LOSS OF COPPER.

Copper present.Dry Assay.Margin.Loss on 100 Parts of Copper.
Per cent.Per cent.Per cent.
100982.02.0
9592-1/22.52.6
9087-3/82.62.9
8582-3/82.63.0
8077-3/82.63.2
7572-3/82.63.5
7067-1/22.53.6
6562-1/22.53.8
6057-5/82.44.0
5552-3/42.34.2
5047-3/42.24.4
45432.04.5
4038-1/81.84.6
3533-1/41.74.8
3028-1/21.505.0
2523-1/21.506.0
2018-1/21.567.8
1816-1/21.538.5
1614-1/21.489.3
1412-5/81.4010.0
1210-5/81.3711.4
108-3/41.2812.8
86-7/81.1414.3
651.0517.5
541.0020.0
431.0025.0
3.752-3/40.9726.0
3.502-9/160.9427.0
3.252-5/160.9128.0
3.002-1/80.8729.0
2.751-15/160.8230.0
2.501-3/40.7731.0
2.251-1/20.7232.0
2.001-5/160.6633.0

The wet assay being known, the dry assay can be calculated with the help of the above table by deducting the amount in the column headed "margin" opposite the corresponding percentage. For example, if the wet assay gives a produce of 17.12 per cent., there should be deducted 1.5; the dry assay would then be 15.62, or, since the fractions are always expressed in eighths, 15-5/8. With impure ores, containing from 25 to 50 per cent. of copper, the differences may be perhaps 1/4 greater.

Wet methods are gradually replacing the dry assay, and it is probable that in the future they will supersede it; for stock-taking, and the various determinations required in smelting works and on mines, they are generally adopted, because they give the actual copper contents, and since it is obvious that a knowledge of this is more valuable to the miner and smelter. Moreover, the working of the dry method has been monopolised by a small ring of assayers, with the double result of exciting outside jealousy and, worse still, of retarding the development and improvement of the process.

The principal stages of the dry assay are: (1) the concentration of the copper in a regulus; (2) the separation of the sulphur by calcining; (3) the reduction of the copper by fusion; and (4) the refining of the metal obtained.

The whole of these operations are not necessary with all copper material. Ores are worked through all the stages; with mattes, the preliminary fusion for regulus is omitted; precipitates are simply fused for coarse copper, and refined; and blister or bar coppers are refined, or, if very pure, subjected merely to washing.

The quantity of ore generally taken is 400 grains, and is known as "a full trial"; but for rich material, containing more than 50 per cent. of copper, "a half trial," or 200 grains, is used.

Fusion for Regulus.—The ore (either with or without a previous imperfect roasting to get rid of any excess of sulphur) is mixed with borax, glass, lime, and fluor spar; and, in some cases, with nitre, or iron pyrites, according to the quality of the ore. The mixture is placed in a large Cornish crucible, and heated as uniformly as possible in the wind furnace, gradually raising the temperature so as to melt down the charge in from 15 to 20 minutes. The crucible is removed and its contents poured into an iron mould. When the slag is solid, it is taken up with tweezers and quenched in water. The regulus is easily detached from the slag. It should be convex above and easily broken, have a reddish brown colour, and contain from 40 to 60 per cent. of copper. A regulus with more than this is "too fine," and with less "too coarse." A regulus which is too fine is round, compact, hard, and of a dark bluish grey on the freshly broken surface. A coarse regulus is flat and coarse grained, and more nearly resembles sulphide of iron in fracture and colour.

If an assay yields a regulus "too coarse," a fresh determination is made with more nitre added, or the roasting is carried further. With low class ores a somewhat coarse regulus is an advantage. If, on the other hand, the regulus is too fine, less nitre or less roasting is the remedy. With grey copper ores and the oxidised ores, iron pyrites is added.