(b) Other substances—possibly of an organic nature and derived from the soil—may have played an important part.
(c) Wet steam and hot solutions of fluorine, boron or sulphur compounds may have effected the decomposition.
The recent progress made in the application of the laws of physical chemistry to geological problems is continually throwing fresh light on this interesting subject. Thus, studies of the dissociation pressures and transition points between the anhydrous and the hydrous states of various substances and the effect of water as a powerful agent of decomposition (hydrolysis) have shown that hydration is a characteristic result of decompositions occurring in the upper portions of the earth's crust and not in the lower ones, and that it is usually checked, or even reversed, when the substance is under great pressure. At great depths kaolins and other complex hydrous silicates give place to anhydrous ones such as muscovite, andalusite and staurolite. There is, therefore, good reason to believe that the kaolinization of Cornish felspar has occurred at only moderate depths from the surface and that it has been chiefly produced by the action of water containing acid gases in solution. The acid in the water may have been absorbed from the atmosphere, or it may be due to vapours rising from below through the felspathic material.
In Great Britain, china clay occurs in the form of powdery particles apparently amorphous, but containing some crystals, scattered through a mass of harder rock, the whole being known as china clay rock or 'carclazite.' The softer portions of this china clay rock are known as 'growan' and the china clay in it represents only a small proportion of the whole material.
The finer particles of clay and other materials are removed by treatment with water, whereby one-third to one-eighth of the material is separated. This small proportion is then subjected to further washing and sedimentation in order to obtain the china clay in a state of commercial purity. It will thus be understood that the Cornish china clays are not 'deposits' in the usual acceptation of that term, the soft growan from which they are obtained being almost invariably the result of decomposition in situ of some species of felspar in disintegrated granite.
The commercial kaolins of France, Germany, America and China very closely resemble the Cornish china clays in composition, but when used in the manufacture of porcelain they create differences in the finished material which are clearly noticeable, though microscopical examination and chemical analysis, at present, fail to distinguish between them in the raw state on account of their great resistance to ordinary chemical and physical forces.
In addition to the breaking up of felspathic rocks with the formation of china clay or kaolin (kaolinization), other decompositions which occur may result in the formation of clays, and an examination of a considerable number of clays by J. M. van Bemmelen ([26]) has led him to suppose that several different clay-forming forces have been at work in the production of clays. He classifies these under four heads:
(1) Kaolinization, or the decomposition of felspathic and similar rocks by the action of telluric water containing active gases in solution.
(2) Ordinary weathering in which the action is largely mechanical, but is accompanied by some hydrolysis owing to the impurities contained in the water which is an essential factor.
(3) Lateritic action—or simple decomposition by heat—which occurs chiefly under tropical conditions, but may also occur in temperate climates, and has for its main product a mixture of free silica and alumina, the latter being in the form of (amorphous) 'laterite.' It may not improbably be a result of the decomposition of the clay molecule similar to that which occurs when china clay is heated, as there is no temperature below which it can be said that china clay does not decompose into free silica and alumina ([29]).