1. Under the ordinary pressure of the atmosphere; and that either,
A, by external application of heat to boilers, with a, an open fire; b, steam; c, hot liquid media.
B, by evaporation with air; a, at the ordinary temperature of the atmosphere; b, by currents of warm air.
2. Under progressively lower degrees of pressure than the atmospheric, down to evaporation in as perfect a vacuum as can be made.
It is generally affirmed, that a thick metallic boiler obstructs the passage of the heat through it so much more than a thin one, as to make a considerable difference in their relative powers of evaporating liquids. Many years ago, I made a series of experiments upon this subject. Two cylindrical copper pans, of equal dimensions, were provided; but the metal of the one was twelve times thicker than that of the other. Each being charged with an equal volume of water, and placed either upon the same hot plate of iron, or immersed, to a certain depth, in a hot solution of muriate of lime, I found that the ebullition was greatly more vigorous in the thick than in the thin vessel, which I ascribed to the conducting substance up the sides, above the contact of the source of heat, being 12 times greater in the former case than in the latter.
If the bottom of a pan, and the portions of the sides, immersed in a hot fluid medium, solution of caustic potash or muriate of lime, for example, be corrugated, so as to contain a double expanse of metallic surface, that pan will evaporate exactly double the quantity of water, in a given time, which a like pan, with smooth bottom and sides, will do immersed equally deep in the same bath. If the corrugations contain three times the quantity of metallic surface, the evaporation will be threefold in the above circumstances. But if the pan, with the same corrugated bottom and sides, be set over a fire, or in an oblong flue, so that the current of flame may sweep along the corrugations, it will evaporate no more water from its interior than a smooth pan of like shape and dimensions placed alongside in the same flue, or over the same fire. This curious fact I have verified upon models constructed with many modifications. Among others, I caused a cylindrical pan, 10 inches diameter, and 6 inches deep, to be made of tin-plate, with a vertical plate soldered across its diameter; dividing it into two equal semi-cylindrical compartments. One of these was smooth at the bottom, the other corrugated; the former afforded as rapid an evaporation over the naked fire as the latter, but it was far outstripped by its neighbour when plunged into the heated liquid medium.
If a shallow pan of extensive surface be heated by a subjacent fire, by a liquid medium, or a series of steam pipes upon its bottom; it will give off less vapour in the same time when it is left open, than when partially covered. In the former case, the cool incumbent air precipitates by condensation a portion of the steam, and also opposes considerable mechanical resistance to the diffusion of the vaporous particles. In the latter case, as the steam issues with concentrated force and velocity from the contracted orifice, the air must offer less proportional resistance, upon the known hydrostatic principle of the pressure being as the areas of the respective bases, in communicating vessels.
In evaporating by surfaces heated with ordinary steam, it must be borne in mind that a surface of 10 square feet will evaporate fully one pound of water per minute, or 725 × 10 = 7250 gr., the same as over a naked fire; consequently the condensing surface must be equally extensive. Suppose that the vessel is to receive of water 2500 libs, which corresponds to a boiler 5 feet long, 4 broad, and 2 deep, being 40 cubic feet by measure, and let there be laid over the bottom of this vessel 8 connected tubes, each 5 inches in diameter and 5 feet long, possessing therefore a surface of 5 feet square. If charged with steam, they will cause the evaporation of half a pound of water per minute. The boiler to supply the steam for this purpose must expose a surface of 5 square feet to the fire. It has been proved experimentally that 10 square feet surface of thin copper can condense 3 libs of steam per minute, with a difference of temperature of 90 degrees Fahr. In the above example, 10 square feet evaporate 1 lib. of water per minute; the temperature of the evaporating fluid being 212° F., consequently 3 : 1 ∷ 90 : 903. During this evaporation the difference of the temperature is therefore = 30°. Consequently the heat of the steam placed in connection with the interior of the boiler, to produce the calculated evaporation should be, 212 + 30 = 242°, corresponding to an elastic force of 53·6 inches of mercury. Were the temperature of the steam only 224, the same boiler in the same time would produce a diminished quantity of steam, in the proportion of 12 to 30; or to produce the same quantity the boiler or tubular surface should be enlarged in the proportion of 30 to 12. In general, however, steam boilers employed for this mode of evaporation are of such capacity as to give an unfailing supply of steam.
