacement of small particles (colloidal) suspended in a liquid. This formula gives us one of the best methods for finding out a very fundamental number in physics—namely—the number of molecules in one gm. molecule of gas (Avogadro’s number). The formula was shortly afterwards verified by Perrin, Prof. of Chemical Physics in the Sorbonne, Paris.
To Einstein is also due the resuscitation of Planck’s quantum theory of energy-emission. This theory has not yet caught the popular imagination to the same extent as the new theory of Time, and Space, but it is none the less iconoclastic in its scope as far as classical concepts are concerned. It was known for a long time that the observed emission of light from a heated black body did not correspond to the formula which could be deduced from the older classical theories of continuous emission and propagation. In the year 1900, Prof. Planck of the Berlin University worked out a formula which was based on the bold assumption that energy was emitted and absorbed by the molecules in multiples of the quantity hν, where h is a constant (which is universal like the constant of gravitation), and ν is the frequency of the light.
The conception was so radically different from all accepted theories that in spite of the great success of Planck’s radiation formula in explaining the observed facts of black-body radiation, it did not meet with much favour from the physicists. In fact, some one remarked jocularly that according to Planck, energy flies out of a radiator like a swarm of gnats.
But Einstein found a support for the new-born concept in another direction. It was known that if green or ultraviolet light was allowed to fall on a plate of some alkali metal, the plate lost electrons. The electrons were emitted with all velocities, but there is generally a maximum limit. From the investigations of Lenard and Ladenburg, the curious discovery was made that this maximum velocity of emission did not at all depend upon the intensity of light, but upon its wavelength. The more violet was the light, the greater was the velocity of emission.
To account for this fact, Einstein made the bold assumption that the light is propagated in space as a unit pulse (he calls it a Light-cell), and falling upon an individual atom, liberates electrons according to the energy equation
1
hν = --- mv² + A,
2
where (m, v) are the mass and velocity of the electron. A is a constant characteristic of the metal plate.
There was little material for the confirmation of this law when it was first proposed (1905), and eleven years elapsed before Prof. Millikan established, by a set of experiments scarcely rivalled for the ingenuity, skill, and care displayed, the absolute truth of the law. As results of this confirmation, and other brilliant triumphs, the quantum law is now regarded as a fundamental law of Energetics. In recent years, X-rays have been added to the domain of light, and in this direction also, Einstein’s photo-electric formula has proved to be one of the most fruitful conceptions in Physics.