Agriculturally, the most important of the Tertiary formations is the Eocene, particularly near London, though it is much covered by sand or gravel. The London clay, which produces a heavy brown soil, is of slight value, though when properly drained it produces good crops of wheat, beans, and cabbages and other market-garden produce. For this purpose it is greatly improved by the addition of lime and of town manure. The South Hampshire Eocene beds of clay are cold, wet and of small agricultural value.
The Eocene clays are composed of a variety of clays, many of which are only distinguishable by the different fossils they contain. The most important are the Reading clays, the London clay and the Bagshot clays.
The Reading clays extend over a considerable area in the South of England and are most valuable near the town from which they derive their name. The best qualities are mottled in a characteristic manner and are particularly suitable for the manufacture of roofing tiles and small terra-cotta—an industry for which Reading is famous.
The London clay is always a treacherous material and is best avoided in the manufacture of bricks and other articles except under highly skilled technical advice.
The Bagshot clays in Dorsetshire are famous for the ball and pipe clays shipped from Poole, whilst at Bovey Tracey and in several parts of Devonshire equally valuable ball clays are found and are shipped from Teignmouth.
These ball clays are of variable composition and colour and require careful selection and testing. They are closely associated with sands, but the lower beds of clay are remarkably stiff, plastic and white-burning. The colour of the raw clay varies from a pale yellow to a dark brown or even to black, but this is little or no criterion of the colour of goods made therefrom, as the colour is due to carbonaceous matters, 4 per cent. or more carbon being usually present.
The 'blue' and 'black' ball clays are the most valued by potters, but the quality is usually ascertained by a burning test.
The value of these ball clays both in Devonshire and Dorset is due to their comparative freedom from iron and alkalies and to their remarkable unctuousness and plasticity. They are, therefore, largely used in the manufacture of all kinds of earthenware of which they form the foundation material.
In composition, ball clays appear to consist chiefly of a hydro-alumino-silicate corresponding to the formula H4Al2Si2O9, and in this they very closely resemble the china clays (kaolins). The latter are, however, but slightly plastic whilst the ball clays are amongst the most plastic clays known. The china clays are also much more refractory than the ball clays owing to the somewhat larger proportion of alkalies in the latter.