Philosophy

by Bertrand Russell

PART II
THE PHYSICAL WORLD

[CHAPTER IX]
THE STRUCTURE OF THE ATOM

In all that we have said hitherto on the subject of man from without, we have taken a common-sense view of the material world. We have not asked ourselves: what is matter? Is there such a thing, or is the outside world composed of stuff of a different kind? And what light does a correct theory of the physical world throw upon the process of perception? These are questions which we must attempt to answer in the following chapters. And in doing so the science upon which we must depend is physics. Modern physics, however, is very abstract, and by no means easy to explain in simple language. I shall do my best, but the reader must not blame me too severely if, here and there, he finds some slight difficulty or obscurity. The physical world, both through the theory of relativity and through the most recent doctrines as to the structure of the atom, has become very different from the world of everyday life, and also from that of scientific materialism of the eighteenth-century variety. No philosophy can ignore the revolutionary changes in our physical ideas that the men of science have found necessary; indeed it may be said that all traditional philosophies have to be discarded, and we have to start afresh with as little respect as possible for the systems of the past. Our age has penetrated more deeply into the nature of things than any earlier age, and it would be a false modesty to over-estimate what can still be learned from the metaphysicians of the seventeenth, eighteenth and nineteenth centuries.

What physics has to say about matter, and the physical world generally, from the standpoint of the philosopher, comes under two main heads: first, the structure of the atom; secondly, the theory of relativity. The former was, until recently, the less revolutionary philosophically, though the more revolutionary in physics. Until 1925, theories of the structure of the atom were based upon the old conception of matter as indestructible substance, although this was already regarded as no more than a convenience. Now, owing chiefly to two German physicists, Heisenberg and Schrödinger, the last vestiges of the old solid atom have melted away, and matter has become as ghostly as anything in a spiritualist seance. But before tackling these newer views, it is necessary to understand the much simpler theory which they have displaced. This theory does not, except here and there, take account of the new doctrines on fundamentals that have been introduced by Einstein, and it is much easier to understand than relativity. It explains so much of the facts that, whatever may happen, it must remain a stepping-stone to a complete theory of the structure of the atom; indeed, the newer theories have grown directly out of it, and could hardly have arisen in any other way. We must therefore spend a little time in giving a bare outline, which is the less to be regretted as the theory is in itself fascinating.

The theory that matter consists of “atoms”, i.e. of little bits that cannot be divided, is due to the Greeks, but with them it was only a speculation. The evidence for what is called the atomic theory was derived from chemistry, and the theory itself, in its nineteenth-century form, was mainly due to Dalton. It was found that there were a number of “elements”, and that other substances were compounds of these elements. Compound substances were found to be composed of “molecules”, each molecule being composed of “atoms” of one substance combined with “atoms” of another or of the same. A molecule of water consists of two atoms of hydrogen and one atom of oxygen; they can be separated by electrolysis. It was supposed, until radio-activity was discovered, that atoms were indestructible and unchangeable. Substances which were not compounds were called “elements”. The Russian chemist Mendeleev discovered that the elements can be arranged in a series by means of progressive changes in their properties; in his time, there were gaps in this series, but most of them have since been filled by the discovery of new elements. If all the gaps were filled, there would be 92 elements; actually the number known is 87, or, including three about which there is still some doubt, 90. The place of an element in this series is called its “atomic number”. Hydrogen is the first, and has the atomic number 1; helium is the second, and has the atomic number 2; uranium is the last, and has the atomic number 92. Perhaps in the stars there are elements with higher atomic numbers, but so far none has been actually observed.

The discovery of radio-activity necessitated new views as to “atoms”. It was found that an atom of one radio-active element can break up into an atom of another element and an atom of helium, and that there is also another way in which it can change. It was found also that there can be different elements having the same place in the series; these are called “isotopes”. For example, when radium disintegrates it gives rise, in the end, to a kind of lead, but this is somewhat different from the lead found in lead-mines. A great many “elements” have been shown by Dr. F. W. Aston to be really mixtures of isotopes, which can be sorted out by ingenious methods. All this, but more especially the transmutation of elements in radio-activity, led to the conclusion that what had been called “atoms” were really complex structures, which could change into atoms of a different sort by losing a part. After various attempts to imagine the structure of an atom, physicists were led to accept the view of Sir Ernest Rutherford, which was further developed by Niels Bohr.

In this theory, which, in spite of recent developments, remains substantially correct, all matter is composed of two sorts of units, electrons and protons. All electrons are exactly alike, and all protons are exactly alike. All protons carry a certain amount of positive electricity, and all electrons carry an equal amount of negative electricity. But the mass of a proton is about 1835 times that of an electron: it takes 1835 electrons to weigh as much as one proton. Protons repel each other, and electrons repel each other, but an electron and a proton attract each other. Every atom is a structure consisting of electrons and protons. The hydrogen atom, which is the simplest, consists of one proton with one electron going round it as a planet goes round the sun. The electron may be lost, and the proton left alone; the atom is then positively electrified. But when it has its electron, it is, as a whole, electrically neutral, since the positive electricity of the proton is exactly balanced by the negative electricity of the electron.

The second element, helium, has already a much more complicated structure. It has a nucleus, consisting of four protons, and two electrons very close together, and in its normal state it has two planetary electrons going round the nucleus. But it may lose either or both of these, and it is then positively electrified.

All the latter elements consist, like helium, of a nucleus composed of protons and electrons, and a number of planetary electrons going round the nucleus. There are more protons than electrons in the nucleus, but the excess is balanced by the planetary electrons when the atom is unelectrified. The number of protons in the nucleus gives the “atomic weight” of the element: the excess of protons over electrons in the nucleus gives the “atomic number”, which is also the number of planetary electrons when the atom is unelectrified. Uranium, the last element, has 238 protons and 146 electrons in the nucleus, and when unelectrified it has 92 planetary electrons. The arrangement of the planetary electrons in atoms other than hydrogen is not accurately known, but it is clear that, in some sense, they form different rings, those in the outer rings being more easily lost than those nearer the nucleus.

I come now to what Bohr added to the theory of atoms as developed by Rutherford. This was a most curious discovery, introducing, in a new field, a certain type of discontinuity which was already known to be exhibited by some other natural processes. No adage had seemed more respectable in philosophy than “natura non facit saltum”, Nature makes no jumps. But if there is one thing more than another that the experience of a long life has taught me, it is that Latin tags always express falsehoods; and so it has proved in this case. Apparently Nature does make jumps, not only now and then, but whenever a body emits light, as well as on certain other occasions. The German physicist Planck was the first to demonstrate the necessity of jumps. He was considering how bodies radiate heat when they are warmer than their surroundings. Heat, as has long been known, consists of vibrations, which are distinguished by their “frequency”, i.e. by the number of vibrations per second. Planck showed that, for vibrations having a given frequency, not all amounts of energy are possible, but only those having to the frequency a ratio which is a certain quantity h multiplied by 1 or 2 or 3 or some other whole number, in practice always a small whole number. The quantity h is known as “Planck’s constant”; it has turned out to be involved practically everywhere where measurement is delicate enough to know whether it is involved or not. It is such a small quantity that, except where measurement can reach a very high degree of accuracy, the departure from continuity is not appreciable.[7]