Pure air is a mechanical mixture of oxygen and nitrogen. While different authorities give slightly varying values for the proportion of oxygen and nitrogen contained, the generally accepted values are:

By volume, oxygen 20.91 per cent, nitrogen 79.09 per cent.
By weight, oxygen 23.15 per cent, nitrogen 76.85 per cent.

Air in nature always contains other constituents in varying amounts, such as dust, carbon dioxide, ozone and water vapor.

Being perfectly elastic, the density or weight per unit of volume decreases in geometric progression with the altitude. This fact has a direct bearing in the proportioning of furnaces, flues and stacks at high altitudes, as will be shown later in the discussion of these subjects. The atmospheric pressures corresponding to various altitudes are given in [Table 12] .

The weight and volume of air depend upon the pressure and the temperature, as expressed by the formula:

P v = 53.33 T ( 9 )
WhereP=the absolute pressure in pounds per square foot,
v=the volume in cubic feet of one pound of air,
T=the absolute temperature of the air in degrees Fahrenheit,
53.33=a constant for air derived from the ratio of pressure, volume and temperature of a perfect gas.

The weight of one cubic foot of air will obviously be the reciprocal of its volume, that is, 1/ v pounds.

[TABLE 27]
VOLUME AND WEIGHT OF AIR
AT ATMOSPHERIC PRESSURE AT VARIOUS TEMPERATURES
Temperature
Degrees
Fahrenheit
Volume
One Pound
in
Cubic Feet
Weight One
Cubic Foot
in Pounds
Temperature
Degrees
Fahrenheit
Volume
One Pound
in
Cubic Feet
Weight One
Cubic Foot
in Pounds
Temperature
Degrees
Fahrenheit
Volume
One Pound
in
Cubic Feet
Weight One
Cubic Foot
in Pounds
3212.390.08071016015.615.06404134020.151.049625
5012.843.07786317015.867.06302436020.655.048414
5512.969.07710718016.119.06203938021.159.047261
6013.095.07636519016.371.06108440021.663.046162
6513.221.07563720016.623.06015842522.293.044857
7013.347.07492321016.875.05925945022.923.043624
7513.473.07422321216.925.05908447523.554.042456
8013.599.07353522017.127.05838850024.184.041350
8513.725.07286023017.379.05754152524.814.040300
9013.851.07219724017.631.05671855025.444.039302
9513.977.07154625017.883.05591957526.074.038352
10014.103.07090726018.135.05514260026.704.037448
11014.355.06966227018.387.05438665027.964.035760
12014.607.06846028018.639.05365170029.224.034219
13014.859.06729929018.891.05293575030.484.032804
14015.111.06617730019.143.05223880031.744.031502
15015.363.06509232019.647.05089885033.004.030299