Porcelain is a kind of pottery ware whose paste is fine grained, compact, very hard, and faintly translucid; and whose biscuit softens slightly in the kiln. Its ordinary whiteness cannot form a definite character, since there are porcelain pastes variously coloured. There are two species of porcelain, very different in their nature, the essential properties of which it is of consequence to establish; the one is called hard, and the other tender; important distinctions, the neglect of which has introduced great confusion into many treatises on this elegant manufacture.
Hard porcelain is essentially composed, first, of a natural clay containing some silica, infusible, and preserving its whiteness in a strong heat; this is almost always a true kaolin; secondly, of a flux, consisting of silica and lime, composing a quartzose felspar rock, called pe-tun-tse. The glaze of this porcelain, likewise earthy, admits of no metallic substance or alkali.
Tender porcelain, styled also vitreous porcelain, has no relation with the preceding in its composition; it always consists of a vitreous frit, rendered opaque and less fusible by the addition of a calcareous or marly clay. Its glaze is an artificial glass or crystal, into which silica, alkalis, and lead enter.
This porcelain has a more vitreous biscuit, more transparent, a little less hard, and less fragile, but much more fusible than that of the hard porcelain. Its glaze is more glossy, more transparent, a little less white, much tenderer, and more fusible.
The biscuit of the hard porcelain made at the French national manufactory of Sèvres is generally composed of a kaolin clay, and of a decomposed felspar rock; analogous to the china clay of Cornwall, and Cornish stone. Both of the above French materials come from Saint Yriex-la-perche, near Limoges.
After many experiments, the following composition has been adopted for the service paste of the royal manufactory of Sèvres; that is, for all the ware which is to be glazed: silica, 59; alumina, 35·2; potash, 2·2; lime, 3·3. The conditions of such a compound are pretty nearly fulfilled by taking from 63 to 70 of the washed kaolin or china clay, 22 to 15 of the felspar; nearly 10 of flint powder, and about 5 of chalk. The glaze is composed solely of solid felspar, calcined, crushed, and then ground fine at the mill. This rock pretty uniformly consists of silica 73, alumina 16·2, potash 8·4, and water 0·6.
The kaolin is washed at the pit, and sent in this state to Sèvres, under the name of decanted earth. At the manufactory it is washed and elutriated with care; and its slip is passed through fine sieves. This forms the plastic, infusible, and opaque ingredient to which the substance must be added which gives it a certain degree of fusibility and semi-transparency. The felspar rock used for this purpose, should contain neither dark mica nor iron, either as an oxide or sulphuret. It is calcined to make it crushable, under stamp-pestles driven by machinery, then ground fine in hornstone mills, as represented in [figs. 897], [898], [899], and [900.] This pulverulent matter being diffused through water, is mixed in certain proportions, regulated by its quality, with the argillaceous slip. The mixture is deprived of the chief part of its water in shallow plaster pans without heat; and the resulting paste is set aside to ripen, in damp cellars, for many months.
When wanted for use, it is placed in hemispherical pans of plaster, which absorb the redundant moisture; after which it is divided into small lumps, and completely dried. It is next pulverized, moistened a little, and laid on a floor, and trodden upon by a workman marching over it with bare feet in every direction; the parings and fragments of soft moulded articles being intermixed, which improve the plasticity of the whole. When sufficiently tramped, it is made up into masses of the size of a man’s head, and kept damp till required.
The dough is now in a state fit for the potter’s lathe; but it is much less plastic than stoneware paste, and is more difficult to fashion into the various articles; and hence one cause of the higher price of porcelain.