During this steep, some carbonic acid is evolved from the grains, and combines with the water, which, at the same time, acquires a yellowish tinge, and a strawy smell, from dissolving some of the extractive matter of the barley husks. The grain imbibes about one half its weight of water, and increases in size by about one-fifth. By losing this extract, the husk becomes about one seventieth lighter in weight, and paler in colour.
The duration of the steep depends, in some measure, upon the temperature of the air, and is shorter in summer than in winter. In general from 40 to 48 hours will be found sufficient for sound dry grain. Steeping has for its object to expand the farina of the barley with humidity, and thus prepare the seed for germination, in the same way as the moisture of the earth prepares for the growth of the radicle and plumula in seed sown in it. Too long continuance in the steep is injurious; because it prevents the germination at the proper time, and thereby exhausts a portion of the vegetative power: it causes also an abstraction of saccharine matter by the water. The maceration is known to be complete when the grain may be easily transfixed with a needle, and is swollen to its full size. The following is reckoned a good test:—If a barley-corn, when pressed between the thumb and fingers, continues entire in its husk, it is not sufficiently steeped; but if it sheds its flour upon the fingers, it is ready. When the substance exudes in the form of a milky juice, the steep has been too long continued, and the barley is spoiled for germination.
In warm weather it sometimes happens that the water becomes acescent before the grain is thoroughly swelled. This accident, which is manifest to the taste and smell, must be immediately obviated by drawing off the foul water through the tap at the bottom of the cistern, and replacing it with fresh cold water. It does no harm to renew it two or three times at one steep.
The couch.—The water being drawn off, and occasionally a fresh quantity passed through, to wash away any slimy matter which may have been generated in warm weather, the barley is now laid upon the couch floor of stone flags, in square heaps from 12 to 16 inches high, and left in that position for 24 hours. At this period, the bulk of the grain being the greatest, it may be gauged by the revenue officers if they think fit. The moisture now leaves the surface of the barley so completely, that it imparts no dampness to the hand. By degrees, however, it becomes warm; the temperature rising 10° above the atmosphere, while an agreeable fruity smell is evolved. At this time, if the hand be thrust into the heap, it not only feels warm, but it gets bedewed with moisture. At this sweating stage, the germination begins; the fibrils of the radicle first sprout forth from the tip of every grain, and a white elevation appears, that soon separates into three or more radicles, which grow rapidly larger. About a day after this appearance, the plumula peeps forth at the same point, proceeding thence beneath the husk to the other end of the seed, in the form of a green leaflet.
The greatest heat of the couch is usually about 96 hours after the barley has been taken out of the steep. In consequence, the radicles tend to increase in length with very great rapidity, and must be checked by artificial means, which constitute the chief art of the maltster. He now begins to spread the barley thinner on the floor, and turns it over several times in the course of a day, bringing the portions of the interior into the exterior surface. The depth, which was originally 15 or 16 inches, is lowered a little at every turning over, till it be brought eventually down to three or four inches. Two turnings a day are generally required. At this period of spreading or flooring, the temperature in England is about 62°, and in Scotland 5 or 6 degrees lower.
About a day after the radicles appear, the rudiments of the stem, or of the plumula, sprout forth, called by the English maltsters the acrospire. It issues from the same end of the seed as the radicle, but turns round, and proceeds within the husk towards the other end, and would there come forth as a green leaf, were its progress not arrested. The malting, however, is complete before the acrospire becomes a leaf.
The barley couch absorbs oxygen and emits carbonic acid, just as animals do in breathing, but to a very limited extent; for the grain loses only three per cent. of its weight upon the malt floor, and a part of this loss is due to waste particles. As the acrospire creeps along the surface of the seed, the farina within undergoes a remarkable alteration. The gluten and mucilage disappear, in a great measure, the colour becomes whiter, and the substance becomes so friable that it crumbles into meal between the fingers. This is the great purpose of malting, and it is known to be accomplished when the plumula or acrospire has approached the end of the seed. Now the further growth must be completely stopped. Fourteen days may be reckoned the usual duration of the germinating stage of the malting operations in England; but in Scotland, where the temperature of the couch is lower, eighteen days or even twenty-one, are sometimes required. The shorter the period within the above limits, the more advantageous is the process to the maltster, as he can turn over his capital the sooner, and his malt is also somewhat the better. Bigg is more rapid in its germination than barley, and requires to be still more carefully watched. In dry weather it is sometimes necessary to water the barley upon the couch.
Occasionally the odour disengaged from the couch is offensive, resembling that of rotten apples. This is a bad prognostic, indicating either that the barley was of bad quality, or that the workmen, through careless shovelling, have crushed a number of the grains in turning them over. Hence when the weather causes too quick germination, it is better to check it by spreading the heap out thinner than by turning it too frequently over. On comparing different samples of barley, we shall find that the best develope the germ or acrospire quicker than the radicles, and thus occasion a greater production of the saccharine principle; this conversion advances along with the acrospire, and keeps pace with it, so that the portion of the seed to which it has not reached, is still in its unaltered starchy state. It is never complete for any single barleycorn till the acrospire has come to the end opposite to that from which it sprung; hence one part of the corn may be sugary, while the other is still insipid. If the grain were allowed to vegetate beyond this term, the radicles being fully one third of an inch long, the future stem would become visibly green in the exterior; it would shoot forth rapidly, the interior of the grain would become milky, with a complete exhaustion of all its useful constituents, and nothing but the husk would remain.
In France, the brewers, who generally malt their barley themselves, seldom leave it on the couch more than 8 or 10 days, which, even taking into account the warmer climate of their country, is certainly too short a period, and hence they make inferior wort to the English brewer, from the same quantity of malt.
At the end of the germination, the radicles have become 11⁄2 longer than the barley, and are contorted so that the corns hook into one another, but the acrospire is just beginning to push through. A moderate temperature of the air is best adapted to malting; therefore it cannot be carried on well during the heat of summer or the colds of winter. Malt-floors should be placed in substantial thick-walled buildings, without access of the sun, so that a uniform temperature of 59° or 60° may prevail inside. Some recommend them to be sunk a little under the surface of the ground, if the situation be dry.