Volta began his life-work as professor of physics at Pavia by extending his observations on gases. He was the first to demonstrate the expansion of gases under heat, especially as regards their increased expansibility at higher temperatures. Many observers had been at work on this problem before his time, but there were serious discrepancies in the results reported. Volta was the first to point out the reasons for the apparent inconsistencies of previous investigators' findings; and from his observations alone some valuable data might have been obtained for the establishment of what has since become known as the "law of Charles."
At this time, his knowledge of English enabled him to follow English discoveries closely, and he seems to have paid particular attention to the work of Cavendish and Priestley. Not long after Cavendish's description of the method of obtaining pure hydrogen, Volta made a series of observations on the relations of spongy platinum to this gas, and pointed out the spontaneous ignition that takes place when the two substances are brought together. This experiment is the basis of what has since been known as the hydrogen lamp, called, from the German observer who first made it a practical instrument, Dobereiner's lamp.
After seven years of teaching, Volta was given the opportunity to visit various parts of Europe, and took advantage of the occasion to meet most of the celebrated men of science. His linguistic faculty stood him in good stead during this sabbatical year, and his travel aided him in completing a thorough acquaintanceship with European languages as well as with scientists. His practical character led him, during his trip, to note the growth of the potato and its uses in various European countries, and he brought the plant home with him to Italy in order to introduce it among the farmers. He succeeded in making his countrymen realize its value, and the introduction of the potato is one of the reasons for which Italians have always looked up to him as a benefactor of his native land. How modern this makes a vegetable we are inclined to think of as having been always an important food resource of the race!
About the middle of the third quarter of the eighteenth century, by one of the fortunate accidents that happen, however, only to genius, Galvani, at the time Professor of anatomy in Bologna, had been led to make the observation that if a frog, so prepared that its hind leg is attached to the trunk only by means of the sciatic nerve, happens to be touched by a metal instrument in such a way as to put nerve and muscle in connection with each other through the metal instrument, a very curious phenomenon is observed, the muscles of the almost severed leg becoming spasmodically contracted and then relaxed whenever the contacts were made and broken. Galvani noted the phenomenon first in connection with an electric machine, and looked for an explanation of it in electricity, thinking that there was an analogy between it and the discharge of the Leyden jar. After several years of careful observation, he published a monograph on the subject, which at once attracted attention all over Europe.
Volta was very much interested in Galvani's work, and took up the development of it from the physical side. At first he agreed with the explanation offered by Galvani, who considered that his experiment demonstrated the presence of electricity in animal bodies, and who proposed to introduce the term "animal electricity." After careful investigation, however, Galvani's assertion that animal electricity existed in a form entirely independent of any external electricity, though it had been accepted by most of the distinguished men of science of the time, seemed to Volta without experimental verification. For many years his most determined efforts were used to demonstrate that the muscle twitchings observed were not due to the presence of animal electricity (galvanism as it had come to be called), but to the fact that the metals touching the different portions of the moist nerve muscle preparation really set up minute currents of ordinary electricity.
Some of the experiments which he devised for this purpose were extremely ingenious, and show how thoroughly empirical were his methods and how modern his scientific spirit. In the course of his experiments he found that a difference in the metals of which the arc was composed, when used for the purpose of eliciting the so-called animal electricity, made a great difference in the electrical phenomena observed and in the amount of muscle twitchings obtained. In one brilliant series of experiments, moreover, he showed that, even when the metallic portions touching nerve and muscle were identical, there might still be distinct electrical phenomena, if only an artificial difference in temperature of the end of the metallic arc were produced. Volta was even able to demonstrate that such minute physical differences as the filing of one end of the metallic arc used might give rise to small currents of electricity.
In the midst of these experiments, he came to the realization that two portions of metal of different kinds, separated by a moist non-conducting material, might be made to produce a constant current of electricity for some time. More than this, however, he found that discs of metal of different kinds might be piled on top of one another with intervening discs of moist cloth, and so produce proportionately stronger currents as more and more of the metal plates were employed. This was the origin of the voltaic pile, as it has been called—the first battery for the production at will of regular currents of electricity of definite strength.[20]
While engaged at this he succeeded in demonstrating what has come to be known as Volta's basic experiment; namely, that two plates of metal of different kinds become electrically excited merely by contact. This was practically the beginning of the great advance in applied electricity which ushered in our modern electrical era. It seems a simple matter now, looking back over the century that has elapsed since then, to have taken the successive steps that Volta did for the construction of his electrical pile and for the demonstration of the principle of contact electricity. Groping, as he was, in the dark, however, it took him three years to make the progress that we have described in a few words. How great his discoveries appeared, even to the most distinguished of his scientific contemporaries, can best be judged from an expression of one of the greatest of French electrical scientists, Arago, who declared "Volta's pile the most wonderful instrument that has ever come from the hand of man, not excluding even the telescope or the steam-engine."
An excellent description of just how Volta made his electric pile and what he was able to accomplish with it experimentally in the laboratory, is to be found in the numbers for January and February, 1900, of the Stimmen aus Maria-Laach—a literary and scientific periodical published by the German Jesuits. This article on Alessandro Volta, by Father Kneller, S. J., was written shortly after the celebration of the hundredth anniversary of Volta's invention of the electric pile, when there had just been a fresh sorting over of Volta's documents, and contains a very full set of references to the biographical material for Volta's life. Father Kneller says:
"Before this, no one thought for a moment of any possibility of the practical application of electricity. But all at once the whole situation changed. After eight years of observation and experiment, Volta accomplished one day, at the beginning of 1800, in his laboratory at Como, the construction of an instrument which was to revolutionize the study and the practical applications of electricity. He made a pile composed of a large number of equal-sized copper and zinc discs. On each copper disc he placed one of zinc, and then on this a moistened piece of cloth, and continued the series of alternate discs and cloths in this order until he had a rather high column. This was an apparatus as simple as possible and from which no one but Volta could possibly have promised any results. The inventor, however, knew what he was about.