[176] Annual Report of the Geol. Surv. for 1895, p. 27 of reprint.
Fig. 54.—Section of part of the Arenig volcanic group, stream south of Bennane Head, Ayrshire.
As an illustration of some of the characteristic features in the succession of deposits in the volcanic series of the south-west of Ayrshire, the accompanying section ([Fig. 54]) is inserted. In descending order we come first upon a group of greywackes and grey shattery mudstones (a), followed by grey-green and dark banded cherts, containing Radiolaria and much plicated. Next comes a group of dark-grey, black and red cherts, with numerous partings and thin bands of tuff and volcanic conglomerate (c). The siliceous bands were certainly deposited during the volcanic eruptions, and they are moulded round the rugose, slaggy upper surface of the band of lavas (d) on which they directly lie. These lavas have the sack-like or pillow structure already described, and they enclose lumps of chert containing Radiolaria. A few yards to the west of the line of section bands of nodular tuff are interposed between the top of the lavas and the overlying cherts, with which also they are interstratified. These tuffs contain blocks of lava six inches or more in diameter. Below the belt of lavas come black cherts and shales (e) succeeded below by volcanic breccias and tuffs (f) alternating with shales in thin inconstant courses. These coarse detrital rocks are thoroughly volcanic in origin, and they contain fragments of the black cherts which lie still lower in the series. The whole depth of strata represented in this section does not amount to much more than 100 feet.
While in some parts of the Ayrshire district the coarse breccias that accumulated around their parent vents form most of the upper part of the volcanic series, in others the lavas are succeeded by fine tuffs which are intercalated among the ordinary sediments, and show a gradual decline and cessation of volcanic energy. South of Ballantrae, for example, the lavas occupy more than two miles of coast, in which space they display hardly any intercalations of sedimentary material, though they show more or less distinctly that they consist of many separate flows. Where they at last end, bands of nodular and fine tuff make their appearance, together with bands of ashy shale and the characteristic zone of the red radiolarian cherts or flints. Above these, in conformable sequence, come bands of black shale, containing abundant Upper Llandeilo graptolites, overlain by greenish or olive-coloured shaly mudstones, which pass upward into a thick overlying group of greywackes.
In this section the alternation of fine pyroclastic with ordinary sediment shows that the volcanic eruptions in the southern part of the Ballantrae district came to an end by a slowly-lessening series of explosions. The ashy material gradually dies out, and does not reappear all through the thick group of sandy and muddy sediments which here overlies the volcanic series.
We thus learn from the evidence of the Ayrshire sections that volcanic action was in full vigour in the south-west of Scotland during the Arenig period, but gradually died out before the end of the Llandeilo period. The rocks in which this volcanic history is chronicled have been very greatly disturbed and plicated, so that though from their frequently vertical position they might be thought to attain a vast depth, they very possibly do not exceed 500 feet in thickness.
As the volcanic series is followed north-eastwards it exhibits a gradual diminution in extent and variety, but this may be at least partly due to the much less depth of it exposed on the crests of the narrow anticlines that bring it to the surface. There is evidence in that region that the eruptions did not everywhere terminate in the Llandeilo period, but were in some districts prolonged into the age of the Bala rocks. Thus in the neighbourhood of Sanquhar volcanic breccias, tuffs and lavas have been found by Messrs. Peach and Horne intercalated in strata apparently belonging to the Bala group. Again, in the district of Hartfell, a moderately coarse volcanic agglomerate occurs in the heart of the so-called "barren mudstones" of the Hartfell black-shale group, which, from its graptolites, is placed on the horizon of the Bala rocks. At Winkstone, Hamilton Hill, and Wrae in Peeblesshire, perlitic felsites and soda-felsites have been detected by Messrs. Peach and Horne and determined by Mr. Teall. They are associated with the Bala limestone, which in some of its conglomeratic bands contains pebbles of felsite.
The intrusive rocks which accompany the Lower Silurian volcanic series of the south of Scotland are best displayed in the south-west of Ayrshire, between Girvan and Ballantrae, where they appear to be on the whole later than at least the great mass of the interstratified lavas and tuffs. The most abundant rocks and the earliest to be injected are complex basic masses which include serpentine, olivine-enstatite rock, troctolite, gabbro and other compounds, all which may be different modifications of the same original basic magma. They do not show a finer texture where they respectively meet, nor any other symptom of having been subsequently intruded into each other, though they do exhibit such structures along their lines of contact with the surrounding rocks, into which they are intrusive. These more basic masses have subsequently been invaded by irregular bosses and dyke-like protrusions, which, when small, are fine-grained dolerites, but when in larger bodies take the form of gabbro, sometimes exhibiting a mineral banding and foliated structure. These banded varieties much resemble the banded Tertiary gabbros of Skye and some parts of the Lewisian gneiss.
At the Byne Hill, near Girvan, a large intrusive boss or ridge displays on its outer margin a fine-grained texture, where it comes in contact with the serpentine. Further inwards it becomes a fine dolerite, passing into gabbro and increasing in coarseness of grain as well as in acidity of composition, through stages of what in the field would be called diorite and quartz-diorite, into a central granitic rock, whereof milky or blue quartz forms the prominent constituent. The intrusive rocks of this district have generally been injected parallel to the stratification-planes, and take on the whole the form of sills.