In order to make liquid air an article of commerce the most important condition was a wholesale decrease in cost of production. In 1857 C. W. Siemens took out a patent for making the liquid on what is known as the regenerative principle, whereby the compressed air is chilled by expanding a part of it. Professor Dewar—a scientist well known for his researches in the field of liquid gases—had in 1892 produced liquid air by a modification of the principle at comparatively small cost; and other inventors have since then still further reduced the expense, until at the present day there appears to be a prospect of liquid air becoming cheap enough to prove a dangerous rival to steam and electricity.
A company, known as the Liquid Air, Power and Automobile Company, has established large plants in America and England for the manufacture of the liquid on a commercial scale. The writer paid a visit to their depot in Gillingham Street, London, where he was shown the process by Mr. Hans Knudsen, the inventor of much of the machinery there used. The reader will doubtless like to learn the “plain, unvarnished truth” about the creation of this peculiar liquid, and to hear of the freaks in which it indulges—if indeed those may be called freaks which are but obedience to the unchanging laws of Nature.
On entering the factory the first thing that strikes the eye and ear is the monstrous fifty horse-power gas-engine, pounding away with an energy that shakes the whole building. From its ponderous flywheels great leather belts pass to the compressors, three in number, by which the air, drawn from outside the building through special purifiers, is subjected to an increasing pressure. Three dials on the wall show exactly what is going on inside the compressors. The first stands at 90 lbs. to the square inch, the second at 500, and the third at 2200, or rather less than a ton pressure on the area of a penny! The pistons of the low-pressure compressor is ten inches in diameter, but that of the high pressure only two inches, or 1/25 of the area, so great is the resistance to be overcome in the last stage of compression.
Now, if the cycle-pump heats our hands, it will be easily understood that the temperature of the compressors is very high. They are water-jacketed like the cylinders of a gas-engine, so that a circulating stream of cold water may absorb some of the heat. The compressed air is passed through spiral tubes winding through large tanks of water which fairly boils from the fierceness of the heat of compression.
When the air has been sufficiently cooled it is allowed to pass into a small chamber, expanding as it goes, and from the small into a larger chamber, where the cold of expansion becomes so acute that the air-molecules collapse into liquid, which collects in a special receptacle. Arrangements are made whereby any vapour rising from the liquid passes through a space outside the expansion chambers, so that it helps to cool the incoming air and is not wasted.
The liquid-air tank is inside a great wooden case, carefully protected from the heat of the atmosphere by non-conducting substances. A tap being turned, a rush of vapour shoots out, soon followed by a clear, bluish liquid, which is the air we breathe in a fresh guise.
A quantity of it is collected in a saucepan. It simmers at first, and presently boils like water on a fire. The air-heat is by comparison so great that the liquid cannot resist it, and strives to regain its former condition.
You may dip your finger into the saucepan—if you withdraw it again quickly—without hurt. The cushion of air that your finger takes in with it protects you against harm—for a moment. But if you held it in the liquid for a couple of seconds you would be minus a digit. Pour a little over your coat sleeve. It flows harmlessly to the ground, where it suddenly expands into a cloud of chilly vapour.
Put some in a test tube and cork it up. The cork soon flies out with a report—the pressure of the boiling air drives it. Now watch the boiling process. The nitrogen being more volatile—as it boils at a lower temperature than oxygen—passes off first, leaving the pure, blue oxygen. The temperature of this liquid is over 312 degrees below zero (as far below the temperature of the air we breathe as the temperature of molten lead is above it!). A tumbler of liquid oxygen dipped into water is soon covered with a coating of ice, which can be detached from the tumbler and itself used as a cup to hold the liquid. If a bit of steel wire be now twisted round a lighted match and the whole dipped into the cup, the steel flares fiercely and fuses into small pellets; which means that an operation requiring 3000 degrees Fahrenheit has been accomplished in a liquid 300 degrees below zero!
Liquid air has curious effects upon certain substances. It makes iron so brittle that a ladle immersed for a few moments may be crushed in the hands; but, curiously enough, it has a toughening effect on copper and brass. Meat, eggs, fruit, and all bodies containing water become hard as steel and as breakable as glass. Mercury is by it congealed to the consistency of iron; even alcohol, that can brave the utmost Arctic cold, succumbs to it. The writer was present when some thermometers, manufactured by Messrs. Negretti and Zambra, were tested with liquid air. The spirit in the tubes rapidly descended to 250 degrees below zero, then sank slowly, and at about 260 degrees froze and burst the bulb. The measuring of such extreme temperatures is a very difficult matter in consequence of the inability of spirit to withstand them, and special apparatus, registering cold by the shrinkage of metal, must be used for testing some liquid gases, notably liquid hydrogen, which is so much colder than liquid air that it actually freezes it into a solid ice form!