"When binary compounds, or compounds of two elements, are decomposed by an electric current, the two elements make their appearance at opposite poles. These elements which are disengaged at the negative pole are termed electro-positive or positive or basylous elements, while those disengaged at the positive pole are termed electro-negative or negative or chlorous elements. But the difference between these two classes of elements is one of degree only, and they gradually merge into each other; moreover the electric relations of elements are not absolute, but vary according to the state of combination in which they exist, so that it is just as impossible to divide the elements into two classes according to this property as it is to separate them into two distinct classes of metals and non-metals."
We follow here the grouping according to external forms, and the student should compare it with the groups marked in the lemniscate arrangement shown in Article II (p. 377, properly p. 437, February), reading the group by the disks that fall below each other; thus the first group is H, Cl, Br, I (hydrogen, chlorine, bromine, iodine) and a blank for an undiscovered element. The elements grow denser in descending order; thus hydrogen is an invisible gas; chlorine a denser gas visible by its colour; bromine is a liquid; iodine is a solid—all, of course, when temperature and pressure are normal. By the lowering of temperature and the increase of pressure, an element which is normally gaseous becomes a liquid, and then a solid. Solid, liquid, gaseous, are three interchangeable states of matter, and an element does not alter its constitution by changing its state. So far as a chemical "atom" is concerned, it matters not whether it be drawn for investigation from a solid, a liquid, or a gas; but the internal arrangements of the "atoms" become much more complicated as they become denser and denser, as is seen by the complex arrangements necessitated by the presence of the 3546 ultimate atoms contained in the chemical "atom" of gold, as compared with the simple arrangement of the 18 ultimate atoms of hydrogen.
According to the lemniscate arrangement, we should commence with hydrogen as the head of the first negative group, but as it differs wholly from those placed with it, it is better to take it by itself. Hydrogen is the lightest of the known elements, and is therefore taken as 1 in ordinary chemistry, and all atomic weights are multiples of this. We take it as 18, because it contains eighteen ultimate atoms, the smallest number we have found in a chemical element. So our "number-weights" are obtained by dividing the total number of atoms in an element by 18 (see p. 349, January).
Hydrogen
(Plate V, 1).—Hydrogen not only stands apart from its reputed group by not having the characteristic dumb-bell shape, well shown in sodium (
, opposite p. 349, January), but it also stands apart in being positive, serving as a base, not as a chlorous, or acid, radical, thus "playing the part of a metal," as in hydrogen chloride (hydrochloric acid), hydrogen sulphate (sulphuric acid), etc.
It is most curious that hydrogen, oxygen and nitrogen, the most widely spread gases, all differ fundamentally in form from the groups they reputedly head.[[19]] Hydrogen was the first chemical element examined by us, nearly thirteen years ago, and I reproduce here the substance of what I wrote in November, 1895, for we have nothing to add to nor amend in it.