The above is equivalent to computing the theoretical amount of air required per pound of fuel by the formula:

Weight per pound = 11.52 C + 34.56
(H -
O
––––
8
)
+ 4.32 S (10)

where C, H, O and S are proportional parts by weight of carbon, hydrogen, oxygen and sulphur by ultimate analysis.

[Pg 153]

In practice it is impossible to obtain perfect combustion with the theoretical amount of air, and an excess may be required, amounting to sometimes double the theoretical supply, depending upon the nature of the fuel to be burned and the method of burning it. The reason for this is that it is impossible to bring each particle of oxygen in the air into intimate contact with the particles in the fuel that are to be oxidized, due not only to the dilution of the oxygen in the air by nitrogen, but because of such factors as the irregular thickness of the fire, the varying resistance to the passage of the air through the fire in separate parts on account of ash, clinker, etc. Where the difficulties of drawing air uniformly through a fuel bed are eliminated, as in the case of burning oil fuel or gas, the air supply may be materially less than would be required for coal. Experiment has shown that coal will usually require 50 per cent more than the theoretical net calculated amount of air, or about 18 pounds per pound of fuel either under natural or forced draft, though this amount may vary widely with the type of furnace, the nature of the coal, and the method of firing. If less than this amount of air is supplied, the carbon burns to monoxide instead of dioxide and its full heat value is not developed.

[TABLE 32]
CALCULATED THEORETICAL AMOUNT OF AIR
REQUIRED PER POUND OF VARIOUS FUELS
FuelWeight of Constituents in One
Pound Dry Fuel
Air Required
per Pound
of Fuel
Pounds
Carbon
Per Cent
Hydrogen
Per Cent
Oxygen
Per Cent
Coke94.010.8
Anthracite Coal91.5 3.5 2.611.7
Bituminous Coal87.0 5.0 4.011.6
Lignite70.0 5.020.0 8.9
Wood50.0 6.043.5 6.0
Oil85.0 3.0 1.014.3

An excess of air is also a source of waste, as the products of combustion will be diluted and carry off an excessive amount of heat in the chimney gases, or the air will so lower the temperature of the furnace gases as to delay the combustion to an extent that will cause carbon monoxide to pass off unburned from the furnace. A sufficient amount of carbon monoxide in the gases may cause the action known as secondary combustion, by igniting or mingling with air after leaving the furnace or in the flues or stack. Such secondary combustion which takes place either within the setting after leaving the furnace or in the flues or stack always leads to a loss of efficiency and, in some instances, leads to overheating of the flues and stack.

[Table 32] gives the theoretical amount of air required for various fuels calculated from formula ([10]) assuming the analyses of the fuels given in [the table].

The process of combustion of different fuels and the effect of variation in the air supply for their combustion is treated in detail in the chapters dealing with the various fuels.
[Pg 154]