PEARLS (Perles, Fr.; Perlen, Germ.); are the productions of certain shell-fish. These molluscæ are subject to a kind of disease caused by the introduction of foreign bodies within their shells. In this case, their pearly secretion, instead of being spread in layers upon the inside of their habitation, is accumulated round these particles in concentric layers. Pearl consists of carbonate of lime, interstratified with animal membrane.
The oysters whose shells are richest in mother of pearl, are most productive of these highly prized spherical concretions. The most valuable pearl fisheries are on the coast of Ceylon, and at Olmutz in the Persian Gulf, and their finest specimens are more highly prized in the East than diamonds, but in Europe they are liable to be rated very differently, according to the caprice of fashion. When the pearls are large, truly spherical, reflecting and decomposing the light with much vivacity, they are much admired. But one of the causes which renders their value fluctuating, is the occasional loss of their peculiar lustre, without our being able to assign a satisfactory reason for it. Besides, they can be now so well imitated, that the artificial pearls have nearly as rich an appearance as the real.
PEARLS, ARTIFICIAL. These are small globules or pear-shaped spheroids of thin glass, perforated with two opposite holes, through which they are strung, and mounted into necklaces, &c., like real pearl ornaments. They must not only be white and brilliant, but exhibit the iridescent reflections of mother of pearl. The liquor employed to imitate the pearly lustre, is called the essence of the east (essence d’orient), which is prepared by throwing into water of ammonia the brilliant scales, or rather the lamellæ, separated by washing and friction, of the scales of a small river fish, the blay, called in French ablette. These scales digested in ammonia, having acquired a degree of softness and flexibility which allow of their application to the inner surfaces of the glass globules, they are introduced by suction of the liquor containing them in suspension. The ammonia is volatilized in the act of drying the globules.
It is said that some manufacturers employ ammonia merely to prevent the alteration of the scales; that when they wish to make use of them, they suspend them in a well clarified solution of isinglass, then pour a drop of the mixture into each bead, and spread it round the inner surface. It is doubtful whether by this method, the same lustre and play of colours can be obtained as by the former. It seems moreover to be of importance for the success of the imitation, that the globules be formed of a bluish, opalescent, very thin glass, containing but little potash and oxide of lead. In every manufactory of artificial pearls, there must be some workmen possessed of great experience and dexterity. The French are supposed to excel in this ingenious branch of industry.
PEARLWHITE, is a submuriate of bismuth, obtained by pouring a solution of the nitrate of that metal into a dilute solution of sea salt, whereby a light and very white powder is obtained, which is to be well washed and dried. See [Bismuth].
PECTIC ACID (Acid pectique, Fr.; Gallertsaüre, Germ.); so named on account of its jellying property, from πηκτις, coagulum, exists in a vast number of vegetables. The easiest way of preparing it, is to grate the roots of carrots into a pulp, to express their juice, to wash the marc with rain or distilled water, and to squeeze it well; 50 parts of the marc are next to be diffused through 300 of rain-water, adding by slow degrees a solution of one part of pure potash, or two of bicarbonate. This mixture is to be heated, so as to be made to boil for about a quarter of an hour, and is then to be thrown boiling-hot upon a filter cloth. It is known to have been well enough boiled, when a sample of the filtered liquor becomes gelatinous by neutralizing it with an acid. This liquor contains pectate of potassa, in addition to other matters extricated from the root. The pectate may be decomposed by a stronger acid, but it is better to decompose it by muriate of lime; whereby a pectate of lime, in a gelatinous form, quite insoluble in water, is obtained. This having been washed with cold water upon a cloth, is to be boiled in water containing as much muriatic acid as will saturate the lime. The pectic acid thus liberated, remains under the form of a colourless jelly, which reddens litmus paper, and tastes sour, even after it is entirely deprived of the muriatic acid. Cold water dissolves very little of it; it is more soluble in boiling water. The solution is colourless, does not coagulate on cooling, and hardly reddens litmus paper; but it gelatinizes when alcohol, acids, alkalis, or salts are added to it. Even sugar transforms it, after some time, into a gelatinous state, a circumstance which serves to explain the preparation of apple, cherry, raspberry, gooseberry, and other jellies.
PECTINE, or vegetable jelly, is obtained by mixing alcohol with the juice of ripe currants, or any similar fruit, till a gelatinous precipitate takes place; which is to be gently squeezed in a cloth, washed with a little weak alcohol, and dried. Thus prepared, pectine is insipid, without action upon litmus, in small pieces, semi-transparent, and of a membranous aspect, like isinglass. Its mucilaginous solution in cold water is not tinged blue with iodine. A very small addition of potash, or its carbonate, converts pectine into pectic acid; both of which substances are transformed into mucic and oxalic acids by the nitric.
PELTRY (Pelleterie, Fr.; Pelzwerk, Germ.); is nearly synonymous with fur, and comprehends the skins of different kinds of wild animals that are found in high northern latitudes, particularly in the American continent; such as the beaver, bear, moosedeer, marten, mink, sable, woolverin, wolf, &c. When these skins have received no preparation but from the hunters, they are most properly called peltry; but when they have had the inner side tawed or tanned (see [Leather]) by an aluminous process, they may then be denominated furs.
The scouring or cleaning of peltry is performed in a large cask, or truncated cone laid on its side, and traversed by a revolving shaft, which is furnished with a few rectangular rounded pegs. These are intended to stir round the skins, while they are dusted over with Paris plaster, whitening, or sometimes sand, made as hot as the hand can bear. The bottom of the cask should be grated, to allow the impurities to fall out. The lustrage, which the cleansed skins next undergo, is merely a species of dyeing, either topical to modify certain disagreeable shades, or general to impart a more beautiful colour to the fur. Under the articles [Dyeing], and the several colours, as also [Hair] and [Morocco], sufficient instructions will be found for dyeing fur. The mordants should be applied pretty hot by a brush, on the hair of the skin, stretched upon a solid table; and after two or three applications, with drying between, the tinctorial infusions may be rubbed on in the same way. The hair must be freed beforehand from all greasiness, by lime water, or a weak solution of carbonate of soda; then well washed. Much nicety, and many successive applications of the dye-stuff, are sometimes requisite to bring out the desired shade.
Under [Hat Manufacture], I referred to this article for a description of the process of secrétage, whereby the hairs of rabbit and hare skins are rendered fit for felting. Dissolve 32 parts of quicksilver in 500 of common aquafortis; and dilute the solution with one half or two thirds of its bulk of water, according to the strength of the acid. The skin being laid upon a table with the hair side uppermost, a brush, made with the bristles of the wild boar, is to be slightly moistened with the mercurial solution, and passed over the smooth surface of the hairs with strong pressure. This application must be repeated several times in succession, till every part of the fur be equally touched, and till about two thirds of the length of the hairs be moistened, or a little more, should they be rigid. In order to complete this impregnation, the skins are laid together in pairs with the hairy sides in contact, put in this state into the stove-room, and exposed to a heat higher in proportion to the weakness of the mercurial solution. The drying should be rapidly effected, otherwise the concentration of the nitrate will not take due effect in causing the retraction and curling of the hairs.