The material which has filled up the vents is almost entirely fragmental, varying from a coarse agglomerate to a fine volcanic tuff. Some minor necks have been completely or in great part filled with angular debris of the ordinary rocks of the neighbourhood. In the western neck on the Largo shore, for example, which rises through the red rocks of the Upper Coal-measures, the material consists largely of fragments of red sandstone, clay and shale. Between Elie and St. Monans, some of the necks are filled almost wholly with debris of black shale and encrinal limestone.
There does not appear to be any relation between the diameter of a funnel and the size of the blocks that now fill it. Some of the larger necks, for example, consist of comparatively fine tuff. The Buddo Ness, on the other hand, though so small a vent, is packed with blocks of shale six feet long, while the sandstone through which the orifice has been drilled passes, as usual, into quartzite for several yards away from the edge. As an example of the general aspect presented by one of the coarse agglomerates in the necks of the Fife coast, a view is given in [Fig. 216] of a portion of the neck at Ardross, about two miles east from Elie. This thoroughly volcanic accumulation is here shown to consist of blocks of all sizes heaped together without any definite arrangement.
Fig. 216.—Agglomerate of neck on shore at Ardross, two miles east from Elie.
Since the first stage in the history of the vents has been the perforation of the solid crust by explosion, and the consequent production of debris from the disrupted rocks, we may hope to detect underneath the pile of thoroughly volcanic ejections, traces of the first explosions. I have been much struck with the fact that in the East of Fife such traces may frequently be found here and there within the outer border of the vents. At Largo, and again between Elie and St. Monans, it may be noticed that the mass of material adhering to the wall of a neck, exposed in ground-plan upon the beach, often consists largely, or even wholly, of debris of sandstone, shale and limestone, while the central and chief mass is made up of green tuff or agglomerate, with occasional pieces of the surrounding stratified rocks scattered through it. It seems probable, therefore, that the sections of these Fife necks, laid bare on the present shore, do not lie far below the original crater-bottoms.
Some light might be expected to be thrown upon the phenomena in an active volcanic chimney by the condition of the fragments of recognizable sedimentary rocks imbedded in the ejected debris which has filled up the orifice. But the assistance from this source is neither so full nor so reliable as could be wished. In some of the Fife vents, indeed, the fragments of shale, sandstone and other sedimentary strata are so unchanged that they cannot on a fresh fracture be distinguished from the adjacent parent strata. The Spirifers, Lingulæ, crinoids, cyprid-cases, ganoid scales and other fossils are often as fresh and perfect in the fragments of rock imbedded in tuff as they are in the rock in situ. In some cases, however, distinct, and occasionally even extreme, metamorphism may be detected, varying in intensity from mere induration to the production of a crystalline texture. The amount of alteration has depended not merely upon the heat of the volcanic vent, but also in great measure upon the susceptibility of the fragments to undergo change and the duration of their exposure to it.
Dr. Heddle has computed the temperature to which fragments of shale, etc., in tuff-necks of the Fife coast have been subjected. He found that the bituminous shales have lost all their illuminants, and of organic matter have retained only some black carbonaceous particles; that the encrinal limestones have become granular and crystalline; that the sandstones present themselves as quartzite, and that black carbonaceous clays show every stage of a passage into Lydian-stone. He inferred from the slight depth to which the alteration has penetrated the larger calcareous fragments, that the heat to which they were exposed must have been but of short continuance. As the result of his experiments, he concluded that the temperature at which the fragments were finally ejected from the volcanic vents probably lay between 660° and 900° Fahr.[98]
[98] Trans. Roy. Soc. Edin. vol. xxviii. p. 487.
It may be perhaps legitimate to infer that, while the fragments that fell back into the volcanic funnel, or which were detached from the sides of the vent, after having been exposed for some time to intense heat under considerable pressure, would suffer more or less metamorphism, those, on the other hand, which were discharged by the æriform explosions from the cool upper crust, on the first outburst of a vent, would not exhibit any trace of such a change. Where, therefore, we meet with a neck full of fragments of unaltered stratified rocks, we may suppose it to have been that of a short-lived volcano; where, on the other hand, the fragments are few and much altered, they may mark the site of a vent which continued longer active. The metamorphism of the fragmentary contents of a volcanic funnel by the action of ascending vapours has already been described in the case of one of the vents of the Carboniferous plateaux ([vol. i. p. 404]).
One of the most curious and puzzling features in the contents of the tuff necks of the Fife coast is the occurrence there of crystals and fragments of minerals, often of considerable size, which do not bear evidence of having-been formed in situ, but have undoubtedly been ejected with the other detritus. Dr. Heddle has noticed the fact, and has described some of the minerals which occur in this way. The following list comprises the species which he and I have found:—