In spite of their great purity, commercial china clays and kaolins are almost devoid of plasticity, nor can this property be greatly increased by any artificial treatment. This has led to the conclusion that plasticity is not an essential characteristic of the clayite or kaolinite molecules, but is due to physical causes not shown by any investigation of the chemical composition of the material.
In addition to the specially purified kaolins just described, alkaline kaolins, siliceous kaolins and ferruginous kaolins are obtained from less pure rocks and do not undergo so thorough a treatment with water. Some of these varieties are not improbably derived from transported kaolins, as they occur in Tertiary strata, and so bear some resemblance to the white fireclays on the Carboniferous limestone of Staffordshire, Derbyshire and North Wales, though the latter are far more plastic.
To be of value, a china clay or kaolin must be as white as possible and must be free from more than an insignificant percentage of metallic oxides which will produce a colour when the clay is heated to bright redness. If the material is to be used in the manufacture of paper, paint or ultra-marine, these colour-producing oxides are of less importance providing that the clay is sufficiently white in its commercial state.
The manufacturer of china-ware and porcelain requires china clay or kaolin which, in addition to the foregoing characteristics, shall be highly refractory. It must, therefore, be free from more than about 2 per cent. of lime, magnesia, soda, potash, titanic acid and other fluxes.
It is a mistake to suppose that all white clays of slight plasticity are china clays or kaolins. Some pipe clays have these characteristics, but they contain so large a proportion of impurities as to be useless for the purposes for which china clay is employed and are consequently of small value.
Users of china clays and kaolins generally find it necessary to carry out a lengthy series of tests before accepting material from a new source, as such a material may possess characteristics not readily shown by ordinary methods of analysis, but which are sufficiently active to make it useless for certain purposes (see [p. 143]).
Pottery clays are, as their name implies, those used in the manufacture of pottery, and comprise the china clays already mentioned ([p. 104]), the ball clays and the less pure clays used in the manufacture of coarse red ware, flower pots, etc.
The china clays ([p. 104]) are not used alone in pottery manufacture as they lack plasticity and cohesion. In the production of china-ware or porcelain they are mixed with a fluxing material such as Cornish stone, pegmatite, or felspar, together with quartz or bone ash. Thus, English china ware is produced from a mixture of approximately equal parts of bone ash, china clay and Cornish stone, whilst felspathic or hard porcelain is made from a mixture of kaolin, felspar and quartz, a little chalk being sometimes added.