Causticity: To 50 cubic centimeters of treated water, to which there has been added one drop of phenolphthalein dissolved in alcohol to give the water a pinkish color, add the acid solution, drop by drop, shaking after each addition, until the color entirely disappears. One-tenth cubic centimeter of acid solution corresponds to one degree of causticity.
The alkalinity may be determined from the same sample tested for causticity by the coloring with methylorange and adding the acid until the sample is on the point of turning red. The total acid added in determining both causticity and alkalinity in this case is the measure of the alkalinity.
Hardness: 100 cubic centimeters of the treated water is used for this test, one cubic centimeter of the soap solution corresponding to one degree of hardness. The soap solution is added a very little at a time and the whole violently shaken. Enough of the solution must be added to make a permanent lather or foam, that is, the soap bubbles must not disappear after the shaking is stopped.
Excess of lime as determined by nitrate of silver: If there is an excess of lime used in the treatment, a sample will become a dark brown by the addition of a small quantity of silver nitrate, otherwise a milky white solution will be formed.
Combined Heat and Chemical Treatment: Heat is used in many systems of feed treatment apparatus as an adjunct to the chemical process. Heat alone will remove temporary hardness by the precipitation of carbonates of lime and magnesia and, when used in connection with the chemical process, leaves only the permanent hardness or the sulphates of lime to be taken care of by chemical treatment.
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The chemicals used in the ordinary lime and soda process of feed water treatment are common lime and soda. The efficiency of such apparatus will depend wholly upon the amount and character of the impurities in the water to be treated. [Table 16] gives the amount of lime and soda required per 1000 gallons for each grain per gallon of the various impurities found in the water. [This table] is based on lime containing 90 per cent calcium oxide and soda containing 58 per cent sodium oxide, [Pg 106] which correspond to the commercial quality ordinarily purchasable. From [this table] and the cost of the lime and soda, the cost of treating any water per 1000 gallons may be readily computed.
Less Usual Reagents—Barium hydrate is sometimes used to reduce permanent hardness or the calcium sulphate component. Until recently, the high cost of barium hydrate has rendered its use prohibitive but at the present it is obtained as a by-product in cement manufacture and it may be purchased at a more reasonable figure than heretofore. It acts directly on the soluble sulphates to form barium sulphate which is insoluble and may be precipitated. Where this reagent is used, it is desirable that the reaction be allowed to take place outside of the boiler, though there are certain cases where its internal use is permissible.
Barium carbonate is sometimes used in removing calcium sulphate, the products of the reaction being barium sulphate and calcium carbonate, both of which are insoluble and may be precipitated. As barium carbonate in itself is insoluble, it cannot be added to water as a solution and its use should, therefore, be confined to treatment outside of the boiler.
Silicate of soda will precipitate calcium carbonate with the formation of a gelatinous silicate of lime and carbonate of soda. If calcium sulphate is also present, carbonate of soda is formed in the above reaction, which in turn will break down the sulphate.