ZINC.
Zinc occurs in nature most commonly as sulphide (blende); it also occurs as carbonate (calamine) and silicate (smithsonite). Each of these is sufficiently abundant to be a source of the metal.
The metal is known in commerce as "spelter" when in ingots, and as sheet zinc when rolled. It is chiefly used in the form of alloys with copper, which are known as brasses. It is also used in the form of a thin film, to protect iron goods from rusting—galvanised iron.
Ores of zinc, more especially blende, are met with in most lead, copper, gold, and silver mines, in larger or small quantities scattered through the lodes. Those ores which generally come under the notice of the assayer are fairly rich in zinc; but alloys and metallurgical products contain it in very varying proportions.
Zinc itself is readily soluble in dilute acids; any residue which is left after boiling with dilute hydrochloric or sulphuric acid consists simply of the impurities of the metal; this is generally lead.
All zinc compounds are either soluble in, or are decomposed by, boiling with acids, the zinc going into solution. Zinc forms only one series of salts, and these are colourless. Their chief characteristic is solubility in an alkaline solution, from which sulphuretted hydrogen produces a white precipitate of zinc sulphide. Zinc is detected by dissolving the substance in hydrochloric or nitric acid, boiling, and adding sodic hydrate in excess, filtering, and adding ammonic sulphide to the filtrate. The precipitate contains the zinc, which can be dissolved out by boiling with dilute sulphuric acid, and detected by the formation of a white precipitate on the addition of potassic ferrocyanide.
The dry assay of zinc can only be made indirectly, and is unsatisfactory. Zinc is volatile, and at the temperature of its reduction is a gas. It is impracticable to condense the vapour so as to weigh the metal, consequently its amount is determined by loss. The following method gives approximate results: Take 10 grams of the dried and powdered ore and roast, first at a low temperature and afterwards at a higher one, with the help of carbonate of ammonia to decompose the sulphates formed; cool and weigh. The metals will be present as oxides. Mix with 2 grams of powdered charcoal and charge into a black-lead crucible heated to whiteness, cover loosely, and leave in the furnace for about a quarter of an hour. Uncover and calcine the residue, cool and weigh. The loss in weight multiplied by 8.03 gives the percentage of zinc in the ore.
WET METHODS.
Solution and separation may be effected as follows: Treat 1 or 3 grams of the substance with 10 or 30 c.c. of hydrochloric acid or aqua regia; evaporate to dryness; take up with 10 c.c. of hydrochloric acid and dilute to 100 c.c.; heat nearly to boiling; saturate with sulphuretted hydrogen; filter, and wash with water acidulated with hydrochloric acid. Boil off the sulphuretted hydrogen and peroxidise with a few drops of nitric acid. Cool; add caustic soda till nearly, but not quite, neutralised, and separate the iron as basic acetate by the method described under Iron. To the filtrate add ammonia till alkaline, and pass sulphuretted hydrogen. Allow to settle and decant on to a filter. Dissolve off the precipitate from the filter with hot dilute hydrochloric acid. The solution will contain the zinc, together with any manganese the ore contained, and, perhaps, traces of nickel and cobalt. If the zinc is to be determined volumetrically, and manganese is present, this latter is separated with carbonate of ammonia, as described further on; but if a gravimetric method is used, and only small quantities of manganese are present, it is better to proceed as if it were absent, and to subsequently determine its amount, which should be deducted.