The electrolyte for this cell is made as follows:
Sodium bichromate 6 oz.
Sulphuric acid 17 oz.
Soft water 56 oz.
This solution is mixed by dissolving the bichromate of sodium in the water and then adding slowly the sulphuric acid. Potassium bichromate may be substituted for the sodium bichromate.
In setting up this cell, the amalgamated zinc is placed within the porous cup, in the bottom of which are about two teaspoonfuls of mercury, the latter serving to keep the zinc well amalgamated. The porous cup is then placed in the glass jar and a sufficient quantity of the electrolyte is placed in the outer jar to come within about one and one-half inches of the top of the porous cup. About two teaspoonfuls of salt are then placed in the porous cup and sufficient soft water added to bring the level of the liquid within the porous cup even with the level of the electrolyte in the jar surrounding the cup. The carbon is then placed through the slot in the cover, and the wire from the zinc is passed through the hole in the cover provided for it, and the cover is allowed to fall in place. The cell is now ready for immediate use.
The action of this cell is as follows: The sulphuric acid attacks the zinc and forms zinc sulphate, liberating hydrogen. The hydrogen attempts to pass to the carbon plate as usual, but in so doing it meets with the oxygen of the chromic acid and forms water therewith. The remainder of the chromic acid combines with the sulphuric acid to form chromium sulphate.
Fig. 65. Fuller Cell
[View full size illustration.]
The mercury placed in the bottom of the porous cup with the zinc keeps the zinc in a state of perpetual amalgamation. This it does by capillary action, as the mercury spreads over the entire surface of the zinc. The initial amalgamation, while not absolutely essential, helps in a measure this capillary action.
In another well-known type of the Fuller battery the carbon is a hollow cylinder, surrounding the porous cup. In this type the zinc usually took the form of a long bar having a cross-shaped section, the length of this bar being sufficient to extend the entire depth of the porous cup. This type of cell has the advantage of a somewhat lower internal resistance than the standard form just described.